Multifunctional high strength metal composite materials
View Patent ↗A method of producing composites of micro-engineered, coated particulates embedded in a matrix of metal, ceramic powders, or combinations thereof, capable of being tailored to exhibit application-specific desired thermal, physical and mechanical properties to form substitute materials for nickel, titanium, rhenium, magnesium, aluminum, graphite epoxy, and beryllium. The particulates are solid and/or hollow and may be coated with one or more layers of deposited materials before being combined within a substrate of powder metal, ceramic or some combination thereof which also may be coated. The combined micro-engineered nano design powder is consolidated using novel solid-state processes that prevent melting of the matrix and which involve the application of varying pressures to control the formation of the microstructure and resultant mechanical properties.
1. A method of producing a metal matrix composite having at least one desired and controlled application specific property, the method comprising the steps of:
selecting at least one micro-engineered particulate;
mixing the micro-engineered particulate with a powder substrate;
pre-consolidating the mixed powder to form an article or near net shape article;
consolidating the article or near net shape article to produce the metal matrix composite exhibiting the at least one desired and controlled application specific property;
wherein the consolidating step comprises dual mode Dynamic Forging,
said dual mode Dynamic Forging comprising the steps of:
in a first mode, applying a pressure to the near net shape article in a range of 5 to 200 Tons within a heated pressure transmitting media while maintaining a temperature from 100 degrees Centigrade to 1400 degrees Centigrade;
during the first mode, maintaining the temperature below a melting point of a material used to form the micro-engineered particulate, the powder substrate, and any coatings applied thereto;
in a second mode, applying a pressure to the near net shape article in a range of 2 to 2500 Tons within a heated pressure transmitting media while maintaining a temperature range of 100 degrees Centigrade to 1400 degrees Centigrade;
during the second mode, maintaining the temperature below a melting point of a material used to form the micro-engineered particulate, the powder substrate, and any coatings applied thereto;
controlling a rate of applied pressure during the first and second modes by means selected from the group consisting of:
integrated hydraulic valves, electrical relays and mechanical limit switches;
controlling a pressurization rate in a range of 2″/min to 120″/min; and,
controlling a decompression rate so as not to exceed 120″/min.
2. The method of claim 1 , wherein the at least one desired and controlled application specific property is selected from the group consisting of: radiation hardening, X-ray shielding, neutron shielding, combined radiation shielding, EMI shielding, corrosion resistance, modulus enhancement, reduced density, thermal expansion variation, thermal conductivity variation, higher tensile strength, increased specific strength, and improved surface finish.
3. The method of claim 1 , wherein the powder substrate is selected from the group consisting of hollow microspheres, solid microspheres/particles, and a combination of hollow microspheres and solid microspheres/particles.
4. The method of claim 1 , wherein a material for the powder substrate is selected from the group consisting of metals, alloys, elements from Groups 1 through 15 of the Periodic Table of Elements, polymers and ceramics.
5. The method of claim 1 , wherein the micro-engineered particulate is encapsulated with one or more coatings, a material for said coatings selected from the group consisting of metals, alloys, elements, and ceramics.
6. The method of claim 1 , further comprising the step of mixing the micro-engineered particulate with at least one non-coated powder substrate comprising a material selected from the group consisting of metals, elements from Groups 1 through 15 of the Periodic Table of Elements, alloys, polymers and ceramics.
7. The method of claim 1 , wherein the micro-engineered particulate comprises a combination of hollow microspheres and solid microspheres/particles encapsulated with one or more coatings.
8. The method of claim 1 , further comprising the step of mixing the micro-engineered particulate with at least one coated powder substrate, a material for a coating for said coated powder substrate selected from the group consisting of metals, alloys, elements and ceramics.
9. The method of claim 1 , further comprising the step of mixing the micro-engineered particulate with at least one coated powder substrate and at least one non-coated powder substrate.
10. The method of claim 1 , wherein the pre-consolidating step comprises a pressing technique selected from the group consisting of: pressing in a hard die, Cold Isostatic Pressing, and metal injection molding.
11. The method of claim 1 , wherein the consolidating step comprises a technique to increase a density and introduce a deformation of the near net shape article, said technique selected from the group consisting of: dual mode Dynamic Forging, P/M forging, Hot Isostatic Pressing, Laser Processing, sintering, pulse sintering, ARCAM, Spark Plasma Sintering (SPS), forging in a granular bed of particles, Metal Injection Molding, Laser-engineered Net Shaping, conventional forging in a mold, direct consolidation of powders by the use of rapid pressure molding, plasma process, thermal spray process, E-Beam Process, Liquid Phase Sintering with pressurization, Liquid Phase Sintering without pressurization, vacuum hot pressing, Electro-consolidation, extrusion and ECAP extrusion.
12. The method of claim 1 , further including the steps of: post processing the metal matrix composite through a technique selected from the group consisting of: coating, extruding, machining, polishing, anodizing, heat treating; and, machining the metal matrix composite into an article having a desired defined shape.