THERMALLY OPERATED VALVE

1 . A valve comprising:

a housing including a valve seat;

a valve pin, said valve pin supported by a support shell; and

said support shell and said valve pin having distinct coefficients of thermal expansion such that when exposed to a temperature change, movement of said support shell and said valve pin being different, and said valve pin can be caused to move toward and away from said valve seat to allow operation of said valve.

2 . The valve as set forth in claim 1 , wherein said valve pin has a lower coefficient of thermal expansion than said support shell.

3 . The valve as set forth in claim 1 , wherein the coefficient of thermal expansion of one of said support shell and said valve pin is at least twice as high as the coefficient of thermal expansion of the other.

4 . The valve as set forth in claim 1 , wherein an end of said valve pin and an end of said support shell remote from said seat, are secured together such that the said movement of said support shell causes said valve pin to move relative to said valve seat.

5 . The valve as set forth in claim 1 , wherein a heater is provided to cause said movement of said valve pin relative to said valve seat.

6 . The valve as set forth in claim 5 , wherein said heater heats said support shell to cause said shell to expand, and cause movement of said valve pin.

7 . The valve as set forth in claim 6 , wherein said support shell is secured in said valve seat housing, and such that expansion of said support shell at a greater rate than expansion of said valve pin causes movement of said valve pin.

8 . The valve as set forth in claim 1 , wherein said valve seat is formed in a diaphragm member.

9 . The valve as set forth in claim 8 , wherein said valve seat is formed as an opening in said diaphragm, and a material allows leakage of a very precise amount of fluid across the material and to said opening, and said valve pin being pulled away from said valve seat, such that a very precise amount of fluid can leak across the material, and to a sampling outlet.

10 . The valve as set forth in claim 1 , wherein said valve pin is formed of tungsten, and said support shell is formed of a stainless steel.

11 . The valve as set forth in claim 1 , wherein said support shell is a cylindrical element surrounding said valve pin.

12 . A valve comprising:

a housing including a valve seat;

a valve pin supported by a support shell;

said support shell having a higher coefficient of thermal expansion than said valve pin such that when exposed to a temperature change, expansion of said support shell being greater than said valve pin, and said valve pin being caused to move toward and away from said valve seat to allow operation of said valve;

an end of said valve pin and an end of said support shell remote from said valve seat secured together such that the movement of said support shell causes said valve pin to move relative to said valve seat; and

a heater provided to cause said movement of said valve pin relative to said valve seat.

13 . The valve as set forth in claim 12 , wherein said valve pin is formed of tungsten, and said support shell is formed of a stainless steel.

14 . A method of operating a valve including the steps of:

(a) providing a housing including a valve seat;

(b) connecting a valve pin to a support shell, said support shell and said valve pin having distinct coefficients of thermal expansion; and

(c) said valve pin and said support shell moving in response to a temperature change with movement of said support shell and said valve pin being different, and said valve pin moving toward or away from said valve seat to allow operation of said valve.

15 . The method as set forth in claim 14 , wherein heat is applied to said support shell and to said valve pin to cause said movement of said valve pin.