Electrode with plural active material layers with different amounts of conductive material for rechargeable lithium battery and method for manufacturing the same and rechargeable lithium battery including the electrode
An electrode for a rechargeable lithium battery and method of manufacturing a rechargeable lithium battery including the electrode is disclosed. In one embodiment, the electrode includes i) a current collector, ii) a first electrode composition layer provided on a surface of the current collector and iii) a second electrode composition layer farther than the first electrode composition layer from the current collector. Further, each of the first and second electrode composition layers comprises an active material and a conductive material, and wherein the amount of the conductive material of the first electrode composition layer is different from that of the conductive material of the second electrode composition layer. The electrode further includes an additional first electrode composition layer farther than the second electrode composition layer from the current collector and an additional second electrode composition layer farther than the additional first electrode composition layer from the current collector.
1. An electrode for a rechargeable lithium battery, the electrode comprising:
a current collector; a first electrode composition layer formed directly on a first surface of the current collector; and
a second electrode composition layer farther than the first electrode composition layer from the current collector,
wherein each of the first and second electrode composition layers comprises an active material and a conductive material, wherein the amount of the conductive material of the first electrode composition layer is different from the amount of the conductive material of the second electrode composition layer, wherein the weight of the conductive material of the first electrode composition layer is greater than the weight of the active material of the first electrode composition layer, and
wherein the second electrode composition layer further comprises about 4 wt % to about 10 wt % of a binder,
wherein the first electrode composition layer is further formed at least directly on a second surface of the current collector, wherein the first and second surfaces are opposing each other, and wherein the second electrode composition layer is formed directly on opposing surfaces of the first electrode composition layer farther than the first electrode composition layer from the current collector,
wherein the electrode further comprises:
an additional first electrode composition layer formed on opposing surfaces of the second electrode composition layer farther than the second electrode composition layer from the current collector, wherein the additional first electrode composition layer has the same wt % of conductive material as the first electrode composition layer; and
an additional second electrode composition layer formed on opposing surfaces of the additional first electrode composition layer farther than the additional first electrode composition layer from the current collector, wherein the additional second electrode composition layer has the same wt % of conductive material as the second electrode composition layer.
2. The electrode of claim 1 , wherein the amount of the conductive material of the first electrode composition layer is greater than the amount of the conductive material of the second electrode composition layer.
3. The electrode of claim 1 , wherein the second electrode composition layer comprises a higher amount of the active material than the amount of the conductive material.
4. The electrode of claim 1 , wherein the current collector is porous.
5. The electrode of claim 1 , wherein the current collector is mesh-type.
6. The electrode of claim 1 , wherein the electrode is a positive electrode.
7. The electrode of claim 6 , wherein the second electrode composition layer comprises about 80 wt % to about 95 wt % of the active material and about 1 wt % to about 10 wt % of the conductive material.
8. The electrode of claim 6 , wherein the first electrode composition layer has a thickness of about 5 μm to about 200 μm, and wherein the second electrode composition layer has a thickness of about 100 μm to about 500 μm.
9. The electrode of claim 6 , wherein the first electrode composition layer comprises about 40 wt % to about 60 wt % of the conductive material and about 20 wt % to about 35 wt % of the positive active material.
10. The electrode of claim 9 , wherein the first electrode composition layer further comprises a binder, and wherein the first electrode composition layer comprises about 5 wt % to about 40 wt % of the binder.
11. The electrode of claim 6 , wherein the positive electrode is thicker than about 300 μm.
12. The electrode of claim 11 , wherein the positive electrode has a thickness of about 300 μm to about 1200 μm.
13. The electrode of claim 6 , wherein the positive electrode has an average porosity of about 30% or more, and wherein the average porosity represents the total volume ratio of inside pores of the positive electrode.
14. The electrode of claim 13 , wherein the average porosity of the positive electrode is from about 30% to about 50%.
15. A rechargeable lithium battery, comprising:
a positive electrode;
a negative electrode; and
a separator interposed between the positive and negative electrodes;
wherein at least one of the positive and negative electrodes comprises:
a current collector;
a first electrode composition layer formed directly on a first surface of the current collector; and
a second electrode composition layer farther than the first electrode composition layer from the current collector,
wherein each of the first and second electrode composition layers comprises an active material and a conductive material, wherein the amount of the conductive material of the first electrode composition layer is different from the amount of the conductive material of the second electrode composition layer, and wherein the weight of the conductive material of the first electrode composition layer is greater than the weight of the active material of the first electrode composition layer, and
wherein the second electrode composition layer further comprises about 4 wt % to about 10 wt % of a binder,
wherein the first electrode composition layer is further formed at least directly on a second surface of the current collector, wherein the first and second surfaces are opposing each other, and wherein the second electrode composition layer is formed directly on opposing surfaces of the first electrode composition layer farther than the first electrode composition layer from the current collector,
wherein the at least one of the positive and negative electrodes further comprises:
an additional first electrode composition layer formed on opposing surfaces of the second electrode composition layer farther than the second electrode composition layer from the current collector, wherein the additional first electrode composition layer has the same wt % of conductive material as the first electrode composition layer; and
an additional second electrode composition layer formed on opposing surfaces of the additional first electrode composition layer farther than the additional first electrode composition layer from the current collector, wherein the additional second electrode composition layer has the same wt % of conductive material as the second electrode composition layer.
16. The rechargeable lithium battery of claim 15 , wherein the amount of the conductive material of the first electrode composition layer is greater than the amount of the conductive material of the second electrode composition layer.
17. The rechargeable lithium battery of claim 15 , wherein the at least one electrode is the positive electrode.