IP Library Granted Patent US 7,960,267
Granted Patent B2
US 7,960,267 · App. 12/414,778 · Granted Jun 14, 2011

Method for making a stressed non-volatile memory device

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Quick Facts
Patent No.
US 7,960,267
App. No.
12/414,778
Granted
Jun 14, 2011
Kind
B2
Abstract

A method of making a semiconductor device on a semiconductor layer includes: forming a gate dielectric over the semiconductor layer; forming a layer of gate material over the gate dielectric; etching the layer of gate material to form a select gate; forming a storage layer that extends over the select gate and over a portion of the semiconductor layer; depositing an amorphous silicon layer over the storage layer; etching the amorphous silicon layer to form a control gate; and annealing the semiconductor device to crystallize the amorphous silicon layer.

Claims (73)

1. A method of making a semiconductor device on a semiconductor layer, comprising:

forming a gate dielectric over the semiconductor layer;

forming a layer of gate material over the gate dielectric;

etching the layer of gate material to form a select gate;

forming a storage layer that extends over the select gate and over a portion of the semiconductor layer;

depositing an amorphous silicon layer over the storage layer;

etching the amorphous silicon layer to form a control gate; and

annealing the semiconductor device to crystallize the amorphous silicon layer,

wherein the step of depositing the amorphous silicon layer comprises sputtering silicon and an impurity, wherein the impurity comprises one of group consisting of nickel, gold, aluminum, silver, and palladium.

2. A method of making a semiconductor device on a semiconductor layer, comprising:

forming a gate dielectric over the semiconductor layer;

forming a layer of gate material over the gate dielectric;

etching the layer of gate material to form a select gate;

forming a storage layer that extends over the select gate and over a portion of the semiconductor layer;

depositing an amorphous silicon layer over the storage layer;

etching the amorphous silicon layer to form a control gate;

annealing the semiconductor device to crystallize the amorphous silicon layer; and

forming a capping layer over the semiconductor device, the capping layer formed prior to the step of annealing the semiconductor device.

3. The method of claim 2 , further comprising removing the capping layer from over the semiconductor device after the step of annealing the semiconductor device.

4. The method of claim 2 , wherein forming the capping layer further comprises forming a capping layer that causes a channel region in the semiconductor layer to be laterally tensile stressed.

5. The method of claim 2 , wherein forming the capping layer further comprises forming the capping layer from tensile stressed silicon nitride.

6. The method of claim 1 , wherein annealing the semiconductor device to crystallize the amorphous silicon layer further comprises annealing the semiconductor device at a temperature in a range of 500 to 1100 degrees Celsius.

7. The method of claim 1 , wherein depositing the amorphous silicon layer over the storage layer further comprises depositing the amorphous silicon layer to have a thickness in a range of 50 to 250 nanometers.

8. The method of claim 1 , wherein etching the amorphous silicon layer to form the control gate further comprises etching the amorphous silicon layer to form the control gate having a portion formed over a portion of the select gate.

9. A method of making a semiconductor device on a semiconductor layer, comprising:

forming a gate dielectric over the semiconductor layer;

forming a layer of gate material over the gate dielectric;

etching the layer of gate material to form a select gate;

forming a storage layer that extends over the select gate and over a portion of the semiconductor layer;

depositing an amorphous silicon layer over the storage layer;

etching the amorphous silicon layer to form a control gate; and

annealing the semiconductor device to crystallize the amorphous silicon layer,

wherein forming the storage layer is further characterized by the storage layer comprising nanocrystals.

10. A method of making a semiconductor device on a semiconductor layer, comprising:

forming a gate dielectric over the semiconductor layer;

forming a layer of gate material over the gate dielectric;

etching the layer of gate material to form a select gate;

forming a storage layer that extends over the select gate and over a portion of the semiconductor layer;

depositing an amorphous silicon layer over the storage layer;

etching the amorphous silicon layer to form a control gate; and

annealing the semiconductor device to crystallize the amorphous silicon layer,

wherein the step of depositing the amorphous silicon layer is performed by sputtering.

11. A method of making a semiconductor device on a semiconductor layer, comprising:

forming a gate dielectric over the semiconductor layer;

forming a layer of gate material over the gate dielectric;

etching the layer of gate material to form a select gate;

forming a charge storage layer that extends over the select gate and over a portion of the semiconductor layer;

depositing an amorphous silicon layer over the charge storage layer;

etching the amorphous silicon layer to form a control gate;

forming a liner on the semiconductor device;

forming a capping layer over the liner; and

annealing the semiconductor device to crystallize the amorphous silicon layer.

12. The method of claim 11 , further comprising removing the capping layer from over the semiconductor device after the step of annealing the semiconductor device.

13. The method of claim 11 wherein forming the capping layer further comprises forming the capping layer from tensile stressed silicon nitride.

14. The method of claim 11 , wherein forming the capping layer further comprises depositing a silicon nitride layer having a thickness in a range of 20 to 200 nanometers.

15. The method of claim 11 , wherein annealing the semiconductor device to crystallize the amorphous silicon layer further comprises annealing the semiconductor device at a temperature in a range of 500 to 1100 degrees Celsius.

