Polyaniline/carbon black composite and preparation method thereof
View Patent ↗A polyaniline/carbon black composite and a preparation method thereof are disclosed The polyaniline/carbon black composite is formed by polyaniline covering carbon black and is with core-shell structure while the polyaniline/carbon black composite contains 10˜30 wt. % of carbon black. The preparation method of polyaniline/carbon black composite includes the steps of: disperse carbon black into solution to form carbon black solution, add aniline into the carbon black solution to form a first solution; dissolve ammonium persulfate into acid aqueous solution to form a second solution; add the second solution to the first solution, after reaction, through filtering and grinding to produce polyaniline/carbon black composite.
1. A preparation method of polyaniline/carbon black composite comprising the steps of:
dispersing carbon black into a solution to form a carbon black solution;
adding aniline into the carbon black solution to form a first solution;
dissolving ammonium persulfate into an acid aqueous solution to form a second solution; and
adding the second solution to the first solution for reaction, and then through filtering and grinding to produce polyaniline/carbon black composite;
wherein the polyaniline/carbon composite has a core-shell structure; and
the weight of the carbon black is 20-30% of the total weight of the polyaniline/carbon black composite.
2. The method as claimed in claim 1 , wherein in the step of dispersing carbon black into solution to form carbon black solution, the solution is mixture of a dispersing agent, ethanol solution and acid.
3. The method as claimed in claim 1 , wherein the step of dispersing carbon black into solution to form carbon black solution further comprising a step of ultrasound vibration.
4. The method as claimed in claim 1 , wherein in the step of dissolving ammonium persulfate into acid aqueous solution to form a second solution, the acid aqueous solution is hydrochloric acid solution.
5. The method as claimed in claim 1 , wherein reaction time of the step of adding the second solution to the first solution for reaction, and then through filtering and grinding to produce polyaniline/carbon black composite ranges from 1 to 5 hours.
6. The method as claimed in claim 5 , wherein optimum reaction time is 2 hours.
7. The method as claimed in claim 1 , wherein in the step of adding the second solution to the first solution for reaction, and then through filtering and grinding to produce polyaniline/carbon black composite, an acid rinsing step is further included between filtering and grinding.
8. The method as claimed in claim 7 , wherein hydrochloric acid is used in the acid rinsing step.