Multi-layer polyester container and method of producing the same
A multi-layer polyester container comprising inner and outer layers of a polyester resin and at least one intermediate layer of a functional resin or a functional resin composition, wherein a difference of tan δ of the inner polyester layer at 80° C. and 60° C. is 0.035 or less in the measurement of the dynamic viscoelasticity (DMS) thereof at 0.5 Hz. Even when the functional resin or the functional resin composition having a large draw stress is used as an intermediate layer, therefore, excellent transparency is obtained while effectively exhibiting the function such as barrier property possessed by the functional resin or the functional resin composition.
1. A multi-layer polyester container comprising inner and outer layers of a polyester resin and at least one intermediate layer of a functional resin, wherein a difference of tan δ of said inner polyester layer at 80° C. and 60° C. is 0.035 or less in the measurement of the viscoelasticity thereof at 0.5 Hz, wherein the multi-layer polyester container is produced by biaxially stretch-blow molding a multi-layer preform which comprises inner and outer layers of a polyester resin and at least one intermediate layer of a functional resin, wherein in conducting the biaxial stretch-blow molding, the multi-layer preform is heated at a temperature of 105 to 120° C., and the multi-layer preform is internally heated by using a heating body heated at 300 to 600° C. and/or hot air of 150 to 220° C.
2. The multi-layer polyester container according to claim 1 , wherein said functional resin has a maximum value of draw stress of 50 N or more when an injection-molded plate thereof having a thickness of 1.5 mm is drawn at 115° C.
3. The multi-layer polyester container according to claim 1 , wherein said functional resin contains an ethylene/vinyl alcohol copolymer or a polymetaxylylene adipamide as a base resin.
4. The multi-layer polyester container according to claim 1 , wherein said functional resin contains a clay dispersed therein.
5. The multi-layer polyester container according to claim 1 , wherein said functional resin is a cyclic olefin resin.
6. A method of producing a multi-layer polyester container by biaxially stretch-blow molding a multi-layer preform which comprises inner and outer layers of a polyester resin and at least one intermediate layer of a functional resin, wherein in conducting the biaxial stretch-blow molding, the multi-layer preform is heated at a temperature of 105 to 120° C., and the multi-layer preform is internally heated by using a heating body heated at 300 to 600° C. and/or hot air of 150 to 220° C.
7. The method of producing a multi-layer polyester container according to claim 6 , wherein said functional resin has a maximum value of draw stress of 50 N or more when an injection-molded plate thereof having a thickness of 1.5 mm is drawn at 115° C.
8. The method of producing a multi-layer polyester container according to claim 6 , wherein a difference of tan δ of the inner polyester layer at 80° C. and 60° C. is 0.035 or less in the measurement of the viscoelasticity thereof at 0.5 Hz.
9. The method of producing a multi-layer polyester container according to claim 6 , wherein the preform is heated uniformly.
10. The method of producing a multi-layer polyester container according to claim 6 , wherein the entire preform is heated.