Rubber composition containing silica reinforcement and functionalized polybutadiene rubber and tires having a component thereof
This invention relates to a silica reinforcement-containing rubber composition which contains a functionalized polybutadiene rubber to promote a relatively low hysteretic loss to thereby enhance its desirability for tire sidewall and subtread applications in a sense of advantageously promoting reduced tire rolling resistance without significantly compromising various other desirable tire performance parameters.
1. A pneumatic tire having at least one of an outer sidewall rubber layer and subtread rubber layer of a rubber composition comprised of, based on parts by weight per 100 parts by weight of rubber (phr):
(A) Conjugated diene-based elastomers comprised of:
(1) about 20 to about 80 phr of a siloxy-aldimine functionalized cis 1,4-polybutadiene elastomer having amine functionality in its molecular chain and an end terminating group reactive with hydroxyl groups contained on said precipitated silica provided by a terminating compound containing a siloxy and an aldimine group represented by the general formula (II):
RCH═N(CH 2 ) x Si(OR 1 ) y R 2 3-y (II)
wherein R represents a phenyl group; R 1 and R 2 may be the same or different and each independently represents a group having 1 to 18 carbon atoms selected from an alkyl, a cycloalkyl, an allyl, or an aryl, wherein at least one R 1 group is an ethyl radical; x is an integer from 1 to 20; and y is an integer from 1 to 3,
2) about 20 to about 80 phr of at least one additional conjugated diene based elastomer comprised of at least one of polymers of at least one of isoprene and 1,3-butadiene and copolymers of styrene and at least one of isoprene and 1,3-butadiene, and
(B) about 30 to about 70 phr of rubber reinforcing filler comprised of rubber reinforcing carbon black and precipitated silica as:
(1) about 20 to about 60 phr of said rubber reinforcing carbon black, and
(2) about 20 to about 60 phr of said precipitated silica, and
(C) coupling agent for said precipitated silica having a moiety reactive with hydroxyl groups on said precipitated silica and another different moiety interactive with said elastomer(s).
2. The tire of claim 1 wherein said subtread rubber layer is exclusive of cord reinforcement.
3. The tire of claim 1 wherein said end terminating compound containing a siloxy and an aldimine group is represented by the general formula (IV):
RCH═N(CH 2 ) x Si(OR 1 ) 2 CH 3 (IV)
where R is a phenyl group and where x is an integer in a range of from 1 to 20 and
where R 1 is an alkyl group and at least one of R 1 is an ethyl group.