Organic electroluminescent device and method of manufacturing the same
An organic electroluminescent device and its method of manufacturing are provided. The organic electroluminescent device may include a rear substrate, an organic electroluminescent unit including a first electrode, an organic film, and a second electrode stacked on a surface of the rear substrate. It may also include a front substrate joined to the rear substrate to seal an internal space in which the organic electroluminescent unit is disposed. It may also include a porous oxide layer composed of a porous silica and a metal compound on a lower surface thereof. A device constructed according to the present invention may have excellent adsorption of moisture and oxygen, thereby increasing the life span of the device.
1. A method of manufacturing an organic electroluminescent device, comprising:
forming an organic electroluminescent (EL) unit comprising a first electrode, an organic film, and a second electrode;
coating a composition comprising a silicon alkoxide and a polar solvent onto a surface of a second substrate that will be an interior surface followed by thermal treatment to form a porous silica layer;
coating a sealant onto at least a side of each of a first substrate and the second substrate corresponding to outside the organic EL unit; and
joining the first substrate and the second substrate.
2. The method of claim 1 , wherein the composition of the coating step further comprises one or more selected from the group consisting of alkaline metal salt, alkaline earth metal salt, metal halide, metal sulfate, and metal perchlorate.
3. The method of claim 2 ,
wherein the alkaline metal salt comprises one or more selected from the group consisting of potassium acetate, potassium nitrate, sodium acetate, and sodium nitrate;
wherein the alkaline earth metal salt comprises one or more selected from the group consisting of calcium acetate, calcium nitrate, barium acetate, and barium nitrate;
wherein the metal sulfate comprises one or more selected from the group consisting of Li 2 SO 4 , Nai 2 SO 4 , CaSO 4 , MgSO 4 , CoSO 4 , Ga 2 (SO 4 ) 3 , Ti(SO 4 ) 2 , and NiSO 4 ;
the metal halide comprises one or more selected from the group consisting of CaCl 2 , MgCl 2 , SrCl 2 , YCl 2 , CuCl 2 , CsF, TaF 5 , NbF 5 , LiBr, CaBr 3 , CeBr 4 , SeBr 2 , VBr 2 , MgBr 2 , BaI 2 , or MgI 2 , and the metal perchlorate is Ba(ClO 4 ) 2 , and Mg(ClO 4 ) 2 .
4. The method of claim 1 , wherein the composition of the coating step further comprises an acrylic resin.
5. The method of claim 1 , further comprising after the step of coating a composition, coating on the porous silica layer a solvent and a second composition comprising one or more selected from the group consisting of alkaline metal salt, alkaline earth metal salt, metal halide, metal sulfate, and metal perchlorate.
6. The method of claim 1 , further comprising after the step of coating the composition, coating a third composition comprising a metal halide and a solvent on the porous silica layer.
7. The method of claim 6 , wherein the metal halide comprises one or more material selected from the group consisting of CaCl 2 , MgCl 2 , SrCl 2 , YCl 2 , CuCl 2 , CsF, TaF 5 , NbF 5 , LiBr, CaBr 3 , CeBr 4 , SeBr 2 , VBr 2 , MgBr 2 , BaI 2 , and MgI 2 .
8. The method of claim 1 , wherein the silicon alkoxide comprises one or more selected from the group consisting of tetraethylorthosilicate and tetramethylorthosilicate.
9. The method of claim 1 , wherein the composition of the coating step further comprises about 0.1 to about 0.9 moles of a catalyst for facilitating a hydrolysis reaction, for each mole of the silicon alkoxide.
10. The method of claim 1 , wherein the thermal treatment is performed at a temperature of about 100 to about 550° C.
11. The method of claim 1 , wherein the porous silica layer comprises a silica frame and a plurality of absorption holes.
12. The method of claim 1 , wherein the porous silica layer has a thickness in the range of 0.1 to 12 μm.