Method of preparing a polyethylene microporous film for a rechargeable battery separator
Disclosed are a polyethylene microporous film and a method of preparing the same. The polyethylene microporous film, which has a laminated structure comprising B layer/A layer/B layer, prepared by melt-mixing a polyethylene and an aliphatic hydrocarbon solvent together at controlled mixing ratios to separately form an A layer and a B layer having different porosities, and then coextruding the A and B layers, thus exhibiting excellent mechanical properties, such as strength and elongation, and high-temperature stability. Therefore, the polyethylene microporous film is suitable for use in a rechargeable battery separator.
1. A method of preparing a polyethylene microporous film for a rechargeable battery separator comprising the steps of:
melt-mixing 20 to about 40 wt % of a polyethylene with 60 to about 80 wt % of an aliphatic hydrocarbon solvent at an extrusion temperature of 160-220° C. and a screw rotation rate of 150-250 rpm using a first intermeshing corotating twin-screw extruder to form an A layer, which is 1 to about 8 μm thick and has a porosity ranging from about 33 to 55%;
melt-mixing 45 to about 65 wt % of a polyethylene with 35 to about 55 wt % of an aliphatic hydrocarbon solvent at an extrusion temperature of 160-220° C. and a screw rotation rate of 150-250 rpm using a second intermeshing corotating twin-screw extruder to form B layers, and each B layer is 1 to about 4 μm thick and has a porosity ranging from about 23 to 41%;
coextruding the A layer and B layers to laminate B layers on both surfaces of the A layer, and then cooling the coextruded layers, to form a gel composition having a laminated structure comprising B layer/A layer/B layer, the laminated structure having an overall porosity ranging from about 28 to about 46% with the A layer having a greater thickness and a higher porosity that either of the B layers, and the laminated structure has a thickness of 3 to about 16 μm;
biaxially stretching the gel composition, to prepare a film;
extracting the aliphatic hydrocarbon solvent from the A layer and B layers of the film using an organic solvent to remove the aliphatic hydrocarbon solvent, to prepare a microporous film; and
heat-treating the microporous film at a temperature not greater than a melting temperature of the polyethylene.
2. The method as set forth in claim 1 , wherein the biaxial stretching is conducted at a ratio ranging from 4×4 to 8×8 at 105 to about 125° C.
3. A method of preparing a polyethylene microporous film for a rechargeable battery separator comprising the steps of:
melt-mixing with 12.8 to about 64.9 wt % of a polyethylene, 0.1 to about 7.2 wt % of a thermoplastic resin incompatible with the polyethylene and having a melting temperature higher than that of the polyethylene, and 35 to about 80 wt % of an aliphatic hydrocarbon solvent at an extrusion temperature of 180-280° C. and a screw rotation rate of 100-300 rpm using a first intermeshing corotating twin-screw extruder to form an A layer, which is 1 to about 8 μm thick and has a porosity ranging from about 33 to 55%,
melt-mixing 20 to about 65 wt % of a polyethylene with 35 to about 80 wt % of an aliphatic hydrocarbon solvent at an extrusion temperature of 180-280° C. and a screw rotation rate of 100-300 rpm using a second intermeshing corotating twin-screw extruder to form B layers, and each B layer is 1 to about 4 μm thick and has a porosity ranging from about 23 to 41%;
coextruding the A layer and B layers to laminate B layers on both surfaces of the A layer, and then cooling the coextruded layers, to form a gel composition having a laminated structure comprising B layer/A layer/B layer, the laminated structure having an overall porosity ranging from about 28 to 46% with the A layer having a greater thickness and a higher porosity than either of the B layers, and the laminated structure having a thickness of 3 to about 16 μm;
biaxially stretching the gel composition, to prepare a film;
extracting the aliphatic hydrocarbon solvent from the A layer and B layers of the film using an organic solvent to remove the aliphatic hydrocarbon solvent, to prepare a microporous film; and
heat-treating the microporous film at a temperature not greater than a melting temperature of the polyethylene.
4. The method as set forth in claim 3 , wherein the biaxial stretching is conducted at a ratio ranging from 4×4 to 8×8 at 105 to about 125° C.
5. The method as set forth in claim 1 , wherein the thickness of the A layer is substantially the same as the combined thickness of the B layers.
6. The method as set forth in claim 3 , wherein the thickness of the A layer is substantially the same as the combined thickness of the B layers.