FLAME RETARDANT COMPOSITION COMPRISING DENDRITIC POLYMERS
The invention relates to a product as obtained by reaction of: a) At least one polyol selected from the group consisting of a linear or branched, trihydric or tetrahydric alcohol and a linear pentahydric or hexahydric alcohol; b) At least one melamine comprising compound; and c) At least one dendritic polymer substituted by hydroxy groups; and to flame retardant compositions comprising these products.
1 . A product obtained by reaction of:
a) At least one polyol selected from the group consisting of a linear or branched trihydric or tetrahydric alcohol, a linear pentahydric or hexahydric alcohol, a linear or cyclic C 4 -C 6 aldose and a linear or cyclic C 4 -C 6 ketose;
b) At least one melamine comprising compound; and
c) At least one dendritic polymer substituted by hydroxy groups.
2 . A product according to claim 1 obtained by reaction of:
a) A linear or branched trihydric or tetrahydric alcohol;
b) A melamine compound selected from the group consisting of melamine phosphate, melamine pyrophosphate and melamine polyphosphate; and
c) At least one dendritic polymer substituted by hydroxy groups.
3 . A product according to claim 1 obtained by reaction of:
a) A tetrahydric alcohol selected from the group consisting of pentaerythritol and dipentaerythritol;
b) A melamine compound selected from the group consisting of melamine phosphate, melamine pyrophosphate and melamine polyphosphate; and
c) A dendritic polymer of the polyester or polyamide type substituted by hydroxy groups.
4 . A product according to claim 1 obtained by reaction of:
a) A tetrahydric alcohol selected from the group consisting of pentaerythritol and dipentaerythritol;
b) A melamine compound selected from the group consisting of melamine phosphate and melamine pyrophosphate; and
c) A dendritic polymer of the polyester or polyamide type substituted by hydroxy groups.
5 . A product according to claim 1 obtained by reaction of:
a) Pentaerythritol;
b) Melamine phosphate; and
c) A dendritic polyester formed from an initiator compound selected from the group consisting of trimethylolpropane, pentaerythritol and ethoxylated pentaerythritol and chain-extending dimethylolpropionic acid or a polycondensation product of a cyclic carboxylic acid anhydride and diisopropanolamine.
6 . A flame retardant composition which comprises
A) A product obtained by reaction of:
a) At least one polyol selected from the group consisting of a linear or branched trihydric or tetrahydric alcohol, a linear pentahydric or hexahydric alcohol, a linear or cyclic C 4 -C 6 aldose and a linear or cyclic C 4 -C 6 ketose;
b) At least one melamine comprising compound; and
c) At least one dendritic polymer substituted by hydroxy groups; and
B) A polymer substrate.
7 . A flame retardant composition according to claim 6 , which comprises
A) A product obtained by reaction of
a) A tetrahydric alcohol selected from the group consisting of pentaerythritol and dipentaerythritol;
b) A melamine compound selected from the group consisting of melamine phosphate and melamine pyrophosphate; and
c) A dendritic polymer of the polyester or polyamide type substituted by hydroxy groups, and
B) A thermoplastic polymer substrate.
8 . A flame retardant composition according to claim 6 , which comprises
A) A product obtained by reaction of
a) Pentaerythritol;
b) Melamine phosphate; and
c) A dendritic polyester formed from an initiator compound selected from the group consisting of trimethylolpropane, pentaerythritol and ethoxylated pentaerythritol and chain-extending dimethylolpropionic acid or a polycondensation product of a cyclic carboxylic acid anhydride and diisopropanolamine; and
B) A thermoplastic polymer substrate selected from the group consisting of polyethylene, polypropylene and high impact polystyrene.
9 . A flame retardant composition according to claim 6 , which comprises d) further additives selected from the group consisting of polymer stabilizers and additional flame-retardants.
10 . Formed articles comprising the flame retardant composition according to claim 6 .
11 . A process for the preparation of a melamine-based flame retardant composition by reaction of a polyol and a melamine comprising compound,
characterized in that
a) At least one polyol selected from the group consisting of a linear or branched trihydric or tetrahydric alcohol, a linear pentahydric or hexahydric alcohol, a linear or cyclic C 4 -C 6 aldose and a linear or cyclic C 4 -C 6 ketose;
b) At least one melamine comprising compound; and
c) At least one dendritic polymer substituted by hydroxy groups;
are reacted in the presence of polymers.
12 . A process according to claim 11 , characterized in that components a), b) and c) are reacted in the presence of thermoplastic polymers by reactive extrusion methods.
13 . A process according to claim 12 , characterized in that components a), b) and c) are reacted in the presence of thermoplastic polymers in a twin-screw extruder.
14 . A process for imparting flame retardancy to a polymer, which process comprises the incorporation of a product according to claim 1 into the polymer.