Prosthetic devices
A prosthetic device made of a first specific type of polyarylene, taken alone or in combination with a second specific type of polyarylene, featuring some unexpected advantages such as a very high strength and stiffness, good elongation properties, high chemical resistance, good biocompatibility as well as an outstanding impact resistance.
1. A prosthetic device comprising at least one part consisting of a material comprising at least one polyarylene (P 1 ) and at least one polyarylene (P 2 ), wherein the efficient arylene recurring units (R 1 ) of the polyarylene (P 1 ) are a mix (M 1 ) consisting of:
at least 70 mole %, based on the total number of moles of efficient arylene recurring units (R 1 ), of rigid rod-forming arylene units (Ra), said rigid rod-forming arylene units (Ra) being optionally substituted by at least one monovalent substituting group
with
from 5 to 30 mole %, based on the total number of moles of efficient arylene recurring units (R 1 ), of kink-forming arylene units (Rb), said kink-forming arylene units being optionally substituted by at least one monovalent substituting group;
and wherein the efficient arylene recurring units (R 2 ) of the polyarylene (P 2 ) are a mix (M 2 ) consisting of:
less than 70 mole %, based on the total number of moles of efficient arylene recurring units (R 2 ), of rigid rod-forming arylene units (Ra), said rigid rod-forming arylene units (Ra) being optionally substituted by at least one monovalent substituting group
with
more than 30 mole %, up to 90 mole %, based on the total number of moles of efficient arylene recurring units (R 2 ), of kink-forming arylene units (Rb), said kink-forming arylene units being optionally substituted by at least one monovalent substituting group, and
further wherein said prosthetic device is:
an orthopaedic prosthesis comprising a manufactured replacement for an end and/or an articulating surface of a bone;
a manufactured replacement for a portion of a bone distant from an articulating surface; or
an artificial body part selected from the group consisting of limbs, eyes, and implants.
2. The prosthetic device according to claim 1 , wherein the polyarylene (P 1 ) is a kinked rigid-rod polyphenylene copolymer, essentially all, the recurring units of which consist of a mix (M 1 ) of p-phenylene substituted by a phenylketone group with unsubstituted m-phenylene in a mole ratio p-phenylene:m-phenylene of from 79:21 to 95:5, and wherein the polyarylene (P 2 ) is a kinked rigid-rod polyphenylene copolymer, essentially all the recurring units of which consist of a mix (M 2 ) of p-phenylene substituted by a phenylketone group with unsubstituted m-phenylene in a mole ratio p-phenylene:m-phenylene of from 35:65 to 60:40.
3. The prosthetic device according to claim 1 , wherein essentially all the recurring units of the polyarylene (P 2 ) are efficient arylene recurring units (R 2 ).
4. The prosthetic device according to claim 1 , wherein the weight of the polyarylene (P 2 ), based on the combined weight of the polyarylene (P 1 ) and the polyarylene (P 2 ), is of at least 5% and at most 95%.
5. The prosthetic device according to claim 1 , wherein the weight of the polyarylene (P 2 ), based on the combined weight of the polyarylene (P 1 ) and the polyarylene (P 2 ), is of at least 40% and at most 85%.
6. The prosthetic device according to claim 1 , wherein the weight of the polyarylene (P 2 ), based on the combined weight of the polyarylene (P 1 ) and the polyarylene (P 2 ), ranges from 40 to 65%.
7. The prosthetic device according to claim 1 , wherein the combined weight of the polyarylene (P 1 ) and of the polyarylene (P 2 ), based on the total weight of the material, is above 80%.
8. The prosthetic device according to claim 1 , wherein said material consists essentially of the polyarylene (P 1 ) and the polyarylene (P 2 ).
9. The prosthetic device according to claim 1 , wherein said prosthetic device is an orthopaedic prosthesis comprising a manufactured replacement for an end and/or an articulating surface of a bone.
10. The prosthetic device according to claim 1 , wherein said prosthetic device is a manufactured replacement for a portion of a bone distant from an articulating surface.
11. The prosthetic device according to claim 1 , wherein said prosthetic device is an artificial body part.
12. The prosthetic device according to claim 11 , wherein said artificial body is selected from the group consisting of limbs, eyes, and implants.