IP Library Granted Patent US 8,084,925
Granted Patent B2
US 8,084,925 · App. 12/427,348 · Granted Dec 27, 2011

Piezoelectric thin film elemental device, sensor and actuator

Assignee: Hitachi Cable, Ltd.
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Quick Facts
Patent No.
US 8,084,925
App. No.
12/427,348
Granted
Dec 27, 2011
Kind
B2
Abstract

A piezoelectric thin film element has a piezoelectric thin film on a substrate, the piezoelectric thin film has a (K 1-x ,Na x )NbO 3 thin film expressed by a compositional formula (K 1-x Na x )NbO 3 (0 <x <1) with a perovskite structure, and a ratio of an out-of-plane directional lattice constant c to an in-plane directional lattice constant a of the thin film is in a range of 0.98 ≦c/a ≦1.01.

Claims (24)

1. A piezoelectric thin film elemental device comprising: a piezoelectric thin film on a substrate, wherein the piezoelectric thin film has a (K 1−x Na x )NbO 3 thin film expressed by a compositional formula (K 1−x Na x )NbO 3 (0<x<1) with a perovskite structure, and a ratio of an out-of-plane directional lattice constant c to an in-plane directional lattice constant a of the thin film is in a range of 0.98≦c/a ≦1.01.

2. The piezoelectric thin film elemental device according to claim 1 , wherein when there are a plurality of (K 1−x Na x )NbO 3 (0<x <1) layers in the piezoelectric thin film, the ratio in at least the thickest same composition layer made of (K 1−x Na x )NbO 3 out of these plurality of layers is within the range of 0.98≦c/a ≦1.01.

3. The piezoelectric thin film elemental device according to claim 1 , wherein the (K 1−x Na x )NbO 3 thin film is preferentially-oriented in a (001) plane direction.

4. The piezoelectric thin film elemental device according to claim 1 , wherein the (K 1−x Na x )NbO 3 thin film is formed by an RF magnetron sputtering technique.

5. The piezoelectric thin film elemental device according to claim 1 , wherein at least one kind of Ta, Li, Sb is added to the (K 1−x Na x )NbO 3 thin film.

6. The piezoelectric thin film elemental device according to claim 1 , wherein the x, being a composition ratio of Na, is in a range of 0.3≦x ≦0.7.

7. The piezoelectric thin film elemental device according to claim 1 , wherein a tensile stress is added to in the piezoelectric thin film, and the ratio of the (K 1−x Na x )NbO 3 thin film is in a range of 0.980≦c/a ≦0.993.

8. The piezoelectric thin film elemental device according to claim 7 , wherein the piezoelectric thin film is provided on a stress relaxation layer with smaller lattice constant than that of the piezoelectric thin film.

9. The piezoelectric thin film elemental device according to claim 1 , wherein a compression stress is generated in the piezoelectric thin film, and the ratio of the (K 1−x Na x )NbO 3 thin film is in a range of 1.004≦c/a ≦1.010.

10. The piezoelectric thin film elemental device according to claim 9 , wherein the piezoelectric thin film is provided on a stress relaxation layer with larger lattice constant than that of the piezoelectric thin film.

11. The piezoelectric thin film elemental device according to claim 1 , wherein an electrode is formed between the substrate and the piezoelectric thin film.

12. The piezoelectric thin film elemental device according to claim 11 , wherein the electrode is formed of Pt or Au.

13. The piezoelectric thin film elemental device according to claim 12 , wherein the electrode formed of Pt is preferentially-oriented in a (111) plane direction.

14. The piezoelectric thin film elemental device according to claim 11 , wherein the electrode is formed by an RF magnetron sputtering technique.

15. The piezoelectric thin film elemental device according to claim 11 , wherein an adhesive layer is provided between the substrate and the electrode.

16. The piezoelectric thin film elemental device according to claim 1 , wherein the substrate is a silicon substrate.

17. The piezoelectric thin film elemental device according to claim 16 , wherein a SiO 2 film is formed on a surface of the silicon substrate.

18. The piezoelectric thin film elemental device according to claim 1 , wherein an electrode is formed on the piezoelectric thin film.

19. An actuator, comprising:

the piezoelectric thin film elemental device according to claim 1 ; and

a voltage applying means for applying voltage to the piezoelectric thin film of the piezoelectric thin film elemental device.

20. A sensor, comprising:

the piezoelectric thin film elemental device according to claim 1 ; and

a voltage detector for detecting voltage generated in the piezoelectric thin film of the piezoelectric thin film elemental device.

Assignments (4)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 19, 2016
From: SCIOCS COMPANY LIMITED
To: SUMITOMO CHEMICAL COMPANY, LIMITED
Reel/Frame 037524/0275 →
CORPORATE SPLIT AND CONFIRMATORY ASSIGNMENT EFFECTIVE APRIL 1, 2015 Recorded Jul 20, 2015
From: HITACHI METALS, LTD.
To: SCIOCS COMPANY LIMITED
Reel/Frame 036134/0081 →
MERGER Recorded Dec 22, 2014
From: HITACHI CABLE, LTD.
To: HITACHI METALS, LTD.
Reel/Frame 034565/0727 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 21, 2009
From: SHIBATA, KENJI; OKA, FUMIHITO; SUENAGA, KAZUFUMI
To: HITACHI CABLE, LTD.
Reel/Frame 022574/0283 →
Priority Claims (1)
JP 2008-147901 · Jun 5, 2008 · national
Continuity (1)
Related Publication 20090302715A1 · Dec 10, 2009