LAYERED FILM COMPOSITIONS, PACKAGES PREPARED THEREFROM, AND METHODS OF USE
The invention relates to films and methods of making the same. The inventive films comprise at least three layers, an inner layer and at least two outer layers located at opposite surfaces of the inner layer. In one embodiment, the inner layer is formed from a composition comprising an ethylene-based interpolymer or a propylene-based interpolymer, and at least one outer layer is formed from a composition comprising one or more propylene-based interpolymers. The invention also provides articles formed from the inventive films, and for methods of making the same.
1 . A film, comprising at least three layers, an inner layer and at least two outer layers located at opposite surfaces of the inner layer, and
wherein the inner layer is formed from a composition comprising an ethylene-based interpolymer, which has a density from 0.87 g/cc to 0.94 g/cc, and a melt index (I2) from 0.5 g/10 min to 10 g/10 min, and
wherein at least one outer layer is formed from a composition comprising a propylene-based interpolymer, which has a density from 0.86 g/cc to 0.89 g/cc, and a melt flow rate (MFR) from 1 g/10 min to 15 g/10 min.
2 . The film of claim 1 , wherein the at least two outer layers are formed from the same composition.
3 . The film of claim 1 , wherein each of the two outer layers is adjacent to the surface of the inner layer.
4 . The film of claim 1 , wherein ethylene-based interpolymer is a linear low density ethylene/α-olefin interpolymer.
5 . The film of claim 4 , wherein the α-olefin of the ethylene/α-olefin interpolymer is selected from the group consisting of C3-C12 α-olefins.
6 . The film of claim 4 , wherein the ethylene/α-olefin interpolymer is a copolymer of ethylene and 1-butene or a copolymer of ethylene and 1-octene.
7 . The film of claim 4 , wherein the ethylene/α-olefin interpolymer has a melt index (I 2 ) from 0.7 g/10 min to 3 g/10 min.
8 . The film of claim 4 , wherein the ethylene/α-olefin interpolymer has a density from 0.87 g/cc to 0.93 g/cc.
9 . The film of claim 4 , wherein the ethylene/α-olefin interpolymer has a melt index from 0.7 to 3 grams/10 minutes, a density from 0.87 g/cc to 0.93 g/cc.
10 . The film of claim 1 , wherein the propylene-based interpolymer is a propylene/α-olefin interpolymer.
11 . The film of claim 1 , wherein the propylene-based interpolymer is a propylene/ethylene interpolymer.
12 . The film of claim 1 , wherein the propylene-based interpolymer is a copolymer of propylene and ethylene.
13 . The film of claim 11 , wherein the propylene/ethylene interpolymer has a melt index (I 2 ) from 2 g/10 min to 10 g/10 min.
14 . The film of claim 12 , wherein the propylene/ethylene interpolymer has a melt index OD from 2 g/10 min to 10 g/10 min.
15 . The film of claim 14 , wherein the propylene-based interpolymer has a melt index from 2 to 10 grams/10 minutes, and a density from 0.87 g/cc to 0.89 g/cc.
16 . The film of claim 1 , wherein the composition, used to form the inner layer, further comprises a propylene-based interpolymer.
17 . The film of claim 16 , wherein the composition, used to form the inner layer, comprises from 20 to 80 weight percent of the propylene-based interpolymer, and from 50 to 80 weight percent of the ethylene-based interpolymer, and wherein each weight percent is based on the sum weight of the propylene-based interpolymer and the ethylene-based interpolymer.
18 . The film of claim 17 , wherein the ethylene-based interpolymer is an ethylene/α-olefin interpolymer.
19 . The film of claim 18 , wherein the ethylene/α-olefin interpolymer has a density from 0.87 g/cc to 0.93 g/cc.
20 . The film of claim 18 , wherein the ethylene/α-olefin interpolymer has a melt index (I2) from 0.7 g/10 min to 3 g/10 min.
21 . The film of claim 1 , wherein the film comprises at least five layers.
22 . The film of claim 1 , wherein the film has a seal strength greater than 7 N, at 10 to 20 micron total film thickness, and 90° C.
23 . The film of claim 1 , wherein the film has a MD shrinkage of at least 10 percent, at a temperature from 90° C. to 120° C.
