IP Library Granted Patent US 8,848,338
Granted Patent B2
US 8,848,338 · App. 12/438,235 · Granted Sep 30, 2014

Electric double layer capacitor

Inventors: Hiroyuki Norieda (Tokyo, JP); Kotaro Kobayashi (Tokyo, JP)
Assignee: W. L. Gore & Associates, Co., Ltd.
H01G11/24H01G11/32H01G11/42Y02T10/7022H01G9/038Y02E60/13
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Quick Facts
Patent No.
US 8,848,338
App. No.
12/438,235
Granted
Sep 30, 2014
Kind
B2
Abstract

Disclosed is an electric double layer capacitor comprising a polarizable electrode layer that contains an activated carbon, a conductive agent, and a binder, wherein an external specific surface area of the activated carbon (defined as a specific surface area calculated from a nitrogen absorption isotherm by a t-plot method by excluding micropores of pore diameter smaller than 20 angstroms), per unit volume of the polarizable electrode layer, lies within a range of 450 to 800 m 2 /cm 3 , and a volume based on inter-particle interstices per unit volume of the polarizable electrode layer lies within a range of 0.05 to 0.12 cm 3 /cm 3 . The electric double layer capacitor according to the present invention is particularly suited to large current, quick discharge applications.

Claims (26)

1. An electric double layer capacitor comprising a polarizable electrode layer that contains an activated carbon, a conductive agent, and a binder, wherein an external specific surface area of said activated carbon (defined as a specific surface area calculated from a nitrogen absorption isotherm by a t-plot method by excluding micropores of pore diameter smaller than 20 angstroms), per unit volume of said polarizable electrode layer, lies within a range of 450 to 800 m 2 /cm 3 , and a volume based on inter-particle interstices per unit volume of said polarizable electrode layer lies within a range of 0.05 to 0.12 cm 3 /cm 3 .

2. An electric double layer capacitor electrode as claimed in claim 1 , wherein a relative particle quantity by volume in a mode diameter of a particle size distribution in said activated carbon lies within a range of 10 to 30%.

3. An electric double layer capacitor electrode as claimed in claim 2 , wherein particles contained within a range of ±30% of said mode diameter are 30 to 60% in terms of the relative particle quantity by volume.

4. An electric double layer capacitor electrode as claimed in claim 1 , wherein the external specific surface area of said activated carbon lies within a range of 1000 to 2000 m 2 /g.

5. An electric double layer capacitor electrode as claimed in claim 1 , wherein said activated carbon is formed from a plant-derived natural material.

6. An electric double layer capacitor electrode as claimed in claim 5 , wherein said plant-derived natural material is a coconut shell.

7. An electric double layer capacitor electrode as claimed in claim 1 , wherein said conductive agent is carbon black and is added in an amount not greater than 5% by mass with respect to the total mass of said polarizable electrode layer.

8. An electric double layer capacitor electrode as claimed in claim 1 , further comprising an electrolytic solution which contains polypropylene carbonate as a solvent in an amount not less than 50% by mass with respect to the mass of said electrolytic solution.

9. An electric double layer capacitor electrode as claimed in claim 1 , wherein capacitance measured under large-current discharge conditions is smaller by 35% or less than the capacitance measured under small-current discharge conditions that are the same as said large-current discharge conditions except that discharge current is 5 mA/cm 2 , said large-current discharge conditions being defined as follows:

Charge: Constant current, constant voltage method

Discharge: Constant current method

Charge current: 5 mA/cm 2

Discharge current: 200 mA/cm 2

Charge voltage: 2.7 V

Charge time: 60 minutes

Discharge voltage: 0 V

Discharge temperature: 25° C.

10. An electric double layer capacitor electrode as claimed in claim 1 , wherein capacitance measured under low-temperature discharge conditions is smaller by 10% or less than the capacitance measured under normal-temperature discharge conditions that are the same as said low-temperature discharge conditions except that discharge temperature is 25° C., said low-temperature discharge conditions being defined as follows:

Charge: Constant current, constant voltage method

Discharge: Constant current method

Charge current: 5 mA/cm 2

Discharge current: 5 mA/cm 2

Charge voltage: 2.7 V

Charge time: 60 minutes

Discharge voltage: 0 V

Discharge temperature: −30° C.

Assignments (2)
CHANGE OF NAME Recorded Jul 16, 2014
From: JAPAN GORE-TEX, INC.
To: W. L. GORE & ASSOCIATES, CO., LTD.
Reel/Frame 033338/0935 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 15, 2009
From: NORIEDA, HIROYUKI; KOBAYASHI, KOTARO
To: JAPAN GORE-TEX, INC.
Reel/Frame 022548/0331 →
Priority Claims (1)
JP 2006-237562 · Sep 1, 2006 · national
Continuity (1)
Related Publication 20100220429A1 · Sep 2, 2010