Halide-based scintillator nanomaterial
Scintillator material comprising nanoparticles (nanocrystals) comprising lead (Pb), iodine (I), and optionally one or both of oxygen (O) and hydrogen (H) wherein the nanoparticles exhibit room-temperature scintillation under gamma irradiation. The scintillator nanoparticles can comprise Pb 3 O 2 I 2 . The scintillator nanoparticles can comprise PbIOH in generally equiatomic proportions or non-equiatomic variants thereof that exhibit scintillation under gamma irradiation. The scintillator nanoparticles have a particle dimension in the range of about 5 to about 100 nm. Microparticles (microcrystals) also are provided comprising lead (Pb), iodine (I), and optionally one or both of oxygen (O) and hydrogen (H) grown in a nanoparticle colloidal solution over time to a particle dimension greater than 0.1 μm, such as about 2 microns. A heterogeneous scintillator material is provided comprising core/shell nanoparticles having a highly hygroscopic or deliquescent halide-based core activated with trivalent Ln 3+ or divalent Ln 2+ lanthanide ions (Ln=La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu) and a stable non-hygroscopic shell thereon. The heterogeneous nanoparticles can comprise highly hygroscopic lanthanide halide (LaBr 3 , LuI 3 ) cores protected with stable non-hygroscopic LaF 3 shells. The heterogeneous nanoparticles can comprise deliquescent alkaline earth halide (SrI 2 , BaI 2 ) cores protected with stable non-hygroscopic (SrF 2 , BaF 2 ) shells.
1. A scintillator material that comprises nanocrystals comprising lead (Pb), iodine (I) and at least one of oxygen (O) and hydrogen (H), wherein the nanocrystals exhibit scintillation in response to ionizing gamma or X-ray radiation at temperatures that include non-cryogenic temperatures including room temperature.
2. The scintillator material of claim 1 wherein the nanocrystals comprise Pb 3 O 2 I 2 that exhibit scintillation in response to the ionizing radiation at temperatures that include non-cryogenic temperatures including room temperature.
3. The scintillator material of claim 2 wherein the nanocrystals have a crystal dimension in the range of about 5 to about 100 nm.
4. The scintillator material of claim 1 wherein the nanocrystals comprise PbIOH wherein Pb, I, O, and H are in generally equiatomic proportions or non-equiatomic variants thereof that exhibit scintillation in response to the ionizing radiation at temperatures that include non-cryogenic temperatures including room temperature.
5. The scintillator material of claim 4 wherein the nanocrystals have a crystal dimension in the range of about 5 to about 100 nm.
6. Scintillator material that comprises microcrystals comprising lead (Pb), iodine (I) and at least one of oxygen (O) and hydrogen (H), grown in a nanocrystal colloidal solution over time to a crystal dimension greater than 0.1 μm, that exhibit scintillation in response to ionizing gamma or X-ray radiation at temperatures that include non-cryogenic temperatures including room temperature.
7. The microcrystals of claim 6 comprising PbIOH wherein Pb, I, O, and H are in generally equiatomic proportions or non-equiatomic variants thereof.
8. The microcrystals of claim 6 having a crystal dimension in the range of about 0.1 μm to about 10 μm depending on the growth time in the nanocrystal colloidal solution.
9. The microcrystals of claim 6 having a crystal dimension of about 2 microns.
10. A gamma or X-ray radiation detection method comprising exposing the scintillator material of claim 1 to ionizing gamma or X-ray radiation and detecting luminescence from the material.
11. A gamma or X-ray radiation detection method comprising exposing the scintillator material of claim 6 to ionizing gamma or X-ray radiation and detecting luminescence from the material.
12. A composite scintillator comprising the nanocrystals of claim 1 disposed in a matrix.
13. A composite scintillator comprising the microcrystals of claim 6 disposed in a matrix.