Pesticidal compositions
To provide a formulation composition which improves the controlling effect of an anthranilamide compound against pests. A pesticide composition which is a concentrated composition containing an anthranilamide compound as a pesticidal active ingredient, a dispersant and a hydrophilic organic solvent, characterized in that when the composition is diluted with water, the anthranilamide compound precipitates as solid particles in water.
1. A pesticide composition, comprising, based on a total weight of the composition:
(i) from 0.1 to 45 wt % of an anthranilamide compound of formula (I):
wherein:
R′ is halogen, alkyl, or cyano;
A is alkyl which is optionally substituted with C 3-4 cycloalkyl; and
m is from 0 to 4;
(ii) from 0.1 to 40 wt % of a dispersant; and
(iii) from 99.8 to 15 wt % of a hydrophilic organic solvent selected from the group consisting of N,N-dimethylacetamide, dimethylformamide, dimethylsulfoxide, cyclohexanone, γ-butyrolactone, N-methyl-2-pyrrolidone, N-octyl-2-pyrrolidone, N-dodecyl-2-pyrrolidone, tetrahydroxyfurfuryl alcohol, and propylene glycol monomethyl ether,
wherein the anthranilamide compound and the dispersant are dissolved in the hydrophilic organic solvent, and
wherein when the composition is diluted with water, the anthranilamide compound uniformly precipitates as fine solid particles in water.
2. The composition of claim 1 , wherein the anthranilamide compound is:
(a) 3-bromo-N-(2-bromo-4-chloro-6-(1-cyclopropylethylcarbamoyl)phenyl)-1-(3-chloropyridin-2-yl)-1H-pyrazol-5-carboxamide;
(b) 3-bromo-N-(4-chloro-2-(1-cyclopropylethylcarbamoyl)-6-methylphenyl)-1-(3-chloropyridin-2-yl)-1H-pyrazol-5-carboxamide;
(c) 3-bromo-N-(2-bromo-4-chloro-6-(cyclopropylmethylcarbamoyl)phenyl)-1-(3-chloropyridin-2-yl)-1H-pyrazol-5-carboxamide;
(d) 3-bromo-N-(4-chloro-2-methyl-6-(methylcarbamoyl)phenyl)-1-(3-chloropyridin-2-yl)-1H-pyrazol-5-carboxamide; or
(e) 3-bromo-1-(3-chloropyridin-2-yl)-N-(4-cyano-2-methyl-6-(methylcarbamoyl)phenyl-1H-pyrazol-5-carboxamide.
3. The composition of claim 1 , wherein the hydrophilic organic solvent is at least one selected from the group consisting of N,N-dimethylacetamide, dimethylsulfoxide, γ-butyrolactone, N-methyl-2-pyrrolidone and cyclohexanone.
4. The composition of claim 1 , wherein the dispersant is a nonionic surfactant and/or an anionic surfactant.
5. The composition of claim 1 , wherein the dispersant is at least one selected from the group consisting of a C 8-12 polyoxyethylene alkyl aryl ether, a polyoxyethylene tristyrylphenyl ether, a C 8-12 alkylbenzene sulfonate and a C 8-18 polyoxyethylene alkyl ether phosphoric acid ester.
6. The composition of claim 1 , comprising:
(i) the anthranilamide compound;
(ii) a nonionic surfactant and/or an anionic surfactant as the dispersant; and
(iii) at least one hydrophilic organic solvent selected from the group consisting of N,N-dimethylacetamide, dimethylsulfoxide, γ-butyrolactone, N-methyl-2-pyrrolidone and cyclohexanone.
7. The composition of claim 1 , comprising:
(i) the anthranilamide compound;
(ii) at least one dispersant selected from the group consisting of a C 8-12 polyoxyethylene alkyl aryl ether, a polyoxyethylene tristyrylphenyl ether, a C 8-12 alkylbenzene sulfonate and a C 8-18 polyoxyethylene alkyl ether phosphoric acid ester; and
(iii) at least one hydrophilic organic solvent selected from the group consisting of N,N-dimethylacetamide, dimethylsulfoxide, γ-butyrolactone, N-methyl-2-pyrrolidone and cyclohexanone.
8. The composition of claim 1 , wherein the content of the anthranilamide compound is from 1 to 20 wt %, based on a total weight of the composition.
9. The composition of claim 1 , wherein the content of the dispersant is from 0.5 to 20 wt %, based on a total weight of the composition.
10. The composition of claim 8 , wherein the content of the dispersant is from 0.5 to 20 wt %, based on a total weight of the composition.
11. The composition of claim 1 , wherein the average particle size of the fine solid particles is from 0.01 to 50 μm.