Image forming method
Disclosed is a method for forming an image with an ink-jet recoding method which forms the image on a coated printing paper by employing an ink containing water in an amount of 20 to 90% weight based on the total weight of the ink, a pigment and a resin, the method containing the sequential steps of: applying an aqueous processing solution on the coated printing paper; drying the aqueous processing solution applied on the coated printing paper; and ejecting droplets of the ink on the coated printing paper, wherein the aqueous processing solution is capable of aggregating the ink or increasing a viscosity of the ink, and the coated printing paper is heated from 40 to 60° C. during the step of ejecting the droplets of the ink.
1. A method for forming an image with an ink-jet recoding method which forms the image on a coated printing paper by employing an ink comprising water in an amount of 20 to 90 weight % based on the total weight of the ink, a pigment and a resin,
the method comprising the sequential steps of:
applying an aqueous processing solution on the coated printing paper;
drying the aqueous processing solution applied on the coated printing paper; and
ejecting droplets of the ink on the coated printing paper,
wherein the aqueous processing solution is capable of aggregating the ink or increasing a viscosity of the ink, and the coated printing paper is heated from 40 to 60° C. during the step of ejecting the droplets of the ink.
2. The method for forming an image with an ink-jet recoding method claim 1 ,
wherein a content of water in the aqueous processing solution after applied on the coated printing paper is reduced in the range of 0.1 weight % to 30 weight % based on a content of water contained in the aqueous processing solution by the drying step, and then, the ejection step of the ink is carried out.
3. The method for forming an image with an ink-jet recoding method of claim 1 ,
wherein the aqueous processing solution contains at least one of the group consisting of a polyvalent metal salt, an acid and a cationic resin.
4. The method for forming an image with an ink-jet recoding method of claim 1 ,
wherein the aqueous processing solution contains a polyvalent metal salt.
5. The method for forming an image with an ink-jet recoding method of claim 3 ,
wherein the polyvalent metal salt contains at least a cation selected from the group consisting of a calcium ion, a copper ion, a nickel ion, a magnesium ion, a barium ion, an aluminium ion, an iron ion, a chromium ion, a yttrium ion and a zirconium ion.
6. The method for forming an image with an ink-jet recoding method of claim 3 ,
wherein the polyvalent metal salt contains at least an anion selected from the group consisting of a carbonate ion, a sulfate ion, a nitrate ion, a chloride ion, an organic acid ion, a borate ion and a phosphate anion.
7. The method for forming an image with an ink-jet recoding method of claim 1 ,
wherein the aqueous processing solution contains an organic acid having a pKa value of 4.5 or less.
8. The method for forming an image with an ink-jet recoding method of claim 3 ,
wherein the acid is at least one selected from the group consisting of hydrochloric acid, nitric acid, sulfuric acid, phosphoric acid, carbonic acid, citric acid, isocitric acid, oxalic acid, maleic acid, fumaric acid, malonic acid, succinic acid, glutaric acid, adipic acid, phthalic acid, isophthalic acid, terephthalic acid, citric acid, 2-pyrrolidone-5-carboxylic acid, benzoic acid, a benzoic acid derivative, salicylic acid, ascorbic acid, malic acid, benzenesulfonic acid, a benzenesulfonic acid derivative, pyruvic acid and oxalacetic acid.
9. The method for forming an image with an ink-jet recoding method of claim 1 ,
wherein the resin has an acid group which is neutralized with an amine.
10. The method for forming an image with an ink-jet recoding method of claim 9 ,
wherein the resin having an acid group which is neutralized with an amine has a weight average molecular weight of 3,000 to 30,000.
11. The method for forming an image with an ink-jet recoding method of claim 9 ,
wherein the resin having an acid group which is neutralized with an amine exhibits an acid value of 60 to 300 mgKOH/g.
12. The method for forming an image with an ink-jet recoding method of claim 1 ,
wherein the resin contained in the ink is a water soluble resin.
13. The method for forming an image with an ink-jet recoding method of claim 1 ,
wherein the water soluble resin has a weight average molecular weight of 5,000 or more.
14. The method for forming an image with an ink-jet recoding method of claim 3 ,
wherein the cationic resin is at least one selected from the group consisting of polyallylamine, polyamine, cation modified acrylate resin, cation modified methacrylic resin, cation modified vinyl resin, cationic polyurethane resin and a copolymer thereof.
15. The method for forming an image with an ink-jet recoding method of claim 1 ,
wherein the ink contains an organic solvent in an amount of 20 to 60 weight % based on a total weight of the ink.
16. The method for forming an image with an ink-jet recoding method of claim 1 ,
wherein the applying step of the aqueous processing solution is conducted two times or more, then the drying step of the aqueous processing solution is carried out.
17. The method for forming an image with an ink-jet recoding method of claim 1 ,
wherein the applying step of the aqueous processing solution is conducted with a method selected from the group consisting of a roller coating method, an ink-jet method, a curtain coating method and a spray coating method.
18. The method for forming an image with an ink-jet recoding method of claim 1 ,
wherein the drying step of the aqueous processing solution is conducted with a heater, a warm air dryer, or a hating roller.
19. The method for forming an image with an ink-jet recoding method of claim 1 ,
wherein the drying step of the aqueous processing solution is conducted with a heater and a warm air dryer.