Rubber composition and pneumatic tire using the same
This invention provides a rubber composition highly balancing flexibility at a low temperature and a low rolling resistance, which is formed by compounding a low-molecular weight conjugated diene-based polymer (B) having at least one functional group, an aromatic vinyl compound content of less than 5% by mass and a weight average molecular weight as measured without terminating by modification through a gel permeation chromatography and converted to polystyrene of not less than 2,000 but less than 150,000 and a filler (C) into a high-molecular weight rubber component (A) having a weight average molecular weight as measured without terminating by modification through a gel permeation chromatography and converted to polystyrene of not less than 150,000.
1. A rubber composition characterized by compounding a polymer (B) comprising conjugated diene and having at least one functional group, an aromatic vinyl compound content of less than 5% by mass and a weight average molecular weight as measured without terminating by modification through a gel permeation chromatography and converted to polystyrene of not less than 2,000 but less than 150,000 and a filler (C) into a rubber component (A) having a weight average molecular weight as measured without terminating by modification through a gel permeation chromatography and converted to polystyrene of not less than 150,000,
wherein the polymer (B) is produced by (1) (co)polymerizing monomers with a polymerization initiator to produce a (co)polymer having a polymerization active site and then modifying the polymerization active site with a modifying agent, or (2) (co)polymerizing monomers with a polymerization initiator having a functional group.
2. A rubber composition formed by compounding a polymer (B) comprising conjugated diene and having at least one functional group, an aromatic vinyl compound content of less than 5% by mass and a weight average molecular weight as measured without terminating by modification through a gel permeation chromatography and converted to polystyrene of not less than 2,000 but less than 150,000 into a rubber component (A) composed of at least one of natural rubber and synthetic diene-based rubbers having a weight average molecular weight as measured without terminating by modification through a gel permeation chromatography and converted to polystyrene of not less than 150,000, characterized in that bubbles are contained in a rubber matrix of the rubber composition,
wherein the polymer (B) is produced by (1) (co)polymerizing monomers with a polymerization initiator to produce a (co)polymer having a polymerization active site and then modifying the polymerization active site with a modifying agent, or (2) (co)polymerizing monomers with a polymerization initiator having a functional group.
3. A rubber composition according to claim 2 , wherein the polymer (B) has a weight average molecular weight as measured without terminating by modification through a gel permeation chromatography and converted to polystyrene of 2,000 to 50,000.
4. A rubber composition according to claim 2 , wherein the polymer (B) has a weight-average molecular weight as measured without terminating by modification through a gel permeation chromatography and converted to polystyrene of not less than 50,000 but less than 150,000.
5. A rubber composition according to claim 3 , wherein a chloroform extractability as extracted with chloroform for 48 hours after vulcanization is not less than 60% by mass based on a total mass of the polymer (B) compounded.
6. A rubber composition according to claim 4 , wherein a chloroform extractability as extracted with chloroform for 48 hours after vulcanization is not more than 60% by mass based on a total mass of the polymer (B) compounded.
7. A rubber composition according to claim 1 , wherein the polymer (B) is included in an amount of 1 to 60 parts by mass based on 100 parts by mass of the rubber component (A).
8. A rubber composition according to claim 1 , wherein the polymer (B) has a vinyl bond content in a conjugated diene compound portion of 5 to 80% by mass.
9. A rubber composition according to claim 1 , wherein the polymer (B) is a butadiene homopolymer or a styrene-butadiene copolymer.
10. A rubber composition according to claim 1 , wherein the functional group of the polymer (B) is at least one selected from the group consisting of a tin-containing functional group, a silicon-containing functional group and a nitrogen-containing functional group.
11. A rubber composition according to claim 10 , wherein the polymer (B) is one formed by modifying a polymerization active site thereof with a tin-containing compound, a silicon-containing compound or a nitrogen-containing compound.
12. A rubber composition according to claim 11 , wherein the tin-containing compound or the silicon-containing compound is a modification terminator represented by the following formula (I):
R 1 a ZX b (I)
[wherein R 1 is independently selected from the group consisting of an alkyl group having a carbon number of 1 to 20, a cycloalkyl group having a carbon number of 3 to 20, an aryl group having a carbon number of 6 to 20 and an aralkyl group having a carbon number of 7 to 20 ; Z is tin or silicon; X is independently chlorine or bromine; a is 0-3 and b is 1-4 provided that a +b =4].
