Electroluminescent ZnS:Mn phosphor and method of making
An electroluminescent phosphor comprising ZnS:Mn is disclosed. Also disclosed are ZnS:Mn electroluminescent phosphors that are free of or substantially free of copper, and/or wherein the phosphor has a D50 size of less than about 5 μm. In addition, a method for preparing a ZnS:Mn phosphor is disclosed, comprising the steps of contacting at least a portion of each of a first solution comprising a Zn 2+ compound, a manganese source, and a second solution comprising a S 2− source agent; and then heating the mixture at a temperature and for a time sufficient to form a phosphor.
1. A method for preparing a ZnS:Mn phosphor comprising the steps of:
(a) contacting at least a portion of a first solution comprising a zinc salt and Mn 2+ with a second solution comprising sodium sulfide to produce a particle, washing and drying the particle, and mixing the dried precipitate with sodium chloride and a manganese compound; and then
(b) heating the particle at a high temperature in air and for a time sufficient to form an orange-yellow emitting phosphor;
wherein no copper is present in any of the first solution, the second solution, or the manganese source.
2. The method of claim 1 , wherein the first solution and the second solution are contacted and then heated prior to contacting with the sodium chloride and manganese compound.
3. The method of claim 1 , wherein the first solution comprises a zinc sulfate.
4. The method of claim 1 , wherein the first solution comprises a manganese sulfate.
5. The method of claim 1 , wherein contacting in a) is performed at a rate sufficiently low to form ZnS:Mn precipitate particles having a D50 of less than about 5 μm.
6. The method of claim 1 , wherein heating comprises annealing at a high temperature in air.
7. The method of claim 1 , wherein contacting comprises reacting the first solution comprising Zn 2+ and Mn 2+ and the second solution comprising sodium sulfide to produce a particle.