Corrugated pattern forming sheet, and methods for manufacturing antireflector, retardation plate, original process sheet plate, and optical element
A corrugated pattern forming sheet exhibiting excellent performance when being used as optical elements, such as an antireflector and a retardation plate is provided. A corrugated pattern forming sheet of the invention includes a resin layer, and a hard layer provided at least in a portion of an outer surface of the resin layer. The hard layer is made of a metal or a metallic compound. The hard layer has a wavelike corrugated pattern. The average pitch of the corrugated pattern is 1 μm or less, and the average depth of the bottom of the corrugated pattern is 10% or more given an average pitch of 100%.
1. A corrugated pattern forming sheet comprising a resin layer, and a hard layer provided at least in a portion of an outer surface of the resin layer, the hard layer having a wavelike corrugated pattern,
wherein the hard layer provided in one whole surface of the resin layer,
wherein the thickness of the hard layer is 5 nm or less,
wherein the hard layer is made of at least one metal or at least one metallic compound, and wherein
the average pitch of the corrugated pattern is 0.4 μm or less, and the average depth of the bottom of the corrugated pattern is 100% or more given an average pitch of 100%.
2. The corrugated pattern forming sheet according to claim 1 , wherein the hard layer is made of a metallic compound.
3. The corrugated pattern forming sheet according to claim 2 , wherein the metallic compound is selected from the group consisting of titanium oxide, aluminum oxide, zinc oxide, magnesium oxide, tin oxide, copper oxide, indium oxide, cadmium oxide, lead oxide, silicon oxide, barium fluoride, calcium fluoride, magnesium fluoride, zinc sulfide, and gallium arsenide.
4. The corrugated pattern forming sheet according to claim 1 , wherein the hard layer is made of a metal.
5. The corrugated pattern forming sheet according to claim 4 ,
wherein the metal is at least one kind of metal selected from the group consisting of gold, aluminum, silver, carbon, copper, germanium, indium, magnesium, niobium, palladium, lead, platinum, silicon, tin, titanium, vanadium, zinc, and bismuth.
6. An antireflector comprising the corrugated pattern forming sheet of any one of claims 1 to 5 .
7. A retardation plate comprising the corrugated pattern forming sheet of any one of claims 1 to 5 .
8. An original process sheet plate, comprising the corrugated pattern forming sheet of any one of claims 1 to 5 .
9. A method for manufacturing an optical element comprising:
coating an uncured curable resin onto a surface of the original process sheet plate of claim 8 , and
peeling a cured coating film from the original process sheet plate after curing the curable resin.
10. A method for manufacturing an optical element comprising:
contacting a sheet-like thermoplastic resin with a surface of the original process sheet plate of claim 8 ;
cooling the thermoplastic resin after softening by heating while pressing to the original process sheet plate; and
peeling the cooled sheet-like thermoplastic resin from the original process sheet plate.
11. A method for manufacturing an optical element comprising:
laminating a material for transferring a corrugated pattern onto a surface of the original process sheet plate of claim 8 ;
preparing a secondary process sheet by peeling the material for transferring the corrugated pattern laminated on the corrugated pattern from the original process sheet plate;
coating an uncured curable resin onto a surface of the secondary process sheet contacting the corrugated pattern of the original process sheet plate; and
peeling a cured coating film from the secondary process sheet after curing the curable resin.
12. A method for manufacturing an optical element comprising:
laminating a material for transferring a corrugated pattern onto a surface of the original process sheet plate of claim 8 ;
preparing a secondary process sheet is prepared by peeling the material for transferring the corrugated pattern laminated on the corrugated pattern from the original process sheet plate;
contacting a sheet-like thermoplastic resin with a surface of the secondary process sheet contacting the corrugated pattern of the original process sheet plate;
cooling the thermoplastic resin after softening by heating while pressing to the secondary process sheet; and
peeling the cooled sheet-like thermoplastic resin from the secondary process sheet.
13. A method for manufacturing a sheet having a corrugated pattern, comprising using a sheet according to any one of claims 1 to 5 as a die to create a sheet with the same average pitch and average depth as the corrugated pattern forming sheet.