13. A rubber composition according to claim 10 , wherein the nitrogen-containing functional group is selected from the group consisting of a substituted amino group represented by the following formula (II):
[wherein R 2 is independently an alkyl group having a carbon number of 1 to 12, a cycloalkyl group or an aralkyl group] and a cyclic amino group represented by the following formula (III):
[wherein R 3 is an alkylene group having 3-16 methylene groups, a substituted alkylene group, an oxyalkylene group or an N-alkylamino-alkylene group].
14. A rubber composition according to claim 10 , wherein the silicon-containing functional group is a functional group derived from a hydrocarbyloxy silane.
15. A rubber composition according to claim 1 , wherein the polymer (B) has a weight average molecular weight as measured without terminating by modification through a gel permeation chromatography and converted to polystyrene of not less than 20,000 but less than 150,000.
16. A rubber composition according to claim 15 , wherein the polymer (B) has a weight average molecular weight as measured without terminating by modification through a gel permeation chromatography and converted to polystyrene of 50,000 to 120,000.
17. A rubber composition according to claim 3 , wherein the polymer (B) has a weight average molecular weight as measured without terminating by modification through a gel permeation chromatography and converted to polystyrene of 2,000 to 30,000.
18. A rubber composition according to claim 4 , wherein the polymer (B) has a weight average molecular weight as measured without terminating by modification through a gel permeation chromatography and converted to polystyrene of 50,000 to 120,000.
19. A rubber composition according to claim 1 , which further contains 20 to 100 parts by mass of the filler (C) based on 100 parts by mass of the rubber component (A).
20. A rubber composition according to claim 19 , which contains 30 to 90 parts by mass of the filler (C) based on 100 parts by mass of the rubber component (A).
21. A rubber composition according to claim 1 , wherein the filler (C) is carbon black and/or silica.
22. A rubber composition according to claim 1 , which contains not less than 10 parts by mass of silica based on 100 parts by mass of the rubber component (A).
23. A rubber composition according to claim 1 , wherein the rubber component (A) comprises at least one selected from the group consisting of an aromatic vinyl compound-conjugated diene compound copolymer (D), a conjugated diene compound polymer (E) and natural rubber.
24. A rubber composition according to claim 23 , wherein the aromatic vinyl compound-conjugated diene compound copolymer (D) is a styrene-butadiene copolymer.
25. A rubber composition according to claim 23 , wherein the conjugated diene compound polymer (E) is a butadiene homopolymer.
26. A rubber composition according to claim 23 , wherein each of the aromatic vinyl compound-conjugated diene compound copolymer (D) and the conjugated diene compound polymer (E) has at least one functional group.
27. A rubber composition according to claim 26 , wherein the functional group in the aromatic vinyl compound-conjugated diene compound copolymer (D) and the conjugated diene compound polymer (E) is at least one selected from the group consisting of a tin-containing functional group, a silicon-containing functional group and a nitrogen-containing functional group.
28. A rubber composition according to claim 1 , wherein a total amount of the polymer (B) and a softening agent (F) compounded is 5 to 80 parts by mass based on 100 parts by mass of the rubber component (A).
29. A rubber composition according to claim 28 , wherein the total amount of the polymer (B) and the softening agent (F) compounded is 5 to 60 parts by mass based on 100 parts by mass of the rubber component (A).
30. A rubber composition according to claim 28 , wherein a proportion of the polymer (B) in total of the polymer (B) and the softening agent (F) is not less than 20% by mass.
31. A rubber composition according to claim 2 , wherein a bubble fraction in the rubber composition is 5 to 35%.
32. A rubber composition according to claim 31 , which further contains a foaming agent (G) into the rubber component (A).
33. A rubber composition according to claim 32 , which is formed by vulcanizing and foaming after compounded with 1 to 20 parts by mass of the foaming agent (G) based on 100 parts by mass of the rubber component (A).
34. A rubber composition according to claim 32 , wherein the foaming agent (G) is at least one selected from the group consisting of azodicarbonamide, dinitrosopenta-methylenetetramine, azobisisobutylonitrile, toluenesulfonyl hydrazide and a toluenesulfonyl hydrazide derivative.
35. A rubber composition according to claim 1 , which is a rubber composition for a tire.
36. A pneumatic tire characterized by using a rubber composition as claimed in claim 35 in a tire member.
37. A. pneumatic tire according to claim 36 , wherein the tire member is at least one selected from the group consisting of a tread portion, a sidewall portion, a bead filler portion, a body ply skim portion and a reinforcing rubber portion for a run-flat tire.
38. A pneumatic tire characterized by using a rubber composition as claimed in claim 36 in at least a ground contact region of a tread portion.
39. A pneumatic tire according to claim 38 , which is a studless tire.
40. A pneumatic tire according to claim 39 , which is a studless tire for a passenger car.