IP Library Patent Application 12740153
Patent Application
App. No. 12/740,153

FILTRATION MEMBRANES

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Quick Facts
Patent No.
US None
App. No.
12/740,153
Abstract

A method for maintaining pore size of a reusable filtration membrane, said method comprising exposing said filtration membrane to a plasma comprising a hydrocarbon or fluorocarbon monomer so as to form a polymeric layer on the surface thereof. The treatment allows the filtration membrane to withstand washing procedures, in particular caustic washing. Thus reusable filtration membranes treated in this way and their use, form a further aspect of the invention.

Claims (28)

1 - 23 . (canceled)

24 . A method for maintaining pore size of a reusable filtration membrane comprising exposing the filtration membrane to a plasma comprising a hydrocarbon or fluorocarbon monomer to form a polymeric layer on a surface of the filtration membrane.

25 . The method of claim 24 , further comprising subjecting the reusable filtration membrane to caustic washing.

26 . The method of claim 24 , wherein the reusable filtration membrane consists essentially of synthetic polymeric material.

27 . The method of claim 26 , wherein the synthetic polymeric material consists essentially of polyethylene.

28 . The method of claim 24 , wherein the plasma is pulsed.

29 . The method of claim 28 , further comprising, in a preliminary step, applying a continuous power plasma to the filtration membrane.

30 . The method of claim 24 , wherein the monomer is a compound of formula (I)

where R 1 , R 2 and R 3 independently are selected from hydrogen, alkyl, haloalkyl or aryl optionally substituted by halo; and R 4 is a group X—R 5 where R 5 is an alkyl or haloalkyl group and X is a bond, a group of formula —C(O)O(CH 2 ),Y— where n is an integer of from 1 to 10 and Y is a bond or a sulphonamide group, or a group —(O) p R 6 (O) q (CH 2 ) t — where R 6 is aryl optionally substituted by halo, p is 0 or 1, q is 0 or 1, and t is 0 or an integer from 1 to 10, provided that where q is 1, t is not 0.

31 . The method of claim 30 , wherein the compound of formula (I) is a compound of formula (II)

CH 2 ═CH—R 5   (II)

where R 5 is an alkyl or haloalkyl group.

32 . The method of claim 30 , wherein the compound of formula (I) is a compound of formula (III)

CH 2 ═CR 7a C(O)O(CH 2 ),R 5   (III)

where n is an integer of from 1 to 10, R 5 is an alkyl or haloalkyl group, and R 7a is hydrogen, C 1-10 alkyl, or C 1-10 haloalkyl.

33 . The method of claim 32 , wherein the compound of formula (III) is a compound of formula (IV)

where R 7a is hydrogen, C 1-10 alkyl, or C 1-10 haloalkyl, and x is an integer of from 1 to 9.

34 . The method of claim 33 , wherein the compound of formula (IV) is 1H,1H,2H,2H-heptadecafluorodecylacylate.

35 . The method of claim 24 , further comprising placing the reusable filtration membrane in a plasma deposition chamber, igniting a glow discharge within the chamber, and applying a pulsed voltage.

36 . The method of claim 35 , wherein the voltage is applied at a power of from 40 to 500 W.

37 . The method of claim 35 , wherein the voltage is pulsed in a sequence in which the ratio of time on to time off is from 1:500 to 1:1500.

38 . The method of claim 35 , further comprising, in a preliminary step, applying a continuous power plasma to the filtration membrane.

39 . The method of claim 38 , wherein the preliminary step is conducted in the presence of an inert gas.

40 . The method of claim 36 , wherein the voltage is pulsed in a sequence in which the ratio of time on to time off is from 1:500 to 1:1500, the reusable filtration membrane consists essentially of a polyethylene material, and the monomer is 1H,1H,2H,2H-heptadecafluorodecylacylate.

41 . A reusable filtration membrane consisting essentially of a synthetic polymeric material that has been treated with a plasma comprising a hydrocarbon or fluorocarbon monomer to form a polymeric layer on a surface of the filtration membrane.

42 . The reusable filtration membrane of claim 41 , wherein the synthetic polymeric material consists essentially of a polyethylene material.

43 . A method of filtering a liquid comprising passing the liquid through a filtration membrane consisting essentially of a synthetic polymeric material that has been treated with a plasma comprising a hydrocarbon or fluorocarbon monomer to form a polymeric layer on a surface of the filtration membrane.

44 . The method of claim 43 , further comprising a subsequent step of washing the filtration membrane in a caustic solution.

Assignments (5)
CONFIRMATION OF RELEASE OF DEBENTURE Recorded Feb 17, 2017
From: GLAS TRUST CORPORATION LIMITED
To: P2I LIMITED
Reel/Frame 041746/0186 →
RELEASE OF SECURITY INTEREST Recorded Dec 16, 2015
From: CLYDESDALE BANK PLC
To: P2I LTD
Reel/Frame 037304/0250 →
CONFIRMATION OF DEBENTURE Recorded Nov 18, 2015
From: P2I LIMITED
To: GLAS TRUST CORPORATION LIMITED
Reel/Frame 037128/0739 →
SECURITY INTEREST Recorded Jul 29, 2014
From: P2I LIMITED
To: CLYDESDALE BANK PLC
Reel/Frame 033430/0697 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 20, 2010
From: COULSON, STEPHEN; WAKEMAN, RICHARD
To: P2I LTD.
Reel/Frame 024711/0738 →