Golf ball having reduced surface hardness
A golf ball comprising a core and a cover layer disposed about the core, the cover layer comprising a cover inner surface, a cover outer surface, a treated cover region, and an untreated cover region, the treated cover region extending inward from the cover outer surface a depth D.sub.CTr, the untreated cover region disposed between the cover inner surface and the treated cover region and having a depth D.sub.CUTr, the treated cover region comprising a fatty acid and/or fatty acid salt composition, wherein the treated cover region comprises a hardness .alpha. and the untreated cover region comprises n regions of hardness wherein n.gtoreq.1 and wherein at least one of the n regions of hardness has a hardness H.sub.1 that is different than the hardness .alpha., and wherein each of said n regions of hardness further comprise a depth D.sub.CUTn such that D.sub.CTr.ltoreq.(1/n)(D.sub.UT1+D.sub.UT2+ . . . +D.sub.UTn).
1. A golf ball comprising:
a core comprising at least one layer;
a cover disposed about the core, the cover comprising a single layer formed from one of a thermoset material and a thermoplastic material throughout, said cover layer having a cover inner surface, a cover outer surface, a treated cover region and an untreated cover region, said treated cover region extending inward from the cover outer surface a depth D CTr , the untreated cover region disposed between the cover inner surface and the treated cover region and having a depth D CUTr , said treated cover region being treated with and comprising a fatty acid and/or fatty acid salt composition wherein the treated cover region comprises a hardness α and the untreated cover region does not comprise the fatty acid and/or fatty acid salt composition and has n regions of hardness wherein n≧1 and wherein at least one of the n regions of hardness has a hardness H 1 that is different than the hardness α, and wherein each of said n regions of hardness further comprise a depth D CUTn such that D CTr ≦(1/n) (D UT1 +D UT2 + . . . +D UTn ).
2. The golf ball of claim 1 , wherein the hardness α is less than the hardness H 1 to define a negative hardness gradient within the cover layer.
3. The golf ball of claim 1 , wherein the hardness α is greater than the hardness β to define a positive hardness gradient within the cover layer.
4. The golf ball of claim 1 , wherein the fatty acid and/or fatty acid salt composition comprises oleic acid, palmitic acid, stearic acid, behenic acid, pelargonic acid, linoleic acid, linolenic acid, arachidonic acid, caproic acid, caprylic acid, capric acid, lauric acid, erucic acid, myristic acid, benzoic acid, phenylacetic acid, or naphthalenoic acid.
5. The golf ball of claim 4 , wherein the fatty acid and/or fatty acid salt composition comprises a cation selected from the group comprising barium, lithium, sodium, zinc, bismuth, chromium, cobolt, copper, potassium, strontium, titanium, tungsten, magnesium, cesium, iron, nickel, silver, aluminum, tin and calcium.
6. The golf ball of claim 1 , further comprising an intermediate core layer disposed about the core and adjacent the cover.
7. The golf ball of claim 1 , wherein the cover layer material is a thermoplastic material comprising ethylene/acrylic acid copolymers, ethylene/methacrylic acid copolymers, ethylene/methyl acrylate/acrylic acid terpolymers, ethylene/n-butyl acrylate/methacrylic acid terpolymers, ethylene/isobutyl-acrylate/methacrylic acid terpolymers, or blends thereof.
8. The golf ball of claim 1 , wherein the cover layer material is a thermoplastic material comprising a thermoplastic polyurethane, a thermoplastic polyurea, a styrene block copolymer, a polyester amide, polyester-ester, polyamides, single-site catalyzed polymers, metallocene-catalyzed polymers, polyesters, poly(ethylene terephthalate), poly(butylene terephthalate), poly(propylene terephthalate), poly(trimethylene terephthalate), poly(ethylene naphthenate), polystyrene polymers, poly(styrene-co-maleic anhydride), acrylonitrile-butadiene-styrene, poly(styrene sulfonate), polyethylene styrene, grafted polypropylenes, grafted polyethylenes, polyvinyl chlorides; grafted polyvinyl chlorides; polyvinyl acetates having less than about 9% of vinyl acetate by weight, polycarbonates, blends of polycarbonate and acrylonitrile-butadiene-styrene, blends of polycarbonate and polyurethane, polyvinyl alcohols, polyvinyl alcohol copolymers, polyethers, polyarylene ethers, polyphenylene oxides; block copolymers of alkenyl aromatics with vinyl aromatics and poly(amic ester)s, polyimides, polyetherketones, polyamideimides, or blends thereof.
