Binder composition, slurry for electrodes, electrode and nonaqueous electrolyte secondary battery
The present invention aims at providing slurry for electrodes having advantageous homogeneity and stability, an electrode having advantageous homogeneous thickness and density, and further, a nonaqueous electrolyte secondary battery having small variability in battery properties. In the present invention, slurry for electrodes is produced by using the binder composition used for manufacturing a nonaqueous electrolyte secondary battery wherein polymers for binding active materials are dissolved or dispersed in organic solvent or water, and a total sum of content ratios of monomer and oligomer is 300 ppm or less.
1. A slurry for electrodes comprising,
a binder composition and active materials capable of reversibly inserting and releasing lithium ion by applying electric potential in an electrolyte, said binder composition comprises a polymer for binding active materials that is dissolved or dispersed in water or organic solvent, and
a sum of contents ratio of following (A) or (B) is 300 ppm or less,
(A) a monomer to form repeated structure included in said polymer by polymerization,
(B) an oligomer of reaction product of said monomer having a weight-average molecular weight 3,000 or less.
2. The slurry as set forth in claim 1 , wherein said polymer in the binder composition is dissolved or dispersed in an organic solvent, and its content ratio is 4 to 13 mass %.
3. The slurry as set forth in claim 1 , wherein said polymer in the binder composition has a content ratio of said monomer (A) of 50 ppm or less.
4. The slurry as set forth in claim 1 , wherein said polymer in the binder composition has a breaking elongation of said polymer of 100 to 3000%.
5. The slurry as set forth in claim 1 , wherein said polymer in the binder composition has a breaking strength of said polymer of 2 MPa or more.
6. The slurry as set forth in claim 1 , wherein said polymer in the binder composition is acrylic polymer.
7. The slurry as set forth in claim 1 , wherein said polymer in the binder composition has a weight-average molecular weight of said polymer is 50,000 to 1,000,000.
8. An electrode comprising a collector and an active material layer formed by coating and drying a slurry for electrodes, said slurry comprises a binder composition and active materials capable of reversibly inserting and releasing lithium ion by applying electric potential in an electrolyte, wherein the binder composition comprises a polymer for binding active materials that is dissolved or dispersed in water or organic solvent, and
a sum of contents ratio of following (A) or (B) is 300 ppm or less,
(A) a monomer to form repeated structure included in said polymer by polymerization,
(B) an oligomer of reaction product of said monomer having a weight-average molecular weight of 3,000 or less.
9. A nonaqueous electrolyte secondary battery comprising an electrode wherein said electrode of claim 8 is at least one of a positive electrode and a negative electrode.
10. An electrode comprising an active material layer formed by coating and drying a slurry for electrodes and a collector, wherein the slurry for electrodes comprises a binder composition and active materials, and the binder composition comprises a polymer for binding active materials that is dissolved or dispersed in water or organic solvent, and
a sum of contents ratio of following (A) or (B) is 300 ppm or less,
(A) a monomer to form repeated structure included in said polymer by polymerization,
(B) an oligomer of reaction product of said monomer having a weight-average molecular weight 3,000 or less.