Production of metathesis products by high melting polymer segment interchange

1. A process for preparing a cross-metathesized product mixture comprising contacting a metathesis catalyst under metathesis conditions with a composition comprising two or more chemically distinguishable ethylenically unsaturated polymers, each polymer having a molecular weight of at least 1000 g/mole, the first of said ethylenically unsaturated polymers having a Tg less than 0° C., and the second of said ethylenically unsaturated polymers comprising hard segments and having an expected Tg or measured Tm value greater than 120° C., to thereby form the cross-metathesized reaction product, which has a random distribution of chemically distinguishable blocks; wherein the ethyleneic content of the first ethylenically unsaturated polymer is at least 15 mole percent, and the ethyleneic content of the second ethylenically unsaturated polymer is 0.01 to 5 mole percent; wherein the chemically distinguishable blocks are evidenced by microdomains as determined by SAXS analysis; and

wherein the first unsaturated polymer is polybutadiene, polyisoprene, poly(2-chloro-1,3-butadiene), or poly(2-fluoro-1,3-butadiene), and the second unsaturated polymer is a copolymer of butadiene with ethylene or propylene, and optionally octene; or

wherein the first unsaturated polymer is an unsaturated polyaromatic compound and the second unsaturated polymer is a poly(ethylene-co-butadiene); or

wherein the first unsaturated polymer is a polyethylene oxide) and the second unsaturated polymer a poly(ethylene-co-butadiene); or

the first unsaturated polymer is functionalized with a polar group and the second unsaturated polymer is a copolymer of ethylene or propylene with a diene or alkyne, and optionally, one or more additional C 2-20 olefins, or partially hydrogenated derivatives thereof; and

wherein the metathesis is conducted in the presence of a catalyst comprising a compound of the general formula:

wherein:

M A is ruthenium or osmium;

X A and X B are the same or different anionic ligand;

L A is a neutral electron donor ligand;

L B is a neutral electron donor ligand or a nitrogen containing heterocyclic carbene; and

R A and R B are independently each occurrence hydrogen, or an alkyl, alkenyl, alkynyl, aryl, carboxylate, alkoxy, alkenyloxy, alkynyloxy, aryloxy, alkoxycarbonyl, alkylthio, alkylsulfonyl, alkylsulfinyl, or silyl group of up to 20 atoms not counting hydrogen, an alkyl, alkoxy, aryl, aralkyl, haloalkyl, haloalkoxy, haloaryl or haloalkaryl substituted derivative thereof; or a functionalized derivative of any of the foregoing wherein the functional group is hydroxyl, thiol, alcohol, sulfonic acid, phosphine, thioether, ketone, aldehyde, ester, ether, amine, imine, amide, imide, imido, nitro, carboxylic acid, disulfide, carbonate, isocyanate, carbodiimide, carboalkoxy, carbamate, acetal, ketal, boronate, cyano, cyanohydrin, hydrazinc, oxime, hydrazide, enamine, sulfone, sulfide, sulfenyl, or halogen.

2. The process according to claim 1 wherein the catalyst comprises a ruthenium derivative wherein L B is a tertiary phosphine, and L A is either a tertiary phosphine or a nitrogen containing heterocyclic ligand.

3. A cross-metathesized reaction product preparable according to claim 1 .

4. The cross-metathesized reaction product according to claim 3 wherein the first unsaturated polymer is a poly(ethylene-co-butadiene) and the second unsaturated polymer is a poly(ethylene-co-octene-co-butadiene).

5. A partially hydrogenated derivative of the cross-metathesized reaction product of claim 3 .

6. A composition comprising the reaction product of claim 3 wherein the first ethylenically unsaturated polymer is incompatiable with the second ethylenically unsaturated polymer, after reaction a portion of each of the polymers remain and are compatiblized by the presence of a quantity of the cross-metathesized reaction product.