IP Library Granted Patent US 9,243,316
Granted Patent B2
US 9,243,316 · App. 12/692,108 · Granted Jan 26, 2016

Method of fabricating piezoelectric material with selected c-axis orientation

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Quick Facts
Patent No.
US 9,243,316
App. No.
12/692,108
Granted
Jan 26, 2016
Kind
B2
Abstract

In accordance with a representative embodiment, a method of fabricating a piezoelectric material comprising a first component and a second component comprises: providing a substrate; flowing hydrogen over the substrate; flowing the first component to form the piezoelectric material over a target; and sputtering the piezoelectric material from the target on the substrate. In accordance with another representative embodiment, a method of fabricating a bulk acoustic wave (BAW) resonator comprises: forming a first electrode over a substrate; forming a seed layer over the substrate; and depositing a piezoelectric material having a compression-negative (C N ) polarity. The depositing of the piezoelectric material comprises: flowing a first component of the piezoelectric material to form the piezoelectric material over a target comprising a second component of the piezoelectric material; and sputtering the piezoelectric material from the target to the substrate.

Claims (37)

1. A method of fabricating a piezoelectric material comprising a first component and a second component, the method comprising:

providing a substrate;

initially flowing hydrogen over the substrate;

after the initially flowing of the hydrogen over the substrate,

flowing the first component to form the piezoelectric material over a surface of a target comprising the second component;

sputtering the piezoelectric material from the target onto the substrate; and

flowing the hydrogen over the substrate during the sputtering at a rate sufficient to cause a piezoelectric film having a defined polarity to be formed over the substrate, wherein

a seed layer is not formed over the substrate prior to the sputtering.

2. A method of fabricating a piezoelectric material as claimed in claim 1 , wherein the piezoelectric film comprises a compression-negative (C N ) polarity.

3. A method of fabricating a piezoelectric material as claimed in claim 1 , wherein the flowing of hydrogen is continuous during the fabricating of the piezoelectric film.

4. A method of fabricating a piezoelectric material as claimed in claim 1 , further comprising, after the depositing:

ceasing flow of the hydrogen;

forming a second substrate over the piezoelectric film; and

sputtering the piezoelectric material from the target over the second substrate.

5. A method of fabricating a piezoelectric material as claimed in claim 4 , further comprising, before forming the second substrate flowing hydrogen over the second substrate, wherein the piezoelectric material comprises a compression-negative (C N ) material.

6. A method of fabricating a piezoelectric material as claimed in claim 3 , wherein the substrates comprise a metal.

7. A method of fabricating a piezoelectric material as claimed in claim 6 , wherein the metal comprises one of: molybdenum (Mo), aluminum (Al), tungsten (W), platinum (Pt), and ruthenium (Ru).

8. A method of fabricating a piezoelectric material as claimed in claim 1 , wherein the first component comprises nitrogen and the second component comprises aluminum.

9. A method of fabricating a piezoelectric material as claimed in claim 4 , wherein the piezoelectric material sputtered on the first substrate comprises a compression-negative (C N ) material, and the piezoelectric material sputtered over the second substrate comprises a compression-positive (C P ) material.

10. A method of fabricating a piezoelectric material as claimed in claim 1 , wherein the flowing of hydrogen during the depositing forms NH x .

11. A method of fabricating a bulk acoustic wave (BAW) resonator having a piezoelectric material consisting essentially of first and second components, the method comprising:

forming a first electrode over a substrate;

forming a seed layer consisting essentially of the second component over the substrate;

flowing the first component of the piezoelectric material to form the piezoelectric material over a surface of a target consisting essentially of the second component of the piezoelectric material; and

sputtering the piezoelectric material from the target onto the seed layer to deposit a piezoelectric layer having a compression-negative (C N ) polarity.

12. A method as of fabricating a BAW resonator as claimed in claim 11 , further comprising forming a second electrode over the piezoelectric material.

13. A method as of fabricating a BAW resonator as claimed in claim 11 , wherein the seed layer comprises aluminum.

14. A method of fabricating a BAW resonator as claimed in claim 13 , wherein the first electrode and the second electrode comprise one of molybdenum (Mo), aluminum (Al), tungsten (W), platinum (Pt), and ruthenium (Ru).

