Glass substrate and method for manufacturing the same
A glass substrate chemically strengthened, includes a primary surface that has a compressive stress layer formed in an uppermost surface layer thereof. The compressive stress layer is configured to enhance strength of the glass substrate due to a compressive stress generated in the compressive stress layer. The compressive layer consists of a layer of a potassium ion concentration equal to or less than 5000 parts per million (ppm).
1. A method for manufacturing a glass substrate for a cover glass for protecting a display screen of a mobile terminal device, comprising the steps of:
chemically strengthening the glass substrate by immersing the glass substrate in heated molten salt containing potassium nitrate such that ions of the glass substrate are ion exchanged for potassium ions of the molten salt at a temperature equal to or less than a glass transition point of the glass substrate; and
removing 1 to 3 μm of an ion exchange layer formed in an uppermost surface layer of a primary surface of the glass substrate, by etching each surface of the glass substrate after the step of chemically strengthening;
wherein a thickness of the glass substrate is 0.5 to 0.7 mm prior to the chemical strengthening step; and
wherein the primary surface of the glass substrate has a potassium ion concentration equal to or less than 5000 parts per million (ppm) after the 1 to 3 μm of the ion exchange layer is removed.
2. The method according to claim 1 ;
wherein the etching is implemented in a wet manner using etching solution that contains at least one of hydrofluoric acid, hexafluorosilicic acid, and buffered hydrofluoric acid.
3. The method according to claim 1 ;
wherein, in the step of chemically strengthening the glass substrate, the heated molten molten salt also contains sodium nitrate.
4. The method according to claim 1 ;
wherein the ion exchange layer has a potassium ion concentration more than 5000 ppm before the 1 to 3 μm of the ion exchange layer is removed.
5. A method for manufacturing a glass substrate for a cover glass for protecting a display screen of a mobile terminal device, comprising the steps of:
preparing a glass substrate having a primary surface that is a hot-formed surface;
chemically strengthening the glass substrate by immersing the glass substrate in heated molten salt containing potassium nitrate such that ions of the glass substrate are ion exchanged for potassium ions of the molten salt at a temperature equal to or less than a glass transition point of the glass substrate; and
removing 1 to 3 μm of an uppermost surface layer of the primary surface of the glass substrate so as to completely eliminate from the primary surface an ion exchange layer of a potassium ion concentration more than 5000 ppm, by etching each surface of the glass substrate after the step of chemically strengthening;
wherein a thickness of the glass substrate is 0.5 to 0.7 mm prior to the chemical strengthening step.
6. The method according to claim 5 ;
wherein the etching is implemented in a wet manner using etching solution that contains at least one of hydrofluoric acid, hexafluorosilicic acid, and buffered hydrofluoric acid.
7. The method according to claim 5 ;
wherein, in the step of chemically strengthening the glass substrate, the heated molten molten salt also contains sodium nitrate.
8. The method according to claim 5 ;
wherein the uppermost surface layer of the primary surface of the glass substrate has a potassium ion concentration more than 5000 ppm before the 1 to 3 μm of the uppermost surface layer is removed.