High molecular weight polyacrylates for aluminum protection in warewash applications
A warewashing detergent composition is provided for use for in cleaning of alkaline sensitive metals such as aluminum or aluminum containing alloys. The compositions include alternatives to sodium tripolyphosphate and/or other phosphorous containing raw materials, while retaining cleaning performance and corrosion prevention. According to the invention, high molecular weight polyacrylates (polyacrylic acid homopolymers) with a molecular weight of at least about 5000 are used as corrosion inhibitors and can be included for aluminum protection in a number of different detergent compositions.
1. A detergent composition comprising:
(a) a metal silicate in an amount effective to provide a use composition having a pH of at least about 8 and obtained by diluting the detergent composition with water, wherein said effective amount of metal silicate is between 30 wt. % and 55 wt. %; and
(b) a corrosion inhibitor component in an amount sufficient for reducing corrosion of aluminum or aluminum containing alloys, the corrosion inhibitor component consisting of one or more polyacrylic acid homopolymers having a molecular weight of at least about 5,000 daltons, wherein said sufficient amount of corrosion inhibitor is between 5 wt. % and 30 wt. %;
wherein said composition contains less than about 0.1% by weight of phosphorous;
wherein said composition does not include 1-hydroxy ethylidene 1-1-diphosphonic acid; and
wherein said composition does not include sodium carbonate.
2. The detergent composition according to claim 1 further comprising:
(c) a cleaning agent comprising a detersive amount of a surfactant.
3. The detergent composition according to claim 2 , wherein the detergent composition comprises between about 0.5 wt. % and about 20 wt. % of the cleaning agent.
4. The detergent composition according to claim 1 , wherein said acrylic acid homopolymer has a molecular weight of greater than 10,000 daltons.
5. The detergent composition according to claim 2 , wherein the cleaning agent comprises at least one of an anionic surfactant, a nonionic surfactant, a cationic surfactant, or a zwitterionic surfactant.
6. The detergent composition according to claim 1 wherein the detergent comprise less than about 0.05% by weight of phosphorous.
7. The detergent composition according to claim 1 wherein the detergent is substantially phosphorous free.
8. A method for manufacturing a detergent composition, the method comprising:
(a) providing an amount of corrosion inhibitor in a detergent composition concentrate sufficient to provide a level of corrosion inhibitor in a use composition as a result of diluting the detergent concentrate with water at a ratio of water to the detergent concentrate of at least about 20:1 wherein said corrosion inhibitor is between 5 wt. % and 30 wt. % in the concentrate and comprises one or more acrylic acid homopolymers having a molecular weight of at least about 5,000 daltons and comprises less than about 0.1% by weight of phosphorous, and wherein said detergent composition concentrate comprises an alkaline source between 30 wt. % and 90 wt. %, and further wherein said alkaline source includes a metal silicate and does not include 1-hydroxy ethylidene 1-1-diphosphonic acid or sodium carbonate.
9. A method for protecting aluminum or aluminum containing alloys from corrosion comprising:
contacting the surface of the same with a corrosion inhibitor comprising:
(a) one or more acrylic acid homopolymers having a molecular weight of at least about 5,000 daltons, and wherein said corrosion inhibitor is between 5 wt, % and 30 wt. % of a detergent composition, said detergent composition including less than about 0.1% by weight of phosphorous and further including
(b) an alkaline source in an amount effective to provide a use composition having a pH of at least about 8, wherein said effective amount of alkaline source is between 30 wt. % and 55 wt. %, and further wherein said alkaline source includes a silicate;
(c) wherein said corrosion inhibitor does not include sodium carbonate; and
(d) wherein said corrosion inhibitor does not include 1-hydroxy ethylidene 1-1-diphosphonic acid.
10. The method of claim 9 , wherein the corrosion inhibitor comprises one or more acrylic acid homopolymers having a molecular weight of greater than 10,000 daltons.