IP Library Granted Patent US 9,005,450
Granted Patent B2
US 9,005,450 · App. 12/809,234 · Granted Apr 14, 2015

Use of magnetic, ionic liquids as an extraction agent

Inventor: Roland Kalb (Leoben, AT)
Assignee: Proionic Production of Ionic Substances GmbH & Co KG
H01F1/447B01D11/0419B01D11/0492B03C1/015B03C1/033
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Quick Facts
Patent No.
US 9,005,450
App. No.
12/809,234
Granted
Apr 14, 2015
Kind
B2
Abstract

The invention relates to a method which uses magnetic ionic liquids for the liquid-liquid, liquid-solid, or liquid-gas extraction, wherein the partition of the phases occurs in a magnetic field.

Claims (26)

1. A process for extraction by means of an extracting medium, comprising the steps of:

generating a magnetic extract of a component by contacting a feed with the extracting medium;

the extracting medium being a paramagnetic ionic liquid which comprises magnetic ions in homogeneous phase; and

separating the magnetic extract from the feed by an interaction between the extracting medium and a magnetic field, wherein the partition of phases occurs by the magnetic field,

wherein the separating is not effected based on density differences of the phases.

2. The process as claimed in claim 1 , wherein the extraction is a liquid-liquid or liquid-solid or liquid-gas extraction.

3. The process as claimed in claim 1 , wherein the paramagnetic ionic liquid contains anions which are transition metal compounds.

4. The process as claimed in claim 1 , wherein the paramagnetic ionic liquid contains cations which are transition metal cations and/or transition metal compounds.

5. The process as claimed in claim 4 , wherein the paramagnetic ionic liquid conforms to one of the general formulae

[A] + [M +v X v+1 ] − ,

([A] + ) 2 [M +v X v+2 ] 2− or

([A] + ) 3 [M +v X v+3 ] 3−

where [A] + is a quaternary ammonium cation [R 1′ R 1 R 2 R 3 N] + ;

a phosphonium cation [R 1′ R 1 R 2 R 3 P] + , a sulfonium cation [R 1′ R 1 R 2 S] + or a heteroaromatic cation;

wherein M +v is a transition metal atom having the oxidation number +v, v being an integer in the range 1-6;

wherein X is an ion or ligand having the charge number −1 and wherein R 1 , R 1′ , R 2 , R 3 are each independently hydrogen, optionally substituted alkyl, alkenyl, aklynyl, cycloalkyl, cycloalkenyl, aryl or heteroaryl; or

two of R 1 , R 1′ , R 2 , R 3 combine with a heteroatom to which they are attached to form a ring, wherein the ring is saturated or unsaturated, substituted or unsubstituted.

6. The process as claimed in claim 1 , wherein the paramagnetic ionic liquid comprises a solution of a paramagnetic inorganic and/or organic salt in a nonparamagnetic ionic liquid.

7. The process as claimed in claim 6 , wherein the nonparamagnetic ionic liquid conforms to the general formula ([A] + ) a [B] a− ;

where [A] + is a quaternary ammonium cation [R 1′ R 1 R 2 R 3 N] + , a phosphonium cation [R 1′ R 1 R 2 R 3 P] + , a sulfonium cation [R 1′ R 1 R 2 S] + or a heteroaromatic cation, wherein R 1′ , R 1 , R 2 , R 3 are each independently hydrogen, optionally substituted alkyl, alkenyl, aklynyl, cycloalkyl, cycloalkenyl, aryl or heteroaryl;

or two of R 1 , R 1′ , R 2 , R 3 combine with the heteroatom to which they are attached to form a ring, wherein the ring is saturated or unsaturated, substituted or unsubstituted, and

wherein [B] a− is an anion with a being one of 1, 2, and 3.

8. The process as claimed in claim 6 , wherein the paramagnetic salt has a melting point of below 200° C.

9. The process as claimed in claim 1 , wherein the paramagnetic ionic liquid comprises a solution of a paramagnetic inorganic and/or paramagnetic organic salt in an ionic liquid; and

wherein the paramagnetic ionic liquid has a melting point of below 200° C.

10. The process as claimed in claim 1 , wherein the paramagnetic ionic liquid is admixed with further functional groups and/or with additives.

Assignments (3)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 17, 2018
From: PROIONIC GMBH & CO KG
To: PROIONIC GMBH
Reel/Frame 047198/0199 →
CHANGE OF NAME Recorded Sep 28, 2018
From: PROIONIC PRODUCTION OF IONIC SUBSTANCES GMBH & CO. KG
To: PROIONIC GMBH & CO KG
Reel/Frame 047161/0606 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 14, 2010
From: KALB, ROLAND
To: PROIONIC PRODUCTION OF IONIC SUBSTANCES GMBH & CO KG
Reel/Frame 025135/0685 →
Continuity (2)
Provisional Application 61015469 · Dec 20, 2007
Related Publication 20110020509A1 · Jan 27, 2011