16. The method of claim 11 , wherein depositing the amorphous silicon layer over the charge storage layer is further characterized by sputtering silicon and an impurity.

17. The method of claim 11 , wherein forming the charge storage layer is further characterized by the charge storage layer comprising nanocrystals.

18. A method of making a semiconductor device on a semiconductor layer, comprising:

forming a gate dielectric over the semiconductor layer;

forming a polysilicon layer over the gate dielectric;

etching the polysilicon layer to form a select gate;

forming a charge storage layer that extends over the select gate and over a portion of the semiconductor layer, wherein the charge storage layer comprises nanocrystals;

depositing an amorphous silicon layer over the charge storage layer;

etching the amorphous silicon layer to form a control gate, the control gate having a portion formed over a portion of the select gate;

forming an insulating liner on the semiconductor device;

forming a tensile stressed silicon nitride layer over the insulating liner;

annealing the semiconductor device to crystallize the amorphous silicon layer; and

removing the tensile stressed silicon nitride layer.

19. The method of claim 18 , wherein:

forming the tensile stressed silicon nitride layer further comprises depositing a silicon nitride layer having a thickness in a range of 20 to 200 nanometers;

annealing the semiconductor device to crystallize the amorphous silicon layer further comprises annealing the semiconductor device at a temperature in a range of 500 to 1100 degrees Celsius; and

depositing the amorphous silicon layer over the charge storage layer is by sputtering.

Assignments (18)
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 11759915 AND REPLACE IT WITH APPLICATION 11759935 PREVIOUSLY RECORDED ON REEL 040925 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE RELEASE OF SECURITY INTEREST. Recorded Feb 17, 2020
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP, B.V. F/K/A FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 052917/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 11759915 AND REPLACE IT WITH APPLICATION 11759935 PREVIOUSLY RECORDED ON REEL 040928 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE RELEASE OF SECURITY INTEREST. Recorded Jan 17, 2020
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 052915/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 11759915 AND REPLACE IT WITH APPLICATION 11759935 PREVIOUSLY RECORDED ON REEL 037486 FRAME 0517. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS. Recorded Dec 10, 2019
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 053547/0421 →
RELEASE OF SECURITY INTEREST Recorded Sep 10, 2019
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 050744/0097 →
CORRECTIVE ASSIGNMENT TO CORRECT THE TO CORRECT THE APPLICATION NO. FROM 13,883,290 TO 13,833,290 PREVIOUSLY RECORDED ON REEL 041703 FRAME 0536. ASSIGNOR(S) HEREBY CONFIRMS THE THE ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS.. Recorded Feb 20, 2019
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: SHENZHEN XINGUODU TECHNOLOGY CO., LTD.
Reel/Frame 048734/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE NATURE OF CONVEYANCE PREVIOUSLY RECORDED AT REEL: 040632 FRAME: 0001. ASSIGNOR(S) HEREBY CONFIRMS THE MERGER AND CHANGE OF NAME. Recorded Sep 21, 2017
From: FREESCALE SEMICONDUCTOR INC.
To: NXP USA, INC.
Reel/Frame 044209/0047 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE PATENTS 8108266 AND 8062324 AND REPLACE THEM WITH 6108266 AND 8060324 PREVIOUSLY RECORDED ON REEL 037518 FRAME 0292. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS. Recorded Feb 1, 2017
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 041703/0536 →
CHANGE OF NAME Recorded Nov 8, 2016
From: FREESCALE SEMICONDUCTOR, INC.
To: NXP USA, INC.
Reel/Frame 040632/0001 →
RELEASE OF SECURITY INTEREST Recorded Nov 7, 2016
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 040928/0001 →
RELEASE OF SECURITY INTEREST Recorded Sep 21, 2016
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP, B.V., F/K/A FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 040925/0001 →
SUPPLEMENT TO THE SECURITY AGREEMENT Recorded Jun 16, 2016
From: FREESCALE SEMICONDUCTOR, INC.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 039138/0001 →
ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS Recorded Jan 13, 2016
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 037518/0292 →
ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS Recorded Jan 12, 2016
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 037486/0517 →
PATENT RELEASE Recorded Dec 21, 2015
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 037354/0793 →
SECURITY AGREEMENT Recorded Nov 6, 2013
From: FREESCALE SEMICONDUCTOR, INC.
To: CITIBANK, N.A., AS NOTES COLLATERAL AGENT
Reel/Frame 031591/0266 →
SECURITY AGREEMENT Recorded Jun 18, 2013
From: FREESCALE SEMICONDUCTOR, INC.
To: CITIBANK, N.A., AS NOTES COLLATERAL AGENT
Reel/Frame 030633/0424 →
SECURITY AGREEMENT Recorded May 19, 2009
From: FREESCALE SEMICONDUCTOR, INC.
To: CITIBANK, N.A.
Reel/Frame 022703/0405 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 31, 2009
From: LOIKO, KONSTANTIN V.; WINSTEAD, BRIAN A.; KIRICHENKO, TARAS A.
To: FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 022475/0649 →