24 . The film of claim 1 , wherein the film has a shrinkage ratio, MD Shrinkage/TD Shrinkage from 0.5 to 1.50 at a temperature from 90° C. to 120° C.
25 . An article comprising at least one component formed from the film composition of claim 1 .
26 . A package comprising at least one component formed from the film composition of claim 1 .
27 . A laminated substrate comprising a laminate formed from the film of claim 1 .
28 . The laminated substrate of claim 27 , wherein the substrate is formed from a composition comprising a polyester.
29 . A film comprising at least three layers, an inner layer and at least two outer layers located at opposite surfaces of the inner layer, and
wherein the inner layer is formed from a composition comprising a first propylene-based interpolymer, which has a density from 0.83 g/cc to 0.89 g/cc, and a melt flow rate (MFR) from 0.5 g/10 min to 10 g/10 min, and
wherein at least one outer layer is formed from a composition comprising a second propylene-based interpolymer, which has a density from 0.86 g/cc to 0.91 g/cc, and a melt flow rate (MFR) from 1 g/10 min to 15 g/10 min.
30 . The film of claim 29 , wherein the at least two outer layers are formed from the same composition.
31 . The film of claim 29 , wherein each of the two outer layers is adjacent to the surface of the inner layer.
32 . The film of claim 29 , wherein the first propylene-based interpolymer is a propylene/α-olefin interpolymer.
33 . The film of claim 29 , wherein the first propylene-based polymer is a propylene/ethylene interpolymer.
34 . The film of claim 29 , wherein the second propylene-based interpolymer is a propylene/α-olefin interpolymer.
35 . The film of claim 29 , wherein the second propylene-based interpolymer is a propylene/ethylene interpolymer.
36 . The film of claim 33 , wherein the first propylene/ethylene interpolymer has a melt index (I 2 ) from 1 g/10 min to 3 g/10 min.
37 . The film of claim 33 , wherein the first propylene/ethylene interpolymer has a density from 0.84 g/cc to 0.89 g/cc.
38 . The film of claim 33 , wherein the first propylene/ethylene interpolymer has a melt index from 1 to 3 grams/10 minutes, a density from 0.84 g/cc to 0.89 g/cc.
39 . The film of claim 35 , wherein the second propylene/ethylene interpolymer has a melt index (I 2 ) from 2 g/10 min to 10 g/10 min.
40 . The film of claim 35 , wherein the second propylene/ethylene interpolymer has a density from 0.86 g/cc to 0.89 g/cc.
41 . The film of claim 35 , wherein the second propylene/ethylene interpolymer has a melt index from 2 to 10 grams/10 minutes, a density from 0.86 g/cc to 0.89 g/cc.
42 . The film of claim 29 , wherein the composition, used to form the inner layer, further comprises an ethylene-based interpolymer.
43 . The film of claim 42 , wherein the composition, used to form the inner layer, comprises from 50 to 80 weight percent of the propylene-based interpolymer, and from 20 to 50 weight percent of the ethylene-based interpolymer, and wherein each weight percent is based on the sum weight of the propylene-based interpolymer and the ethylene-based interpolymer.
44 . The film of claim 43 , wherein the ethylene-based interpolymer is an ethylene/α-olefin interpolymer.
45 . The film of claim 44 , wherein the ethylene/α-olefin interpolymer has a density from 0.87 g/cc to 0.93 g/cc.
46 . The film of claim 45 , wherein the ethylene/α-olefin interpolymer has a melt index (I2) from 0.7 g/10 min to 3 g/10 min.
47 . The film composition of claim 29 , wherein the composition, used to form the outer layer, further comprises an ethylene-based interpolymer.
48 . The film of claim 29 , wherein the film comprises at least five layers.
49 . The film of claim 29 , wherein the film has a seal strength greater than 7 N, at 10 to 20 micron total film thickness, and 90° C.
50 . The film of claim 34 , wherein the film has an MD shrinkage of at least 10 percent, at a temperature from 90° C. to 120° C.
51 . The film of claim 34 , wherein the film has a shrinkage ratio, MD Shrinkage/TD Shrinkage from 0.5 to 1.50, at a temperature from 90° C. to 120° C.
52 . An article comprising at least one component formed from the film of claim 29 .
