Method for producing a composite material with improved adhesion between thermoplastics and polyurethane
The present disclosure relates to a method for producing composite materials containing as a first layer a foamed thermoplastic support and as a second layer polyurethane (PU), the resulting composite materials being characterized by improved foam adhesion, wherein (i) a foamed polycarbonate molding composition is produced by injection molding using chemical or physical foaming techniques, and (ii) the polyurethane reaction system is applied on top and allowed to cure. The disclosure also provides the composite systems produced by this method and their use as a component, in particular in the automotive sector.
1. Method for producing a composite material, comprising
(i) producing a foamed polycarbonate moulding composition by injection moulding using chemical and/or physical foaming techniques, and
(ii) applying a polyurethane reaction system on top of said polycarbonate moulding composition and allowing to cure;
wherein said moulding composition comprises:
A) 20 to 99.9 parts by weight of aromatic polycarbonate and/or aromatic polyester carbonate,
B) 0.1 to 40 parts by weight of rubber-modified graft polymer,
C) 0 to 40 parts by weight of vinyl (co)polymer (C.1) and/or polyalkylene terephthalate (c.2),
D) 0 to 50 parts by weight of glass fibres, and
E) 0 to 30 parts by weight of additives.
2. Method according to claim 1 , wherein the polycarbonate moulding composition comprises glass fibres.
3. Method according to claim 1 , wherein the foamed polycarbonate moulding composition is produced by injection moulding, by
(i-1) mixing A-E of the polycarbonate composition and
(i-2) melt compounding and melt extruding the mixture resulting from (i-1) at a temperature of 200° C. to 320° C. wherein
in (i-2)
(i-2.1) a batch comprising chemical blowing agent and at least one of components A, B or C is fed to an extruder with the mixture resulting from (i-1), or
(i-2.2) a chemical blowing agent is mixed with the mixture resulting from (i-1), or
(i-2.3) a physical blowing agent is added to the melt.
4. Method according to claim 3 , wherein the chemical blowing agent is used and is citric acid and/or formic acid.
5. Method according to claim 3 , wherein the physical blowing agent is used and is an inert gas.
6. Method according to claim 3 , wherein the physical blowing agent is used and is nitrogen, argon, or carbon dioxide.
7. Method according to claim 1 , wherein the foamed polycarbonate moulding composition are produced by injection moulding, by
(i-1) mixing AE of the polycarbonate composition
(i-2) melt compounding and melt extruding the mixture resulting from (i-1) at a temperature of 200° C. to 320° C.
wherein, in (i-2)
(i-2.3) a physical blowing agent is added to the melt, the addition being made
to a screw of an extruder or a twin-shaft screw, or
to a space in front of a screw of an extruder or a twin-shaft screw, or
to the resulting mixture immediately after an internal mixer, extruder or twin-shaft screw.
8. Method according to claim 7 , wherein the physical blowing agent is an inert gas.
9. Method according to claim 7 , wherein the physical blowing agent is nitrogen, argon, or carbon dioxide.
10. Method according to claim 1 , wherein component C) is present.
11. Method according to claim 1 , wherein said moulding composition comprises:
A) 50 to 91.5 parts by weight of aromatic polycarbonate and/or aromatic polyester carbonate,
B) 0.4 to 35 parts by weight of rubber-modified graft polymer,
C) 1 to 30 parts by weight of vinyl (co)polymer (C.1) and/or polyalkylene terephthalate (C.2),
D) 7 to 35 parts by weight of glass fibres, and
E) 0.1 to 18 parts by weight of additives.
12. Method according to claim 1 , wherein component B) comprises one or more graft polymers of
B.1 10 to 90 wt % relative to component B, of at least one vinyl polymer on
B.2 90 to 10 wt. % relative to component B, of at least one graft base selected from the group consisting of diene rubbers, EP(D)M rubbers, acrylate, polyurethane, silicone, silicone acrylate, chloroprene and ethylene/vinyl acetate rubbers.
13. Method according to claim 1 , wherein component D) is present and is a sized glass fibre having
D.1 a glass fibre selected from at least one component of the group consisting of continuous strands, long glass fibres, and chopped strands,
D.2 a size containing an epoxy polymer, wherein the size partially or wholly covers the surface of the glass fibres and/or fills any pores in the glass fibres, and
D.3 optionally a coupling agent.
14. Method according to claim 1 , wherein component E) is present and is selected from the group consisting of flame retardants, flame retardant synergists, antidripping agents, lubricants and release agents, nucleating agents, antistatics, stabilisers, fillers and reinforcing materials differing from component D), and dyes and pigments.
15. Method according to claim 1 , wherein the polyurethane reaction system is a polyurethane foam and/or a compact polyurethane layer.
16. Method according to claim 1 , wherein said composite material comprises at least one further polymeric layer (3).
17. Method according to claim 16 , wherein the further polymeric layer (3) is a layer based on polyvinyl chloride (PVC) and/or a thermoplastic urethane (TPU).
18. Method according to claim 16 , wherein layer (3) is joined directly to the polyurethane reaction system.
19. Method according to claim 1 , wherein the composite material achieves an initial adhesion rating of less than 3, achieves a foam adhesion after double climate test rating of less than 3, or achieves a blooming rate rating of 1-3.