Method of dehydrating acetic acid
View Patent ↗The invention pertains to a process for dehydrating wet acetic acid. One embodiment of the invention comprises contacting wet acetic acid with acetyl chloride. Another embodiment of the invention comprises contacting wet acetic acid; acetic anhydride; and a catalytic effective amount of hydrogen chloride, acetyl chloride, or a chlorosilane.
1. A process for dehydrating wet acetic acid, comprising contacting wet acetic acid and acetyl chloride wherein the contacting results in a total water conversion of from 10 to 99 weight % of the water in the wet acetic acid.
2. The process of claim 1 wherein the contacting is at a temperature from 25° C. to 200° C.
3. The process of claim 2 wherein the temperature is from 50° C. to 85° C.
4. The process of claim 1 where in the wet acetic acid comprises 0.01 to ≦0.15 weight % water based upon the weight of the wet acetic acid.
5. The process of claim 1 , wherein the acetyl chloride is from −75 to 5000 mole % excess compared to the water.
6. The process of claim 5 wherein the acetyl chloride is from −25 to 100 mole % excess compared to the water.
7. The process of claim 1 wherein the wet acetic acid comprises from >0 to 50,000 ppm water based on the weight of the acetic acid.
8. A process for dehydrating wet acetic acid, comprising:
contacting wet acetic acid, acetic anhydride, and a catalytic effective amount of i) hydrogen chloride, ii) a chlorosilane, iii) acetyl chloride, or iv) mixtures of i), ii) and iii), wherein the contacting results in a total water conversion of from 10 to 99 weight % of the water in the wet acetic acid, and wherein the contacting results in in situ production of acetyl chloride.
9. The process of claim 8 wherein the contacting is at a temperature from 25° C. to 200° C.
10. The process of claim 9 wherein the temperature is from 50° C. to 85° C.
11. The process of claim 8 wherein a catalytic effective amount of i) hydrogen chloride is contacted with the wet acetic acid and the acetic anhydride.
12. The process of claim 11 wherein the i) hydrogen chloride is formed in situ from the contacting of ii) or iii) with the acetic anhydride and the wet acetic acid.
13. The process of claim 8 wherein the catalytic effective amount is from 5 ppm to 50,000 ppm based on the weight of the wet acetic acid.
14. The process of claim 13 wherein the catalytic effective amount is from 5 to 2000 ppm based upon the weight of the wet acetic acid contacted.
15. The process of claim 8 where in the wet acetic acid comprises >0 to 50,000 ppm water based upon the weight of the wet acetic acid.
16. The process of claim 15 wherein the wet acetic acid comprises >0 to 2000 ppm water based upon the weight of the wet acetic acid.
17. The process of claim 8 wherein the acetic anhydride is in from −75 to 300 mole % excess to the water in the wet acetic acid.
18. The process of claim 17 wherein the acetic anhydride is in from −25 to 100 mole % excess to the water in the wet acetic acid.
19. A process of dehydrating wet acetic acid, comprising:
contacting wet acetic acid comprising >0 to 2000 ppm water based on the weight of wet acetic acid; acetic anhydride in −25 to 100 mole % excess compared to the water in the wet acetic acid; and a catalytic effective amount of hydrogen chloride, a chlorosilane, or acetyl chloride at a temperature from 50 to 85° C., wherein the contacting results in a total water conversion of from 20 to 95 weight % of the water in the wet acetic acid, and wherein the contacting results in in situ production of acetyl chloride.