Methods of forming an amorphous silicon thin film
View Patent ↗A method for forming an amorphous silicon thin film is disclosed. In some embodiments, a method includes loading a substrate into a reaction chamber; and conducting a plurality of deposition cycles on the substrate. Each of at least two of the cycles includes: supplying a silicon precursor to the reaction chamber during a first time period; applying radio frequency power to the reaction chamber at least partly during the first time period; stopping supplying of the silicon precursor and applying of the radio frequency power during a second time period between the first time period and an immediately subsequent deposition cycle; and supplying hydrogen plasma to the reaction chamber during a third time period between the second time period and the immediately subsequent deposition cycle. The method allows formation of an amorphous silicon film having an excellent step-coverage and a low roughness at a relatively low deposition temperature.
1. A method for forming an amorphous silicon thin film on a substrate, the method comprising:
loading a substrate into a reaction chamber; and
conducting a plurality of deposition cycles on the substrate, at least two of the cycles, each comprising:
supplying a silicon precursor to the reaction chamber during a first time period;
supplying hydrogen plasma to the reaction chamber at least partly during the first time period; and
stopping supplying of the silicon precursor and the hydrogen plasma to the reaction chamber during a second time period between the first time period and an immediately subsequent deposition cycle.
2. The method of claim 1 , wherein the at least two of the cycles further comprise supplying a purge gas to the reaction chamber at least partly during the second time period.
3. The method of claim 1 , wherein the silicon precursor comprises a silane compound.
4. The method of claim 3 , wherein the silane compound comprises a chlorosilane compound.
5. The method of claim 4 , wherein the chlorosilane compound comprises chlorosilane (SiH 3 Cl), dichlorosilane (SiH 2 Cl 2 ), trichlorosilane (SiHCl 3 ), hexachlorodisilane (Si 2 H 6 ), and silicon tetrachloride (SiCl 4 ).
6. The method of claim 1 , wherein supplying the hydrogen plasma comprises:
supplying hydrogen gas to the reaction chamber; and
applying radio frequency power to the reaction chamber while supplying the hydrogen gas, thereby generating hydrogen plasma in situ.
7. The method of claim 1 , wherein supplying the hydrogen plasma comprises supplying remotely generated hydrogen plasma to the reaction chamber.
8. The method of claim 1 , wherein the at least two of the cycles further comprise supplying hydrogen plasma to the reaction chamber during a third time period between the second time period and the immediately subsequent deposition cycle, wherein no silicon precursor is supplied to the reaction chamber during the third time period.
9. The method of claim 8 , wherein supplying the hydrogen plasma during the third time period comprises:
supplying hydrogen gas to the reaction chamber; and
applying radio frequency power to the reaction chamber while supplying the hydrogen gas, thereby generating hydrogen plasma in situ.
10. The method of claim 8 , wherein the at least two of the cycles further comprise stopping supplying of the hydrogen plasma to the reaction chamber during a fourth time period between the third time period and the immediately subsequent deposition cycle.
11. The method of claim 10 , wherein the at least two of the cycles further comprise supplying a purge gas to the reaction chamber at least partly during the fourth time period.
12. The method of claim 1 , wherein conducting the plurality of deposition cycles comprises conducting the at least one deposition cycle at a reaction chamber temperature of about 300° C. or lower.
13. A method of making an electronic device, the method comprising:
providing a substrate including a trench including surfaces;
depositing amorphous silicon on one or more of the surfaces of the trench of a substrate by the method of claim 1 ;
filling the trench with silicon dioxide; and
performing a heat treatment to convert the amorphous silicon to silicon oxide.
14. The method of claim 13 , wherein filling the trench comprises performing a spin-on-glass process.
15. An electronic device comprising a silicon dioxide layer formed by the method of claim 13 .
16. A method for forming an amorphous silicon thin film on a substrate, the method comprising:
loading a substrate into a reaction chamber; and
conducting a plurality of deposition cycles on the substrate, at least two of the cycles, each comprising
supplying a silicon precursor to the reaction chamber during a first time period;
applying radio frequency power to the reaction chamber at least partly during the first time period;
stopping supplying of the silicon precursor and applying of the radio frequency power during a second time period between the first time period and an immediately subsequent deposition cycle; and
supplying hydrogen plasma to the reaction chamber during a third time period between the second time period and the immediately subsequent deposition cycle.
17. The method of claim 16 , wherein no silicon precursor is supplied to the reaction chamber during the third time period.
18. The method of claim 17 , wherein no hydrogen gas is supplied to the reaction chamber during the first time period.
19. The method of claim 16 , wherein the at least two of the cycles further comprise supplying a purge gas to the reaction chamber at least partly during the second time period.
20. The method of claim 16 , wherein the silicon precursor comprises a chlorosilane compound.
21. The method of claim 20 , wherein the chlorosilane compound comprises chlorosilane (SiH 3 Cl), dichlorosilane (SiH 2 Cl 2 ), trichlorosilane (SiHCl 3 ), hexachlorodisilane (Si 2 H 6 ), and silicon tetrachloride (SiCl 4 ).
22. The method of claim 16 , wherein supplying the hydrogen plasma comprises:
supplying hydrogen gas to the reaction chamber; and
applying radio frequency power to the reaction chamber while supplying the hydrogen gas, thereby generating hydrogen plasma in situ.
23. The method of claim 16 , wherein supplying the hydrogen plasma comprises supplying remotely generated hydrogen plasma to the reaction chamber.
24. The method of claim 16 , wherein the at least two of the cycles further comprise supplying a purge gas to the reaction chamber during a fourth time period between the third time period and the immediately subsequent deposition cycle.
25. The method of claim 16 , wherein conducting the plurality of deposition cycles comprises conducting the at least one deposition cycle at a reaction chamber temperature of about 300° C. or lower.
26. A method of making an electronic device, the method comprising:
providing a substrate including a trench including surfaces;
depositing amorphous silicon on one or more of the surfaces of the trench of a substrate by the method of claim 16 ;
filling the trench with silicon dioxide; and
performing a heat treatment to convert the amorphous silicon to silicon oxide.
27. The method of claim 26 , wherein filling the trench comprises performing a spin-on-glass process.
28. An electronic device comprising: a silicon dioxide layer formed by the method of claim 26 .