Thermosensitive recording material comprising a back coating
A thermosensitive recording material comprising a substrate, a thermosensitive recording layer applied to the front and a back coating which comprises a polyurethane-based-cross-linking component in addition to pigments and binders.
1. A heat-sensitive recording material comprising a substrate having a first side and a second side;
at least one heat-sensitive recording layer on said first side with at least one dye precursor and at least one dye acceptor, the dye precursors and dye acceptor reactable with one another under the action of heat to form color; and
a pigment-containing back coating on said second side,
said back coating containing at least one polyurethane-based component as a crosslinking agent.
2. The heat-sensitive recording material according to claim 1 , wherein said pigment comprises calcium carbonate.
3. The heat-sensitive recording material according to claim 2 , wherein said back coating additionally comprises the combination of starch and styrene-butadiene latex as binder.
4. The heat-sensitive recording material according to claim 1 , wherein said back coating additionally comprises the combination of starch and styrene-butadiene latex as binder.
5. The heat-sensitive recording material according to claim 4 , wherein said starch is present in said back coating in a range of from 1 to 5 wt. % and said styrene-butadiene latex is present in a range of from 12 to 19 wt. %.
6. The heat-sensitive recording material according to claim 1 , wherein said polyurethane-based component is present in a range of from 0.5 to 8 wt. %.
7. The heat-sensitive recording material according to claim 1 , wherein said pigment content of said back coating is in a range of from 75 to 90 wt. %.
8. The heat-sensitive recording material according to claim 1 , additionally comprising a binder in said back coating and wherein the pigment-binder ratio in said back coating is in a range of from 10:1 to 2:1, and
the binder-crosslinker ratio in said back coating is in a range of from 10.5:1 to 5:1.
9. The heat-sensitive recording material according to claim 1 , wherein said heat-sensitive recording layer comprises two dye acceptors, which is N-(p-toluenesulfonyl)- N′-3-(p-toluenesulfonyloxyphenyl)urea of the formula (1):
and a urea-urethane compound of the formula (2):
10. The heat-sensitive recording material according to claim 1 , wherein said heat-sensitive recording layer comprises N-(p-toluenesulfonyl)-N′-3-(p-toluenesulfonyloxyphenyl)-urea of the formula (1) as the dye acceptor:
and 2-(2H-benzotriazole-2-yl)-p-cresol of the formula (3) as the sole sensitizer: