High strength steel plate, steel pipe with excellent low temperature toughness, and method of production of same
The present invention provides high strength steel plate with excellent low temperature toughness, high strength steel pipe using this as a base metal, and methods of production of the same. The steel plate of the present invention contains Mo: 0.05 to 1.00% and B: 0.0003 to 0.0100%, has a Ceq of 0.30 to 0.53, has a Pcm of 0.10 to 0.20, and has a metal structure which has an area percentage of polygonal ferrite of 20 to 90% and has a balance of a hard phase comprised of one or both of bainite and martensite. To obtain this steel plate, strain-introducing rolling is performed with a start temperature of not more than Ar 3 +60° C., an end temperature of Ar 3 or more, and a reduction ratio of 1.5 or more, then the plate is air-cooled and then acceleratedly cooled from Ar 3 −100° C. to Ar 3 −10° C. in temperature by 10° C./s or more.
1. High strength steel plate with excellent low temperature toughness, having a chemical composition containing, by mass %,
C: 0.01 to 0.08%,
Si: 0.01 to 0.50%,
Mn: 0.5 to 2.0%,
S: 0.0001 to 0.005%,
Ti: 0.003 to 0.030%,
Mo: 0.05 to 1.00%,
B: 0.0003 to 0.010%, and
0 : 0.0001 to 0.008%,
limiting
P: 0.050% or less and
Al: 0.020% or less, and
having a balance of iron and unavoidable impurities,
having a Ceq, calculated by the following (formula 1), of 0.30 to 0.53,
having a Pcm, found the following (formula 2), of 0.10 to 0.20, and
having a metal structure with an area percentage of polygonal ferrite of 20 to 90% and a balance of a hard phase comprised of one or both of bainite and martensite:
Ceq =C+Mn/6+(Ni+Cu)/15+(Cr+Mo+V)/5 . . . (formula 1)
Pcm =C+Si/30+(Mn+Cu+Cr)/20+Ni/60+Mo/15+V/10+5B . . . (formula 2)
where, C, Si, Mn, Ni, Cu, Cr, Mo, V, and B are contents of the individual elements (mass %).
2. High strength steel plate with excellent low temperature toughness as set forth in claim 1 , further containing, by mass %, one or both of
Cu: 0.05 to 1.5% and
Ni: 0.05 to 5.0%.
3. High strength steel plate with excellent low temperature toughness as set forth in claim 1 , further containing, by mass %, one or more of
Cr: 0.02 to 1.50%,
W: 0.01 to 0.50%,
V: 0.01 to 0.10%,
Nb: 0.001 to 0.20%,
Zr: 0.0001 to 0.050%, and
Ta: 0.0001 to 0.050%.
4. High strength steel plate with excellent low temperature toughness as set forth in claim 1 , further containing, by mass %, one or more of
Mg: 0.0001 to 0.010%,
Ca: 0.0001 to 0.005%,
REM: 0.0001 to 0.005%,
Y: 0.0001 to 0.005%,
Hf: 0.0001 to 0.005%, and
Re: 0.0001 to 0.005%.
5. High strength steel plate with excellent low temperature toughness as set forth in claim 1 , characterized by having a metal structure with an area percentage of polygonal ferrite of 20 to 80%.
6. High strength steel pipe with excellent low temperature toughness characterized by having a base metal comprised of steel plate as set forth in claim 1 .
7. A method of production of high strength steel plate with excellent low temperature toughness characterized by taking a steel slab comprised of the chemical compositions as set forth in claim 1 , reheating it to 950° C. or more, hot rolling it, performing, as the final step in said hot rolling, strain-introducing rolling with a start temperature of not more than Ar3+60° C., and end temperature of not less than Ar3, and a reduction ratio of not less than 1.5, then air-cooling, then acceleratedly cooling from Ar3-100° C. to Ar3-10° C. in temperature by a 10° C/s or more cooling rate until a temperature of not more than a Bs calculated by the following (formula 3)
Bs (° C.)=830−270C−90Mn−37Ni−70Cr−83Mo . . . (formula 3)
where, C, Mn, Ni, Cr, and Mo are contents of the individual elements (mass %).
8. A method of production of high strength steel pipe with excellent low temperature toughness characterized by forming steel plate produced by the method as set forth in claim 7 into a pipe shape by a UO process, welding the abutting parts from the inside and outside surfaces by submerged arc welding, then expanding the pipe.