IP Library Granted Patent US 8,318,233
Granted Patent B2
US 8,318,233 · App. 12/748,013 · Granted Nov 27, 2012

Emulsions useful in beverages

View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 8,318,233
App. No.
12/748,013
Granted
Nov 27, 2012
Kind
B2
Abstract

It has now been found that emulsions having a discrete phase volume fraction of 60% to 67% with excellent stability may be prepared using at least one low molecular weight surfactant. Such emulsions have high oil loading and a small mean particle size of less than 0.2 microns. Further, such emulsions may be used in beverages without weighting agents.

Claims (48)

1. An oil-in-water emulsion comprising:

a) a water-containing continuous phase;

b) an oil-containing discrete phase; and

c) at least one low molecular weight surfactant;

wherein the volume fraction of the discrete phase is from 60% to 67%;

the emulsion has a mean particle size of less than 0.2 microns;

the low molecular weight surfactant is selected from the group consisting of quillaja solid extract, polysorbate, and mixtures thereof; and

wherein the low molecular weight (LMW) surfactant is present in an amount of from 2% to 25% (wt/wt).

2. The emulsion of claim 1 , wherein the volume fraction of the discrete phase is from 62% to 65%.

3. The emulsion of claim 1 , wherein the low molecular weight surfactant is selected from the group consisting of quillaja solid extract, polysorbate.

4. The emulsion of claim 1 , wherein the low molecular weight surfactant is quillaja solid extract and polysorbate.

5. The emulsion of claim 4 , wherein the polysorbate is polyoxyethylene (20) sorbitan monostearate (Tween 60).

6. The emulsion of claim 1 , wherein the mean particle size of the emulsion is less than 0.15 microns.

7. The emulsion of claim 1 , wherein at least 90% of the emulsion particles are no greater than 0.2 microns.

8. The emulsion of claim 7 , wherein at least 90% of the emulsion particles are no greater than 0.15 microns.

9. The emulsion of claim 1 , wherein the emulsion is stable such that the mean particle size remains less than 0.2 microns for at least 3 months.

10. The emulsion of claim 9 , wherein the emulsion is stable such that the mean particle size remains less than 0.2 microns for at least 6 months.

11. The emulsion of claim 9 , wherein the emulsion is stable such that the mean particle size remains less than 0.2 microns for at least 12 months.

12. The emulsion of claim 1 , in which the emulsion is a non-weighted emulsion.

13. A method of making the oil-in-water emulsion of claim 1 comprising:

a) mixing water, oil and at least one low molecular weight surfactant to obtain a volume fraction of the discrete phase from 60% to 67%; and

b) homogenizing with less than 10 passes at a pressure of 17 to 65.5 MPascals;

to result in an oil-in-water emulsion with a mean particle size of less than 0.2 microns:

the low molecular weight surfactant is selected from the group consisting of quillaja solid extract, polysorbate, and mixtures thereof: and

wherein the low molecular weight (LMW) surfactant is present in an amount of from 2% to 25% (wt/wt).

14. The method of claim 13 , wherein the volume fraction of the discrete phase is from 62% to 65%.

15. The method of claim 13 , wherein the low molecular weight surfactant is selected from the group consisting of quillaja solid extract and polysorbate.

16. The method of claim 13 , wherein the low molecular weight surfactant is quillaja solid extract and polysorbate.

17. The method of claim 16 , wherein the polysorbate is polyoxyethylene (20) sorbitan monostearate (Tween 60).

18. The method of claim 13 , wherein the mean particle size of the emulsion is between 0.1 and 0.2 microns.

19. The method of claim 13 , wherein at least 90% of the emulsion particles are no greater than 0.2 microns.

20. The method of claim 19 , wherein at least 90% of the emulsion particles are no greater than 0.15 microns.

21. An oil-in-water emulsion comprising:

a) a water-containing continuous phase;

b) an oil-containing discrete phase; and

c) at least one low molecular weight surfactant;

wherein the volume fraction of the discrete phase is from 60% to 67%;

the emulsion has a mean particle size of less than 0.2 microns;

the low molecular weight surfactant is selected from the group consisting of quillaja solid extract, polysorbate, sugar esters, and mixtures thereof; and

wherein at least one low molecular weight (LMW) surfactant is present in an amount of from 8% to 14% (wt/wt).

22. An oil-in-water emulsion comprising:

a) a water-containing continuous phase;

b) an oil-containing discretephase; and

c) at least one low molecular weight surfactant;

wherein the volume fraction of the discrete phase is from 60% to 67%;

the emulsion has a mean particle size of less than 0.2 microns;

the low molecular weight surfactant is selected from the group consisting of quillaja solid extract, polysorbate, sugar esters, and mixtures thereof; and

wherein at least one low molecular weight (LMW) surfactant is present in an amount of from 12% to 14% (wt/wt).

Assignments (3)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 7, 2012
From: BRUNOB II B.V.; NATIONAL STARCH LLC
To: CORN PRODUCTS DEVELOPMENT, INC.
Reel/Frame 028912/0774 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 2, 2012
From: NATIONAL STARCH LLC; BRUNOB II B.V.
To: CORN PRODUCTS DEVELOPMENT, INC.
Reel/Frame 027645/0724 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 21, 2010
From: TRAN, IRENE; LI, JASON Z.
To: BRUNOB II B.V.; NATIONAL STARCH LLC
Reel/Frame 024420/0104 →