Vapor phase assisted post-consumer polymer processing apparatus and method
Embodiments of the invention provide a process for processing post-consumer polymer. The polymer is contacted with a control medium having a carrier gas and a reactive vapor. Such a process is useful for processing post-consumer polymers with lower energy and reactants than with liquid reactants, and also promotes decontamination of the recycled polymer during the reaction.
1. A process for processing post-consumer polyester polymers comprising the steps of:
a) conveying post-consumer polymer feed material to a reaction vessel;
b) heating the polymer feed material to a temperature sufficient to initiate and sustain reaction in a solid state;
c) contacting the heated polymer with a control medium comprising a carrier gas and a reactive vapor;
d) performing a solid state reaction (SSR) between the polymer and control medium, to provide a product;
e) discharging the product,
wherein the reactive vapor comprises ethylene glycol at a concentration of about 10 and 3,000 ppm in the control medium.
2. A process according to claim 1 , wherein the polymer comprises PET.
3. A process according to claim 1 , wherein the process permits the recovery of product having a number average molecular weight in the range of 3000 to 115,000 and an intrinsic viscosity in the range of 0.15 to 1.30 dl/g.
4. A process according to claim 3 , wherein the product is discharged to an extruder to produce a food grade product.
5. A process according to claim 1 , wherein a residence time for the reaction is about 2 to about 8 hours.
6. A process according to claim 1 , wherein a temperature of the polymer during the reaction is about 190 to about 220 ° C.
7. A process according to claim 1 , wherein the discharged product of step e) has contaminant levels below 0.22 ppm.
8. A process according to claim 1 , wherein the discharged product of step e) has an intrinsic viscosity between 0.78 and 0.82 dl/g.
9. A process according to claim 1 , wherein the carrier gas is nitrogen.
10. A process according to claim 1 , wherein the carrier gas is carbon dioxide.
11. A process according to claim 1 , further comprising removing contaminants from the polymer with the control medium.
12. A process according to claim 11 , further including recovering the control medium, separating the contaminants from the control medium, and reintroducing the control medium to the polymer.
13. A process for processing post-consumer polyester polymers comprising the steps of:
a) conveying post-consumer polymer feed material to a reaction vessel;
b) heating the polymer feed material to a temperature sufficient to initiate and sustain reaction in a solid state;
c) contacting the heated polymer with a control medium comprising a carrier gas and a reactive vapor;
d) performing a solid state reaction (SSR) between the polymer and control medium, to provide a product;
e) simultaneously with step (d), reducing the level of contaminants within the polymer with the control medium; and
f) discharging the product,
wherein the reactive vapor comprises ethylene glycol at a concentration of about 10 and 3,000 ppm in the control medium.
14. A process according to claim 13 , wherein the contaminants are selected from the group consisting of organic volatile polar, organic volatile non-polar, organic non-volatile polar, organic non-volatile polar contaminants, and any combination thereof.
15. A process according to claim 13 , wherein the contaminants are selected from the group consisting of toluene, benzophenone, lindane, chlorobenzene, phenyl cyclohexane, methyl salicylate, methyl stearate, chloroform, and any combination thereof.
16. A process according to claim 13 , wherein steps (d) and (e) are done under atmospheric pressure.
17. A process according to claim 1 , wherein the carrier gas comprises nitrogen, the rate of polymer molecular weight increase is decreased in the solid state reaction, and the discharged product of step e) has contaminant levels below 0.22 ppm.
18. A process according to claim 13 , wherein the discharged product of step e) has contaminant levels below 0.22 ppm.
19. A process for processing post-consumer polyester polymers comprising the steps of:
a) conveying post-consumer polymer feed material to a reaction vessel;
b) heating the polymer feed material to a temperature sufficient to initiate and sustain reaction in a solid state;
c) contacting the heated polymer with a control medium comprising a carrier gas and a reactive vapor;
d) performing a solid state reaction (SSR) between the polymer and control medium, to provide a product;
e) discharging the product,
wherein the reactive vapor comprises ethylene glycol at a concentration of about 10 and 3,000 ppm in the control medium, a residence time for the reaction is about 2 to about 8 hours, a temperature of the polymer during the reaction is about 190 to about 220 C, and the process permits the recovery of product having a number average molecular weight in the range of 3000 to 115,000 and an intrinsic viscosity in the range of 0.15 to 1.30 dl/g.
20. A process according to claim 19 wherein the discharged product of step e) has contaminant levels below 0.22 ppm.
21. A process according to claim 20 , wherein the contaminants are selected from the group consisting of toluene, benzophenone, lindane, chlorobenzene, phenyl cyclohexane, methyl salycilate, methyl stearate, chloroform, and any combination thereof.
22. A process according to claim 19 wherein the product is discharged to an extruder to produce a food grade product.
23. A process according to claim 19 wherein the rate of polymer molecular weight increase is decreased in the solid state reaction.
24. A process according to claim 19 wherein the rate of polymer molecular weight increase is decreased in the solid state reaction, the discharged product of step e) has contaminant levels below 0.22 ppm, the product is discharged to an extruder to produce a food grade product.