Polymer electrolyte membrane comprising alkylether graft chain and method of producing the same
A method of producing an electrolyte membrane for use in a fuel cell, including: performing radiation-induced graft polymerization of a vinyl monomer having a nucleophilic functional group selected from an acylvinyl ether derivative, a styrene derivative, and a methacrylic acid derivative, with a polymer substrate having a fluorine-containing polymer, an olefin-containing polymer, or an aromatic polymer; deprotecting an ester bond of a graft chain on the polymer substrate introduced by the radiation-induced graft polymerization; and introducing an alkylethersulfonic acid structure into the nucleophilic functional group of the graft chain thus deprotected, by use of an electrophilic reagent selected from cyclic sulfonic acid ester and alkylhalide sulfonate.
1. A method of producing an electrolyte membrane comprising alkylether graft chains for use in a fuel cell, comprising:
performing radiation-induced graft polymerization of a vinyl monomer having nucleophilic functional groups, the vinyl monomer selected from an acylvinyl ether derivative, a styrene derivative, and a methacrylic acid derivative, with a polymer substrate comprising a polymer selected from a fluorine-containing polymer, an olefinic polymer, and an aromatic polymer;
deprotecting the nucleophilic functional group, which is protected by an ester bond, of a graft chain on the polymer substrate introduced by the radiation-induced graft polymerization; and
introducing an alkylethersulfonic acid structure into the deprotected nucleophilic functional group of the graft chain, by use of an electrophilic reagent selected from cyclic sulfonic acid ester and alkylhalide-sulfonate.
2. The method of claim 1 , wherein:
the acylvinyl ether derivative is selected from the group consisting of vinyl acetate, vinyl propionate, vinyl butyrate, and vinyl benzoate;
the styrene derivative is selected from the group consisting of 2-hydroxystyrene, 3-hydroxystyrene, 4-hydroxystyrene, 4-(methylhydroxystyrene), 4-(1-ethylhydroxystyrene), 4-(1-hydroxy-1-methylethylstyrene), 4-acetoxystyrene, 4-t-butyloxycarboxystyrene, and 4-acetoxymethylstyrene; and
the methacrylic acid derivative is selected from the group consisting of 1-hydroxymethylacrylic acid, 1-(1-hydroxyethyl)acrylic acid, methyl 1-hydroxymethyl acrylate, methyl 1-(1-hydroxyethyl) acrylate, ethyl 1-hydroxymethyl acrylate, ethyl 1-(1-hydroxyethyl) acrylate, 1-acetoxymethylacrylic acid, 1-(acetoxyethyl)acrylic acid, methyl 1-acetoxymethyl acrylate, and methyl 1-(acetoxyethyl) acrylate.
3. The method of claim 1 wherein:
the cyclic sulfonic acid ester is selected from the group consisting of 1,3-propanesultone, 1,4-butanesultone, 1,1,2,2-tetrafluoroethylsultone, and 1,1,2,2,3,3-hexafluoropropanesultone; and
the alkyl halide sulfonic acid is selected from the group consisting of sodium 2-bromoethylsulfonate and sodium 3-bromopropylsulfonate.