Silicone release coating compositions
View Patent ↗A release coating composition is prepared comprising a polyorganosiloxane (A) having alkenyl groups, a crosslinking agent (B) having organohydrogensiloxane groups, a catalyst for the hydrosilylation reaction between (A) and (B), and an anchorage additive for enhancing the adhesion of the composition to a polymer film substrate. The anchorage additive is the reaction product of a fluid polyorganosiloxane (C) containing at least one alkenyl group and at least one silanol group with a hydrolysable silane (D) containing at least one epoxide group. The curable silicone release coating composition can be applied to a substrate known as a ‘liner’ retaining a label, which liner can for example be paper or a polymer film, and cured.
1. A release coating composition comprising: a polyorganosiloxane (A) having alkenyl groups; a crosslinking agent (B) having organohydrogensiloxane groups; a catalyst for the hydrosilylation reaction between (A) and (B); an anchorage additive for enhancing the adhesion of the composition to a polymer film substrate, characterised in that the anchorage additive is the reaction product of a fluid polyorganosiloxane (C) containing at least one alkenyl group and at least one silanol group with a hydrolysable silane (D) containing at least one epoxide group; and a filler present from 0 to 30% by weight of the release coating composition, wherein the release coating composition is free from a fluoroorganosilicone compound.
2. A release coating composition according to claim 1 , wherein the polyorganosiloxane (C) has a degree of polymerisation of 4 to 50 siloxane units.
3. A release coating composition according to claim 2 , wherein the polyorganosiloxane (C) is a polydiorganosiloxane having terminal silanol groups.
4. A release coating composition according to claim 3 , wherein the polyorganosiloxane (C) is a copolymer of methylvinylsiloxane units and dimethylsiloxane units.
5. A release coating composition according to claim 2 , wherein the silane (D) comprises an (epoxy-substituted alkyl) di or trialkoxy silane.
6. A release coating composition according to claim 2 , wherein the epoxide groups in the silane (D) are present as glycidyl groups.
7. A release coating composition according to claim 2 , wherein the epoxide groups in the silane (D) are epoxycyclohexyl groups.
8. A release coating composition according to claim 1 , wherein the polyorganosiloxane (C) is a polydiorganosiloxane having terminal silanol groups.
9. A release coating composition according to claim 8 , wherein the polyorganosiloxane (C) is a copolymer of methylvinylsiloxane units and dimethylsiloxane units.
10. A release coating composition according to claim 1 , wherein the silane (D) comprises an (epoxy-substituted alkyl) di or trialkoxy silane.
11. A release coating composition according to claim 1 , wherein the epoxide groups in the silane (D) are present as glycidyl groups.
12. A release coating composition according to claim 1 , wherein the epoxide groups in the silane (D) are epoxycyclohexyl groups.
13. A release coating composition according to claim 1 , wherein the fluid polyorganosiloxane (C) and hydrolysable silane (D) are reacted in a weight ratio in the range 10:90 to 90:10.
14. A release coating composition according to claim 1 , wherein the anchorage additive is the reaction product of the polyorganosiloxane (C), the silane (D) and a di(hydrocarbyl)dialkoxysilane in which each hydrocarbyl group is selected from alkyl and alkenyl groups.
15. A release coating composition according to claim 1 , wherein the polyorganosiloxane (A) is a branched siloxane comprising one or more Q units of the formula (SiO 4/2 ), from 15 to 995 D units of the formula R b 2 SiO 2/2 and M units of the formula R a R b 2 SiO 1/2 , wherein the R a and R b substituents are selected from alkyl and alkenyl groups having 1 to 6 carbon atoms, at least three R a substituents in the branched siloxane being alkenyl units.
16. A release coating composition according to claim 1 , wherein the composition further contains a cure inhibitor selected from ethylenically or aromatically unsaturated amides, acetylenic compounds, ethylenically unsaturated isocyanates, olefinic siloxanes, unsaturated hydrocarbon diesters, conjugated ene-ynes, hydroperoxides, nitriles and diaziridines.
17. A release coating composition according to claim 1 , wherein the anchorage additive is present at 0.5 to 10% by weight of the release coating composition.
18. A process for providing a release coating to a polymer film comprising:
applying to the polymer film a release coating composition comprising:
a polyorganosiloxane (A) having alkenyl groups; a crosslinking agent (B) having organohydrogensiloxane groups; a catalyst for the hydrosilylation reaction between (A) and (B); an anchorage additive for enhancing the adhesion of the release coating composition to the polymer film, wherein the anchorage additive is the reaction product of a fluid polyorganosiloxane (C) containing at least one alkenyl group and at least one silanol group with a hydrolysable silane (D) containing at least one epoxide group; a filler present from 0 to 30% by weight of the release coating composition; wherein the release coating composition is free from a fluoroorganosilicone compound;
and heating the applied release coating composition to cure the applied release coating composition.