Composite for Li-ion cells and the preparation process thereof
Disclosed herein is a composite for Li-ion cells, comprising an active material particle for Li-ion cells and an electronically conductive elastic material bound or attached to the active material particle. According to the present invention, the electronically conductive elastic material bound or attached to the active material particle allows the particle to maintain electronic contact with the electrode laminate matrix despite ongoing movement or expansion and contraction of the active material particles, such that the cycling efficiency and reversible capacity of the Li-ion cells prepared from the composite of the present invention is improved.
1. A composite for Li-ion cells, comprising an active material particle for Li-ion cells and an electronically conductive elastic carbon material bound or attached to the active material particle by an attaching phase, wherein the electronically conductive elastic carbon material comprises expanded graphite and the attaching phase is selected from the group consisting of a non-lithium ion conducting material that does not react with the active cathode phase at the temperature of formation and a melting attaching or glue phase that includes a Li-ion conducting material.
2. The composite of claim 1 wherein the active material particle comprises a cathode active material particle.
3. The composite of claim 2 wherein the cathode active material particle is at least one selected from the group consisting of LiCoO 2 , LiMn 2 O 4 , Li(NiCoMn)O 2 , Li(NiCo)O 2 , and LiFePO 4 .
4. The composite of claim 1 wherein the non-lithium ion conducting material is at least one selected from the group consisting of a metal oxide, oxide of the metalloid, lithium carbonate, and oxide of the lanthanoid.
5. The composite of claim 4 wherein the metal oxide is MxOy in which M=Co, Cu, V, Ti, Al, or W, x=1-2 and y=2-3, the oxide of the metalloid is B 2 O 3 or SiO 2 and the oxide of the lanthanide is La—O, or Yb—O.
6. The composite of claim 1 wherein the Li-ion conducting material is at least one selected from the group consisting of oxy-halide glass, lithium oxide glass based on B 2 O 3 , and lithium oxide glass based on P 2 O 5 .
7. The composite of claim 6 wherein the oxy-halide glass is B 2 O 3 —Li 2 O-LiX (X=F or Cl), the oxide glass based on B 2 O 3 is Li 2 O—B 2 O 3 or Li 2 O—B 2 O 3 —SiO 2 , the oxide glass based on P 2 O 5 is Li 2 O—P 2 O 5 or Li 2 O—P 2 O 5 —Al 2 O 3 .