Method of preparing toner
Provided is a method of preparing a toner, the method including: preparing a solvent emulsion by stirring a medium including a polar medium, an organic solvent, and a surfactant; adding toner components including a resin and a pigment to the solvent emulsion; removing the organic solvent from the solvent emulsion including the toner components; and collecting a toner particle from the solvent emulsion from which the organic solvent is removed.
1. A method of preparing a toner, the method comprising:
preparing a solvent emulsion by stirring a medium comprising a polar medium, an organic solvent, and a surfactant, wherein the polar medium is a non-solvent to the toner components and the organic solvent is immiscible with the polar medium, and has a boiling point lower than the polar medium;
adding toner components comprising a resin and a pigment to the solvent emulsion, wherein the resin comprises a water dispersible functional group;
removing the organic solvent from the solvent emulsion comprising the toner components; and
collecting a toner particle from the solvent emulsion from which the organic solvent is removed.
2. The method of claim 1 , wherein the polar medium is at least one selected from the group consisting of water; glycerol; 1,3-propylene glycol, diethylene glycol, dipropylene glycol, 1,3-butylene glycol, 1,2-propylene glycol, 1,3-propanediol, 1,4-butanediol, sorbitol, polyvinyl alcohol and a polyvinyl alcohol copolymer.
3. The method of claim 1 , wherein the polar medium is water.
4. The method of claim 1 , wherein the organic solvent is at least one solvent selected from the group consisting of methyl acetate, ethyl acetate, isopropyl acetate, methyl ethyl ketone, dimethyl ether, diethyl ether, 1,1-dichloroethane, 1,2-dichloroethane, dichloromethane, chloroform, and a mixture thereof.
5. The method of claim 1 , wherein the toner components are simultaneously or sequentially added to the solvent emulsion.
6. The method of claim 1 , wherein the resin comprises at least one resin selected from the group consisting of polyester resin, styrene copolymer resin and epoxy resin.
7. The method of claim 1 , wherein the water dispersible functional group comprises a metal salt form of at least one functional group selected from the group consisting of a hydroxyl group, a mercapto group, a carboxyl group, a phosphate group, a sulfonic acid group, and a sulfate group.
8. The method of claim 1 , wherein the pigment is added to the solvent emulsion in a form of master batch wherein the pigment is dispersed in the resin.
9. The method of claim 8 , wherein the pigment is added to the master batch in a range from 10 to 60 weight % with respect to the total weight of the master batch.
10. The method of claim 1 , wherein the toner component further comprises at least one additive selected from the group consisting of a releasing agent, a charge control agent, and an external additive.
11. The method of claim 10 , wherein when the toner components further comprise a releasing agent, the toner components are added to the solvent emulsion in an order of the resin and the releasing agent.
12. The method of claim 10 , wherein when the toner components further comprise a releasing agent, the toner components are added to the solvent emulsion in an order of the releasing agent and the resin.
13. The method of claim 10 , wherein when the toner components further comprise a charge control agent, the pigment and the charge control agent of the toner components, are simultaneously added to the solvent emulsion with the resin or sequentially added to the solvent emulsion after the resin.
14. The method of claim 1 , wherein an average volume diameter of the toner particle is between 2.0 and 8.0 μm, and a 80% span value of the toner particle is equal to or below 0.88.
15. The method of claim 1 , wherein a circularity of the toner particle is in a range between 0.95 and 0.99.