Coated cutting tools having a platinum group metal concentration gradient and related processes
The present disclosure is directed to cutting tools. The disclosed cutting tools may have a wear resistant coating on a substrate. The substrate may have hard particles cemented in a binder phase. The binder may have a near-surface concentration gradient of at least one platinum group element and/or rhenium. Processes for producing cutting tools are also disclosed.
1. A cutting tool comprising:
a substrate comprising hard particles and a binder, the binder comprising a near-surface platinum group metal concentration gradient; and
at least one wear resistant coating on at least a portion of the substrate.
2. The cutting tool of claim 1 , wherein the platinum group metal comprises rhenium, ruthenium, osmium, rhodium, iridium, palladium, platinum, or combinations of any thereof.
3. The cutting tool of claim 1 , wherein the hard particles comprise metal carbide, metal nitride, metal carbonitride, metal boride, metal silicide, metal oxide, or combinations of any thereof.
4. The cutting tool of claim 3 , wherein the metal comprising the hard particles comprises titanium, chromium, vanadium, zirconium, hafnium, tantalum, molybdenum, niobium, tungsten, or combinations of any thereof.
5. The cutting tool of claim 1 , wherein the binder comprises cobalt, nickel, iron, alloys of any thereof, or combinations of any thereof.
6. The cutting tool of claim 1 , wherein the at least one wear resistant coating comprises a metal carbide, a metal nitride, a metal carbonitride, a metal boride, a metal silicide, a metal oxide, or a combination of any thereof.
7. The cutting tool of claim 6 , wherein the metal comprising the wear resistant coating comprises titanium, chromium, vanadium, zirconium, hafnium, tantalum, molybdenum, niobium, tungsten, aluminum, boron, silicon, or combinations of any thereof.
8. The cutting tool of claim 1 , wherein the near-surface platinum group metal concentration gradient comprises from 10 weight percent to 100 weight percent platinum group metal on a total binder weight basis at the substrate surface and zero to background levels of platinum group metal in a bulk region of the substrate.
9. The cutting tool of claim 1 , wherein the near-surface platinum group metal concentration gradient comprises from 10 weight percent to 100 weight percent platinum group metal on a total binder weight basis at the substrate surface and decreases with depth to zero or background levels of platinum group metal.
10. The cutting tool of claim 1 , wherein the near-surface platinum group metal concentration gradient comprises from 10 weight percent to 100 weight percent platinum group metal on a total binder weight basis at the substrate surface and decreases logarithmically with depth to zero or background levels of platinum group metal in a bulk region of the substrate.
11. The cutting tool of claim 1 , wherein the at least one wear resistant coating has the characteristics of a coating applied by physical vapor deposition.
12. The cutting tool of claim 1 , wherein the at least one wear resistant coating has the characteristics of a coating applied by chemical vapor deposition.
13. The cutting tool of claim 1 , wherein the at least one wear resistant coating has a thickness of from 1 to 30 micrometers.
14. The cutting tool of claim 1 , wherein the at least one wear resistant coating has a thickness of from 1 to 10 micrometers.
15. The cutting tool of claim 1 , wherein the at least one wear resistant coating has a thickness of from 2 to 6 micrometers.
16. The cutting tool of claim 1 , wherein the at least one wear resistant coating comprises two or more layers.
17. The cutting tool of claim 1 , wherein the cutting tool is selected from a group consisting of a burr, an endmill, a drill, and an insert.
18. The cutting tool of claim 1 , wherein the platinum group metal comprises rhenium, ruthenium, osmium, rhodium, iridium, or combinations of any thereof.
19. A cutting tool comprising:
a cemented carbide substrate comprising tungsten carbide particles and a cobalt binder, the binder comprising a near-surface platinum group metal concentration gradient of 10 weight percent to 100 weight percent platinum group metal on a total binder weight basis at the substrate surface and logarithmically decreasing with depth to background levels of platinum group metal;
wherein the platinum group metal is selected from the group consisting of ruthenium, osmium, rhodium, iridium, palladium, platinum, and combinations of any thereof; and
at least one wear resistant coating on at least a portion of the substrate, the coating comprising a metal carbide, metal nitride, metal carbonitride, metal boride, metal silicide, metal oxide, or combination of any thereof, of a group IIIA, group IVA, group IVB, group VB, or group VIIB metal.
20. The cutting tool of claim 19 , wherein the cutting tool is selected from a group consisting of a burr, an endmill, a drill, and an insert.
21. The cutting tool of claim 19 , wherein the platinum group metal comprises rhenium, ruthenium, osmium, rhodium, iridium, or combinations of any thereof.