53 . A package comprising at least one component formed from the film of claim 29 .
54 . A laminated substrate comprising a laminate formed from the film of claim 29 .
55 . The laminated substrate of claim 54 , wherein the substrate is formed from a composition comprising a polyester.
56 . A method for forming a film comprising at least three layers, an inner layer and at least two outer layers located at opposite surfaces of the inner layer, said method comprising:
a) selecting the polymer composition for the formation of each layer of the film composition;
b) coextruding the compositions of each film layer to form a first film composition;
c) subjecting the first film composition to a double bubble process to form the film; and
wherein the inner layer is formed from a composition comprising an ethylene-based interpolymer, which has a density from 0.87 g/cc to 0.94 g/cc, and a melt index (I2) from 0.5 g/10 min to 10 g/10 min, and
wherein at least one outer layer is formed from a composition comprising a propylene-based interpolymer, which has a density from 0.86 g/cc to 0.89 g/cc, and a melt flow rate (MFR) from 1 g/10 min to 15 g/10 min.
57 . A method for forming a film comprising at least three layers, an inner layer and at least two outer layers located at opposite surfaces of the inner layer, said method comprising:
a) selecting the polymer composition for the formation of each layer of the film composition;
b) coextruding the compositions of each film layer to form a first film composition;
c) subjecting the first film composition to a double bubble process to form the film; and
wherein the inner layer is formed from a composition comprising a first propylene-based interpolymer, which has a density from 0.83 g/cc to 0.89 g/cc, and a melt flow rate (MFR) from 0.5 g/10 min to 10 g/10 min, and
wherein at least one outer layer is formed from a composition comprising a second propylene-based interpolymer, which has a density from 0.86 g/cc to 0.91 g/cc, and a melt flow rate (MFR) from 1 g/10 min to 15 g/10 min.
58 . A film, comprising at least three layers, an inner layer and at least two outer layers located at opposite surfaces of the inner layer, and
wherein the inner layer is formed from a composition comprising a propylene-based interpolymer, which has a density from 0.86 g/cc to 0.89 g/cc, and a melt flow rate (MFR) from 1 g/10 min to 15 g/10 min, and
wherein at least one outer layer is formed from a composition comprising an ethylene-based interpolymer, which has a density from 0.87 g/cc to 0.94 g/cc, and a melt index (I2) from 0.5 g/10 min to 10 g/10 min.
59 . The film of claim 58 , wherein the composition, used to form the inner layer, further inner layer further comprises an ethylene-based interpolymer.
60 . The film of claim 58 , wherein the composition, used to form the outer layer, further inner layer further comprises an propylene-based interpolymer.
61 . The film of claim 58 , wherein the film composition comprises at least five layers.
62 . The film of claim 58 , wherein the film composition has a seal strength greater than 7 N, at 10 to 20 micron total film thickness, and 90° C.
63 . The film of claim 58 , wherein the film composition has a MD shrinkage of at least 10 percent, at a temperature from 90° C. to 120° C.
64 . The film of claim 58 , wherein the film has a shrinkage ratio, MD Shrinkage/TD Shrinkage from 0.5 to 1.50, at a temperature from 90° C. to 120° C.
65 . An article comprising at least one component formed from the film of claim 58 .
66 . A package comprising at least one component formed from the film of claim 58 .
67 . A laminated substrate comprising a laminate formed from the film of claim 58 .
68 . The laminated substrate of claim 67 , wherein the substrate is formed from a composition comprising a polyester.
69 . A method for forming a film comprising at least three layers, an inner layer and at least two outer layers located at opposite surfaces of the inner layer, said method comprising:
a) selecting the polymer composition for the formation of each layer of the film composition;
b) coextruding the compositions of each film layer to form a first film composition;
c) subjecting the first film composition to a double bubble process to form the film; and
wherein the inner layer is formed from a composition comprising a propylene-based interpolymer, which has a density from 0.86 g/cc to 0.89 g/cc, and a melt flow rate (MFR) from 1 g/10 min to 15 g/10 min, and
wherein at least one outer layer is formed from a composition comprising an ethylene-based interpolymer, which has a density from 0.87 g/cc to 0.94 g/cc, and a melt index (I2) from 0.5 g/10 min to 10 g/10 min.