Method for forming electrical traces on substrate
View Patent ↗A method for forming electrical traces on a substrate includes the steps of: providing a substrate; printing an ink pattern using an ink on the substrate, the ink including a aqueous medium containing silver ions and a heat sensitive reducing agent; heating the ink pattern to reduce silver ions into silver particles thereby forming an semi-finished traces; and forming a metal overcoat on the semi-finished traces by electroless plating thereby obtaining patterned electrical traces.
1. A method for forming electrical traces on a substrate, the method comprising:
printing an ink pattern on the substrate using an ink, the ink comprising an aqueous medium containing silver ions and a heat sensitive reducing agent, the heat sensitive reducing agent being capable of reacting with the silver ions at a temperature in the range from approximately 50° C. to approximately 250° C., the aqueous medium comprising water, a water-soluble silver salt, and a water-soluble organic solvent, the weight percent of the water-soluble organic solvent being in the range from 4%-50%, the molar concentration of the silver salt being in the range from 0.02 mol/L-2 mol/L, and the weight percent of the heat sensitive reducing agent being in the range from approximately 0.5% to approximately 0.87%;
heating the ink pattern to reduce silver ions into silver particles thereby forming semi-finished traces on the substrate; and
forming a metal overcoat on the semi-finished traces by electroless plating thereby obtaining patterned electrical traces on the substrate.
2. The method of claim 1 , wherein the substrate is treated with a solution containing potassium hydroxide and water, prior to the step of printing the ink pattern.
3. The method of claim 1 , wherein the substrate is ultrasonically processed in a mixture of acetone, tert-butyl alcohol, and deionized water for 5 to 15 minutes prior to the step of printing the ink pattern.
4. The method of claim 1 , wherein the heat sensitive reducing agent is one of polyvinylalcohol and polyvinylpyrrolidone, and a combination thereof.
5. The method of claim 1 , wherein the water soluble-silver salt is selected from the group consisting of silver nitrate, silver sulfate, silver acetate, and silver citrate.
6. The method of claim 5 , wherein the aqueous medium further comprises a surfactant.
7. The method of claim 5 , wherein the aqueous medium further comprises an adhesive agent, and the adhesive agent is methyl cellulose.
8. The method of claim 1 , wherein the ink pattern is heated for about 3 minutes to about 30 minutes.
9. The method of claim 1 , wherein a heating temperature in the heating step is in the range from approximately 50° C. to approximately 100° C.
10. The method of claim 1 , wherein the substrate with the semi-finished traces formed thereon is dried at 60° C.-70° C. after the heating step.
11. The method of claim 1 , wherein the material of the metal overcoat is copper.
12. The method of claim 11 , wherein the substrate formed with the semi-finished traces is dipped into an electroless plating solution in the electroless plating step, and the electroless plating solution contains copper sulfate, potassium sodium tartrate, ethylene diamine tetraacetic acid disodium salt, formaldehyde and methanol.
13. The method of claim 1 , wherein the material of the metal overcoat is nickel or silver.