IP Library Granted Patent US 8,399,772
Granted Patent B2
US 8,399,772 · App. 12/439,919 · Granted Mar 19, 2013

Control of carbon nanostructure growth in an interconnect structure

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Quick Facts
Patent No.
US 8,399,772
App. No.
12/439,919
Granted
Mar 19, 2013
Kind
B2
Abstract

An interconnect structure on a substrate is provided. The interconnect structure comprises electrically conductive interconnect elements on at least two interconnect levels on or above a substrate level. In the interconnect structure of the invention, at least one electrically conductive via connects a first interconnect element on one interconnect level or on the substrate level to a second interconnect element on a different interconnect level. The via extends in a via opening of a first dielectric layer and comprises an electrically conductive via material that contains electrically conductive cylindrical carbon nanostructures. At least one cover-layer segment reaches into a lateral extension of the via opening and defines a via aperture that is small enough to prevent a penetration of the carbon nanostructures through the via aperture. This structure enhances control of carbon nanostructure growth in a height direction during fabrication of the interconnect structure.

Claims (29)

1. An interconnect structure on a substrate, with electrically conductive interconnect elements on at least two interconnect levels on or above a substrate level, wherein

at least one electrically conductive via connects a first interconnect element on one interconnect level or on the substrate level to a second interconnect element on a different interconnect level, the via extending in a via opening of a first dielectric layer and comprising an electrically conductive via material that contains electrically conductive cylindrical carbon nanostructures, and wherein

at least one cover-layer segment reaches into a lateral extension of the via opening and defines a via aperture over the via opening, wherein the via aperture is small enough to prevent a penetration of the carbon nanostructures through the via aperture.

2. The interconnect structure of claim 1 , wherein the via material comprises carbon nanotubes or carbon nanowires, and wherein the via aperture is smaller than or equal to twice an outer cylinder diameter of a single carbon nanotube or carbon nanowire.

3. The interconnect structure of claim 1 , wherein the via material comprises carbon nanotubes or carbon nanowires, and wherein the via aperture is smaller than or equal to an outer cylinder diameter of a single carbon nanotube or carbon nanowire.

4. The interconnect structure of claim 1 , wherein the at least one cover-layer segment is arranged at a first via end of the via, which is more distant from the substrate than a second via end of the via.

5. The interconnect structure of claim 1 , wherein the via material in the via opening is seated on a catalytic layer, which is suitable for supporting growth of the carbon nanostructures.

6. The interconnect structure of claim 1 , wherein the cover-layer segment is made of a dielectric material.

7. The interconnect structure of claim 1 , wherein the cover-layer segment is arranged on a dielectric liner.

8. The interconnect structure of claim 1 , wherein the cover-layer segment covers a top section of a sidewall of the via opening and laterally abuts to a dielectric liner that is arranged between the second interconnect element and the first dielectric layer outside the via opening.

9. The interconnect structure of claim 1 , wherein the cover-layer segment forms a section of a cover layer that covers a bottom face of a first interconnect opening in the first dielectric layer, which interconnect opening is filled by the second interconnect element.

10. The interconnect structure of claim 1 , wherein the via material comprises carbon nanotubes or carbon nano wires, which have an orientation of their longitudinal axis in a height direction pointing from the first to the second interconnect element.

11. A method for fabricating an interconnect structure that has a via connecting a first electrically conductive interconnect element on one interconnect level or on the substrate level and a second interconnect element on a different interconnect level, comprising the steps of:

providing a substrate with the first interconnect element on one interconnect level or on the substrate level;

depositing a first dielectric layer on the first interconnect element;

fabricating, in the dielectric layer, a via opening that reaches to the first interconnect element;

fabricating a cover-layer segment on the first dielectric layer that reaches into a lateral extension of the via opening and defines a via aperture over the via opening;

fabricating an electrically conductive via material that contains electrically conductive cylindrical carbon nanostructures in the via opening; and

fabricating the second interconnect element that contacts the via;

wherein the via aperture is made small enough to prevent a penetration of the carbon nanostructures through the via aperture.

12. The method of claim 11 , comprising, before the step of fabricating the via material in the via opening, a step of fabricating a catalytic layer, which is suitable for supporting growth of the carbon nanostructures, on a bottom face of the via opening.

13. The method of claim 11 , wherein the step of fabricating a cover-layer segment on the first dielectric layer comprises: non-conformally depositing a cover layer on a top face of the first dielectric layer.

14. The method of claim 12 , wherein the cover layer is selectively deposited, thus avoiding a deposition of the cover-layer material on a bottom face of the via opening.

15. The method of claim 12 , comprising a step of removing cover-layer material, which has been deposited during the step of non-conformally depositing the cover layer, from a bottom face of the via opening.

16. The method of claim 11 , comprising a step of removing the cover layer from the top face of the first dielectric layer outside the via opening.

17. The method of claim 11 , wherein the deposition of the via material in the via opening is sustained in height until the via material abuts to the cover-layer segment.

18. The method of claim 11 , which is performed as a part of a single- or dual-damascene process.

19. A method for fabricating an integrated-circuit device, comprising a step of fabricating an interconnect structure by means of the method of claim 11 .

20. The interconnect structure of claim 1 , wherein the via aperture is smaller than a lateral dimension of the via opening.

Assignments (12)
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 12298143 PREVIOUSLY RECORDED ON REEL 042985 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY AGREEMENT SUPPLEMENT. Recorded Oct 22, 2019
From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 051029/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 12298143 PREVIOUSLY RECORDED ON REEL 039361 FRAME 0212. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY AGREEMENT SUPPLEMENT. Recorded Oct 22, 2019
From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 051029/0387 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 12298143 PREVIOUSLY RECORDED ON REEL 038017 FRAME 0058. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY AGREEMENT SUPPLEMENT. Recorded Oct 22, 2019
From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 051030/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 12298143 PREVIOUSLY RECORDED ON REEL 042762 FRAME 0145. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY AGREEMENT SUPPLEMENT. Recorded Oct 22, 2019
From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 051145/0184 →
RELEASE OF SECURITY INTEREST Recorded Sep 10, 2019
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 050745/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 12681366 PREVIOUSLY RECORDED ON REEL 038017 FRAME 0058. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY AGREEMENT SUPPLEMENT. Recorded May 9, 2017
From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 042985/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 12681366 PREVIOUSLY RECORDED ON REEL 039361 FRAME 0212. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY AGREEMENT SUPPLEMENT. Recorded May 9, 2017
From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 042762/0145 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 12092129 PREVIOUSLY RECORDED ON REEL 038017 FRAME 0058. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY AGREEMENT SUPPLEMENT. Recorded Jul 14, 2016
From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 039361/0212 →
SECURITY AGREEMENT SUPPLEMENT Recorded Mar 7, 2016
From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 038017/0058 →
EMPLOYMENT AGREEMENT--DUTY TO ASSIGN INVENTIONS TO COMPANY Recorded Feb 5, 2013
From: GOSSET, LAURENT
To: PHILIPS SEMICONDUCTORS CROLLES
Reel/Frame 029759/0539 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 31, 2013
From: TORRES, JOAQUIN
To: NXP B.V.; ST MICROELECTRONICS (CROLLES 2) SAS
Reel/Frame 029735/0150 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 28, 2009
From: KONINKLIJKE PHILIPS ELECTRONICS N.V.
To: NXP B.V.
Reel/Frame 022597/0832 →