Tire innerliner
A method of preparing a green tire innerliner, the method comprising mixing one or more vulcanizable rubbery polymers, less than 0.75 parts by weight zinc oxide, less than 0.75 parts by weight magnesium oxide, and less than 0.75 parts by weight sulfur, per 100 parts by weight rubber, to form a vulcanizable mixture and extruding the mixture to form a green tire innerliner.
1. A method of preparing a green tire innerliner, the method comprising:
mixing a rubber composition including a polymeric component and a curative to form a vulcanizable composition of matter, where the polymeric component consists of a halogenated poly(isobutylene-co-isoprene) copolymer and optionally one or more additional elastomers selected from the group consisting of natural rubber and poly(styrene-co-butadiene), where the curative includes sulfur, magnesium oxide, and zinc oxide, where the vulcanizable composition of matter comprises less than 0.75 parts by weight zinc oxide, per 100 parts by weight rubber, less than 0.75 parts by weight magnesium oxide, per 100 parts by weight rubber, and less than 0.75 parts by weight sulfur, per 100 parts by weight rubber, and where the total weight of the sulfur, zinc oxide, and magnesium oxide is less than 1.2 parts by weight per 100 parts by weight rubber; and
extruding the vulcanizable composition of matter to form a green tire innerliner.
2. The method of claim 1 , where the halogenated poly(isobutylene-co-isoprene) copolymer comprises from about 1 to about 3 percent by weight halogen, based upon the total weight of the halogenated poly(isobutylene-co-isoprene) copolymer.
3. The method of claim 1 , where the vulcanizable composition includes less than 0.55 parts by weight sulfur per 100 parts by weight rubber.
4. The method of claim 1 , where the vulcanizable composition includes less than 0.5 parts by weight magnesium oxide per 100 parts by weight rubber.
5. The method of claim 1 , further comprising the step of building a green tire by employing the green tire innerliner.
6. The method of claim 5 , further comprising the step of curing the green tire.
7. The method of claim 1 , where the vulcanizable composition further comprises a filler.
8. The method of claim 7 , where the vulcanizable composition comprises from about 30 to about 100 parts by weight of filler per hundred parts rubber.
9. The method of claim 1 , where the polymeric component comprises from about 5 to about 40 percent by weight natural rubber, based upon the total weight of the polymeric component.
10. The method of claim 1 , where the vulcanizable composition includes from about 0.05 to about 1.1 parts by weight total curative per 100 parts rubber.
11. The method of claim 1 , where the halogenated poly(isobutylene-co-isoprene) is brominated poly(isobutylene-co-isoprene).
12. A method of preparing a green tire innerliner, the method comprising:
mixing a rubber composition including a polymeric component and a curative to form a vulcanizable composition of matter, where the polymeric component consists of a halogenated poly(isobutylene-co-isoprene) copolymer, and optionally one or more additional elastomers selected from the group consisting of natural rubber, and poly(styrene-co-butadiene), and where the curative includes sulfur, magnesium oxide, and zinc oxide, where the molar ratio of the total sulfur plus magnesium oxide plus zinc oxide to the moles of crosslinkable pairs on the halogenated poly(isobutylene-co-isoprene) copolymer is at least 0.05:1 up to 1.8:1; and
extruding the vulcanizable composition of matter to form a green tire innerliner.
13. The method of claim 12 , where the molar ratio of the total sulfur plus magnesium oxide plus zinc oxide to the moles of crosslinkable pairs on the halogenated poly(isobutylene-co-isoprene) copolymer is at least 0.1:1 up to 1.5:1.
14. The method of claim 12 , where the vulcanizable composition includes from about 0.1 to about 0.75 parts by weight magnesium oxide per 100 parts rubber.