Abrasive compounds for semiconductor planarization
View Patent ↗A polishing slurry for semiconductor planarization containing cerium oxide particles and water, wherein the content of the cerium oxide particles having a diameter of 3 μm or more is 500 ppm or less (weight ratio) in a solid, preferably 100 ppm or less and it is more preferable that D99 (99% by volume of the whole particles in polishing slurry) of the cerium oxide particles is 1 μm or less. The polishing slurry can reduce the generation of scratches, and can polish a surface of the semiconductor substrate in the wiring formation process of semiconductor device precisely at a high speed.
1. A method for producing a polishing slurry for semiconductor planarization, comprising
mechanically grinding cerium oxide particles,
mixing at least a dispersing agent and water with the cerium oxide particles to prepare a polishing slurry,
filtering the polishing slurry through a filter wherein holes of the filter are formed by superposing filter fibers and reducing the diameter of the holes continuously from the outside of the filter to the inside, wherein the filter fibers are not mutually fixed, and
performing said filtering multiple times until the content of cerium oxide particles having a diameter of at least 3 μm is not more than 500 ppm, calculated based on the weight of particles obtained by filtering with a film filter for analysis on which hole diameters of 3 μm are formed by punching the film and the weight of all the solids in the polishing slurry,
wherein said polishing slurry is capable of semiconductor planarization.
2. The method for producing a polishing slurry for semiconductor planarization according to claim 1 , further comprising a classification step.
3. The method for producing a polishing slurry for semiconductor planarization according to claim 1 , wherein 99% by volume of the cerium oxide particles have a size of less than 1.0 μm in said polishing slurry.
4. The method for producing a polishing slurry for semiconductor planarization according to claim 1 , wherein the median diameter (D50) of secondary particles of the cerium oxide particles in said polishing slurry is in the range of 0.03 to 0.5 μm.
5. The method for producing a polishing slurry for semiconductor planarization according to claim 1 , wherein the content of the cerium oxide particles having a diameter of at least 3 μm is not more than 200 ppm, calculated based on the weight of particles obtained by filtering with a film filter for analysis on which hole diameters of 3 μm are formed by punching the film and the weight of all the solids in the polishing slurry.
6. The method for producing a polishing slurry for semiconductor planarization according to claim 1 , wherein the polishing slurry is a single-liquid type polishing slurry consisting essentially of the cerium oxide particles, a dispersant, a polymer additive and water.
7. The method for producing a polishing slurry for semiconductor planarization according to claim 1 , wherein the polishing slurry is a double-liquid type polishing slurry consisting essentially of the cerium oxide particles, a dispersant, and water.
8. The method for producing a polishing slurry for semiconductor planarization according to claim 1 , wherein the mechanically grinding is dry grinding.
9. The method for producing a polishing slurry for semiconductor planarization according to claim 8 , wherein the dry grinding is by using a jet mill.
10. The method for producing a polishing slurry for semiconductor planarization according to claim 1 , wherein the mechanically grinding is by wet grinding.
11. The method for producing a polishing slurry for semiconductor planarization according to claim 10 , wherein the wet grinding is by using a planet bead mill.