9. The golf ball of claim 1 , wherein hardness α is different than hardness H 1 by about 3 Shore C or greater.
10. The golf ball of claim 1 , wherein hardness α is different than hardness H 1 by about 2 Shore D or greater.
11. The golf ball of claim 1 , wherein the cover outer surface has been treated with the fatty acid and/or fatty acid salt composition for a duration of from about 0.5 minutes to about 24 hours at a temperature of from about 60° F. to about 350° F.
12. The golf ball of claim 1 , wherein the cover outer surface has further been exposed to a neutralizing solution for a duration of from about 0.5 minutes to about 24 hours at a temperature of from about 60° F. to about 350° F.
13. The golf ball of claim 1 , further comprising an intermediate cover layer disposed between the core and the cover layer comprising a thickness of from about 0.010 inches to about 0.150 inches.
14. A golf ball comprising:
a core comprising at least one layer;
a cover disposed about the core, the cover comprising a single layer formed from one of a thermoset material and a thermoplastic material throughout, said cover having a cover inner surface, a cover outer surface, a treated cover region and an untreated cover region, said treated cover region extending inward from the cover outer surface a depth D CTr , the untreated cover region disposed between the cover inner surface and the treated cover region and having a depth D CUTr , said treated cover region having been exposed to and comprising a fatty acid and/or fatty acid salt composition wherein the treated cover region comprises a hardness α and the untreated cover region does not comprise the fatty acid and/or fatty acid salt composition and has n regions of hardness within depth D CUTr wherein n≧1 and wherein at least one of the n regions of hardness has a hardness H 2 different than the hardness α, each of said n regions further having a depth D CUTn such that D CTr ≦(n)(D CUT1 +D CUT2 + . . . +D CUTn ).
15. The golf ball of claim 14 , wherein the at least one cover layer comprises a thermoplastic composition.
16. The golf ball of claim 14 , wherein the at least one cover layer comprises a thermoset composition.
17. The golf ball of claim 14 , wherein the hardness α is less than the hardness H 2 to define a negative hardness gradient within the cover layer.
18. The golf ball of claim 14 , wherein the hardness α is greater than the hardness β to define a positive hardness gradient within the cover layer.
19. A golf ball comprising:
a core comprising at least one layer;
a cover disposed about the core, the cover comprising a single layer formed from one of a thermoset material and a thermoplastic material throughout, said cover having an inner cover surface, an outer cover surface, a treated cover region and an untreated cover region, said treated cover region extending inward from the cover outer surface a depth D CTr , the untreated cover region disposed between the cover inner surface and the treated cover region and having a depth D CUTr , said treated cover region comprising a fatty acid and/or fatty acid salt composition wherein the treated cover region comprises a hardness α and the untreated cover region does not comprise the fatty acid and/or fatty acid salt composition and has n regions of hardness within depth D CUTr wherein n≧1 and wherein at least one of said n regions of hardness has a hardness H 3 that is different than the hardness α, each of said n regions of hardness further having a depth D CUTn such that D CTr ≦(1/n 2 )(D CUT1 +D CUT2 + . . . +D CUTn ).
20. The golf ball of claim 19 , wherein the at least one cover layer comprises a thermoplastic composition.
21. The golf ball of claim 19 , wherein the at least one cover layer comprises a thermoset composition.
22. The golf ball of claim 19 , wherein the hardness α is less than the hardness H 3 to define a negative hardness gradient within the cover layer.
23. The golf ball of claim 19 , wherein the hardness α is greater than the hardness β to define a positive hardness gradient within the cover layer.