Method for applying a diffusion barrier interlayer for high temperature components
A coated substrate and a method of forming a diffusion barrier coating system between a substrate and a MCrAl coating, including a diffusion barrier coating deposited onto at least a portion of a substrate surface, wherein the diffusion barrier coating comprises a nitride, oxide or carbide of one or more transition metals and/or metalloids and a MCrAl coating, wherein M includes a transition metal or a metalloid, deposited on at least a portion of the diffusion barrier coating, wherein the diffusion barrier coating restricts the inward diffusion of aluminum of the MCrAl coating into the substrate.
1. A method of forming a diffusion barrier coating system between a substrate and coating comprising:
depositing a diffusion barrier coating onto at least a portion of a substrate surface, wherein said diffusion barrier coating comprises at least two compositionally different layers,
(i) a first layer having a composition selected from the group consisting of TaN, WN, Ti—Si—N, Zr—Si—N, Ta—Si—N, and Ti—Si—C—N; and
(ii) a second layer having at least 50 at % aluminum selected from the group consisting of Al 2 O 3 , Al, and AlN, wherein said second layer is distal from said substrate surface,
wherein said diffusion barrier coating layers are deposited by vapor deposition by providing a precursor gas including an element selected from the group consisting of O, N, C, and silicon at a flow rate of 1 sccm to 100 sccm, and providing a target including an element selected from the group consisting of tantalum, titanium, tungsten, zirconium, silicon, and aluminum and operating said target at a power in the range of 0.5 kW to 5kW for a deposition time in the range of 5 minutes to 100 minutes; and subsequently
depositing [M a Cr b X c ] y Al (100-y) coating distinct from the second layer of the diffusion barrier coating on at least a portion of said diffusion barrier coating, wherein
M is selected from the group consisting of iron, cobalt, nickel, manganese, tungsten, and molybdenum,
X is selected from the group consisting of a carbon and phosphorous, and
“y” is in the range of 85 wt % to 95 wt % of the total composition, “a” is in the range of 70 wt % to 90 wt % of “y”, “b” is in the range of 5 wt % to 25 wt % of “y”, and “c” is in the range of 0.1 wt % to 5 wt % of “y”,
wherein said [M a Cr b X c ] y Al (l00-y) coating is deposited by vapor deposition by utilizing a first target including chromium and at least one transition metal selected from the group consisting of iron, cobalt, nickel, manganese, tungsten, and molybdenum and a second target including aluminum, wherein said second target is operated at a power P 1 that is in the range of 20 to 40 percent of a power P 2 said first target is operated, for a deposition time in the range of 100 minutes to 600 minutes, and
wherein said [M a Cr b X c ] y Al (l00-y) coating exhibits a weight gain of up to 0.0006 g/cm 2 and a total loss in aluminum of 80 percent or less when thermally cycled at temperatures of 1010° C. for 50 minutes and force air cooling to room temperature for 10 minutes, for up to 2015 cycles.
2. The method of claim 1 , wherein said diffusion barrier coating includes at least two layers and said layers exhibit a thickness in the range of 0.1 μm to 10 μm individually.
3. The method of claim 1 , wherein said diffusion barrier coating exhibits a thickness in the range of 0.1 μm to 10 μm in combination.
4. A method of forming a diffusion barrier coating system between a substrate and a coating comprising:
depositing a diffusion barrier coating onto at least a portion of a substrate surface, wherein said diffusion barrier coating comprises at least two compositionally different layers,
(i) a first layer having a composition selected from the group consisting of Ti—Si—N, Zr—Si—N, Ta—Si—N, and Ti—Si—C—N; and
(ii) a second layer having at least 50 at % aluminum selected from the group consisting of Al 2 O 3 , Al, and AlN, wherein said second layer is distal from said substrate surface,
wherein said diffusion barrier coating layers are deposited by vapor deposition by providing a precursor gas including an element selected from the group consisting of O, N, C, and silicon at a flow rate of 1 sccm to 100 sccm, and providing a target including an element selected from the group consisting of tantalum, titanium, zirconium, silicon, and aluminum and operating said target at a power in the range of 0.5 kW to 5 kW for a deposition time in the range of 5 minutes to 100 minutes; and subsequently
depositing [MCr] y Al (100-y) coating distinct from the second layer of the diffusion barrier coating on at least a portion of said diffusion barrier coating, wherein
M is selected from the group consisting of iron, cobalt, nickel, manganese, tungsten, and molybdenum, and
“y” is in the range of 85 wt % to 95 wt % of the total composition,
wherein said [MCr] y Al (l00-y) coating is deposited by vapor deposition by utilizing a first target including chromium and at least one transition metal selected from the group consisting of iron, cobalt, manganese, tungsten and molybdenum, and a second target including aluminum, wherein said second target is operated at a power P 1 that is in the range of 20 to 40 percent of a power P 2 said first target is operated, for a deposition time in the range of 100 minutes to 600minutes, and
wherein said [MCr] y Al (l00-y) coating exhibits a weight gain of up to 0.0006 g/cm 2 and a total loss in aluminum of 80 percent or less when thermally cycled at temperatures of 1010° C. for 50 minutes and force air cooling to room temperature for 10 minutes, for up to 2015 cycles.