Device and method for handling multi-component mixture
Device and method for handling multi-component mixtures, comprising at least two not completely mixable fluid phases. The device comprises an arrangement of at least two high-pressure separators, being operatively connected each with a low-pressure separator. Each high-pressure separator comprises an outlet line for volatile gaseous constituents. Each low-pressure separator is operatively connected to a gas collecting container or shares at least one gas collecting container with a further low-pressure separator. At least one high-pressure separator has at least one outlet connection for gaseous constituents, being connected with a part to the analysis. The device is used in high-throughput research or in combinatory chemistry, preferably for the research of multi-component mixtures produced in experiments with catalyst, or in connection with high-pressure processes.
1. A device for handling and analyzing multi-component mixtures, comprising:
(a) at least two parallel reaction spaces;
(b) at least one high-pressure separation unit for each reaction space;
(c) at least one connection from an outlet side of the reaction spaces to the at least one high-pressure separation unit; and
(d) at least one low-pressure separation unit connected to the at least one high-pressure separation unit via a connection;
wherein each high-pressure separation unit is provided with at least one discharge connection for gaseous components, which is connected to a unit for analysis,
wherein each low-pressure separation unit comprises a discharge pipe for liquid components and a discharge pipe for gaseous components, the discharge pipe of the low-pressure separation unit for gaseous components being connected with at least one gas-collecting receiver, and
wherein the device is configured to direct the gaseous components from the at least one high pressure separation unit to the unit for analysis without passing through the at least one low-pressure separation unit.
2. The device according to claim 1 , wherein each low-pressure separation unit has a supply for inert gas and strip gas.
3. The device according to claim 1 , wherein in a parallel arrangement of at least two low-pressure separation units per at least two low-pressure separation units at least two connections are provided to a gas-collecting receiver, respectively, which is shared by the at least two low-pressure separation units.
4. The device according to claim 1 , wherein each discharge connection comprises at least one restrictor.
5. The device according to claim 3 , wherein the ratio of internal volume of the high-pressure separation unit to the volume of an employed catalyst is in a range of from approximately 10:1 to approximately 100:1.
6. A device for handling and analyzing multi-component mixtures, comprising:
(a) at least two parallel reaction spaces;
(b) at least one high-pressure separation unit for each reaction space;
(c) at least one connection from an outlet side of the reaction spaces to the at least one high-pressure separation unit; and
(d) at least one low-pressure separation unit connected to the at least one high-pressure separation unit via a connection;
wherein each high-pressure separation unit is provided with at least one discharge connection for gaseous components, which is directly connected to a unit for analysis such that the device is configured to direct the gaseous components from the at least one high pressure separation unit to the unit for analysis without passing through the at least one low-pressure separation unit, and
wherein each low-pressure separation unit comprises a discharge pipe for liquid components and a discharge pipe for gaseous components.
7. A method for handling multi-component mixtures using the device according to claim 6 , the method comprising:
separating at least one multi-component mixture, which emanates from the at least two parallel reaction spaces into the at least one high-pressure separation unit that corresponds to said reaction spaces, respectively, which is in operative connection with the at least one low-pressure separation unit;
discharging highly volatile gaseous components from at least one high-pressure region of the at least one high-pressure separation unit via the at least one discharge connection for gaseous components, which directly leads to the system for analysis.
8. The method according to claim 7 , wherein each discharge connection ( 90 ) comprises at least one restrictor.
9. The method according to claim 7 further comprising:
(i) opening a valve between at least one qas-collecting receiver, which is connected to the at least one low-pressure separation unit, and a vacuum pump, and pumping down at least parts of the gas phase being present within the gas-collecting receiver;
(ii) closing a valve between the gas-collecting receiver and the vacuum pump as soon as a pre-determined pressure is reached;
(iii) opening the connection from the at least one high-pressure separation unit to the at least one low-pressure separation unit as soon as a pre-determined filling level of the at least one high-pressure separation unit is reached, and feeding the fluid being present in the at least one high-pressure separation unit into the at least one low-pressure separation unit;
(iv) feeding inert gas/strip gas into the fluid being present in the at least one low-pressure separation unit;
(v) transferring the inert gas/strip gas which has been fed into the at least one low-pressure separation unit and/or the gaseous components from the at least one low-pressure separation unit into a gas-collecting receiver;
(vi) discharging the liquid fluid which has been collected within the at least one low-pressure separation unit via a discharge pipe;
(vii) performing the method by means of an automatic process control;
(viii) online-analysis of gaseous compounds which are discharged from the high-pressure region via discharge connection;
(ix) performing the method by means of an automatic process control;
(x) taking-up the liquid fluid which has been discharged from the at least one low-pressure separation unit by means of an automatic sample-collecting system and/or analysis of the product mixture.
10. The method according to claim 7 , wherein the highly volatile gaseous compounds, which are discharged at the at least one high-pressure separation unit and are fed via the discharge connection to the unit for analysis, is hot gas.
11. The method according to claim 9 wherein, by means of restrictor elements in the at least one discharge connection, the discharge of gaseous components, which have a lower volatility, from the at least one high-pressure separation unit into the at least one discharge connection, is prevented except for a pre-determined residual value.
12. The method according to claim 9 , wherein gaseous components are continuously discharged via the at least one discharge connection for gaseous components.