15. A method of fabricating a BAW resonator as claimed in claim 11 , further comprising, after the forming of the first electrode and before the forming of the seed layer, forming a plasma and removing a contaminant from a surface of the first electrode.

16. A method of fabricating a BAW resonator as claimed in claim 11 , further comprising, after the forming of the seed layer, maintaining a flow of an inert gas over the surface of the seed layer during the depositing of the first component and the piezoelectric material.

17. A method of fabricating a BAW resonator as claimed in claim 12 , further comprising, after the depositing of the piezoelectric material: sputtering a second piezoelectric material over the second electrode, wherein the second piezoelectric material comprises a compression-positive (C P ) polarity.

18. A method of fabricating a BAW resonator as claimed in claim 12 , wherein the first electrode and the second electrode comprise a metal.

19. A method of fabricating a BAW resonator as claimed in claim 18 , wherein the metal comprises one of: molybdenum (Mo), aluminum (Al), tungsten (W), platinum (Pt), and ruthenium (Ru).

20. A method of fabricating a BAW resonator as claimed in claim 11 , wherein the first component comprises nitrogen and the second component comprises aluminum.

21. A method of fabricating a BAW resonator as claimed in claim 11 , wherein the seed layer is selected to foster growth of the piezoelectric material comprising the compression-negative (C N ) polarity.

22. A method of fabricating a BAW resonator as claimed in claim 11 , wherein vacuum is maintained during the method.

23. The method of claim 11 , wherein the first component is nitrogen (N) and the second component is aluminum (Al).

Assignments (8)
CORRECTIVE ASSIGNMENT TO CORRECT THE EXECUTION DATE PREVIOUSLY RECORDED AT REEL: 047422 FRAME: 0464. ASSIGNOR(S) HEREBY CONFIRMS THE MERGER. Recorded Mar 6, 2019
From: AVAGO TECHNOLOGIES GENERAL IP (SINGAPORE) PTE. LTD.
To: AVAGO TECHNOLOGIES INTERNATIONAL SALES PTE. LIMITED
Reel/Frame 048883/0702 →
MERGER Recorded Oct 5, 2018
From: AVAGO TECHNOLOGIES GENERAL IP (SINGAPORE) PTE. LTD.
To: AVAGO TECHNOLOGIES INTERNATIONAL SALES PTE. LIMITED
Reel/Frame 047422/0464 →
TERMINATION AND RELEASE OF SECURITY INTEREST IN PATENTS Recorded Feb 3, 2017
From: BANK OF AMERICA, N.A., AS COLLATERAL AGENT
To: AVAGO TECHNOLOGIES GENERAL IP (SINGAPORE) PTE. LTD.
Reel/Frame 041710/0001 →
PATENT SECURITY AGREEMENT Recorded Feb 11, 2016
From: AVAGO TECHNOLOGIES GENERAL IP (SINGAPORE) PTE. LTD.
To: BANK OF AMERICA, N.A., AS COLLATERAL AGENT
Reel/Frame 037808/0001 →
TERMINATION AND RELEASE OF SECURITY INTEREST IN PATENT RIGHTS (RELEASES RF 032851-0001) Recorded Feb 2, 2016
From: DEUTSCHE BANK AG NEW YORK BRANCH, AS COLLATERAL AGENT
To: AVAGO TECHNOLOGIES GENERAL IP (SINGAPORE) PTE. LTD.
Reel/Frame 037689/0001 →
PATENT SECURITY AGREEMENT Recorded May 8, 2014
From: AVAGO TECHNOLOGIES GENERAL IP (SINGAPORE) PTE. LTD.
To: DEUTSCHE BANK AG NEW YORK BRANCH, AS COLLATERAL AGENT
Reel/Frame 032851/0001 →
MERGER Recorded May 7, 2013
From: AVAGO TECHNOLOGIES WIRELESS IP (SINGAPORE) PTE. LTD.
To: AVAGO TECHNOLOGIES GENERAL IP (SINGAPORE) PTE. LTD.
Reel/Frame 030369/0471 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 22, 2010
From: LARSON, JOHN, III; MISHIN, SERGEY
To: AVAGO TECHNOLOGIES WIRELESS IP (SINGAPORE) PTE. LTD.
Reel/Frame 023834/0467 →