Method for separation and recycle of pure sulfur dioxide from a gaseous mixture in is cycle with ionic liquids
View Patent ↗The present invention relates to a method for separation and recycling of pure sulfur dioxide from a gaseous mixture in the IS cycle. More specifically, the present invention relates to a method for separation and recycling of pure sulfur dioxide from a gaseous mixture in the IS cycle using an ionic liquid under a specific condition. When compared with the conventional amine-based absorbent, the use of the ionic liquid enables continuous absorption and stripping of SO 2 even at high temperature, and enables a reversible absorption of SO 2 without loss, decomposition or degradation of a solvent due to good chemical stability, thereby enabling separation and recycling of pure SO 2 from a gaseous mixture in the IS cycle.
1. A method for separation and recycling of pure sulfur dioxide (SO 2 ) from a gaseous mixture in the iodine-sulfur (IS) cycle, comprising: contacting a gaseous mixture discharged from the IS cycle comprising decomposition of sulfuric acid (H 2 SO 4 ), Bunsen reaction of SO 2 and decomposition of hydrogen iodide (HI) with an ionic liquid, thereby absorbing and separating SO 2 contained in the gaseous mixture by the ionic liquid; and
degassing the absorbed and separated SO 2 from the ionic liquid.
2. The method for separation and recycling of pure SO 2 according to claim 1 , wherein the absorption and separation of SO 2 is performed at 20 to 50° C.
3. The method for separation and recycling of pure SO 2 according to claim 1 , wherein the stripping is performed at 120 to 250° C.
4. The method for separation and recycling of pure SO 2 according to claim 1 , wherein the ionic liquid is an ionic compound comprising a cation selected from imidazolium, pyrrolidinium, piperidinium, morpholinium and pyridinium and an anion selected from hydrogen sulfate (HOSO 3− ), methyl sulfate (CH 3 OSO 3− ), ethyl sulfate (C 2 H 6 OSO 3− ), methanesulfonate (CH 3 SO 3− ), acetate (CH 3 COO − ), tetrafluoroborate (BF 4− ), hexafluorophosphate (PF 6− ) and chloride (Cl − ) or a mixture thereof.
5. The method for separation and recycling of pure SO 2 according to claim 1 , wherein the ionic liquid is imidazolium acetate, imidazolium chloride or a mixture thereof.
6. The method for separation and recycling of pure SO 2 according to claim 1 , wherein the ionic liquid is used in an amount from 1.5 to 5.0 mols based on 1 mol of the gaseous mixture discharged from the IS cycle.
7. The method for separation and recycling of pure SO 2 according to claim 1 , wherein the gaseous mixture discharged from the IS cycle includes 40 to 80 weight % of SO 2 and 20 to 60 weight % of oxygen (O2).
8. The method for separation and recycling of pure SO 2 according to claim 1 , wherein the separation and recycling of SO 2 is performed continuously in an absorption tower and a stripping tower.
9. The method for separation and recycling of pure SO 2 according to claim 1 , by which SO 2 is recycled with recovery rate of 85 to 95% and purity of 98 to 99%.
10. The method for separation and recycling of pure SO 2 according to claim 4 , wherein the ionic liquid is imidazolium acetate, imidazolium chloride or a mixture thereof.