Crystal growth method and semiconductor light emitting device
View Patent ↗According to one embodiment, a crystal growth method is disclosed for growing a crystal of a nitride semiconductor on a major surface of a substrate. The major surface is provided with asperities. The method can include depositing a buffer layer on the major surface at a rate of not more than 0.1 micrometers per hour. The buffer layer includes Ga x Al 1-x N (0.1≦x<0.5) and has a thickness of not smaller than 20 nanometers and not larger than 50 nanometers. In addition, the method can include growing the crystal including a nitride semiconductor on the buffer layer at a temperature higher than a temperature of the substrate in the depositing the buffer layer.
1. A crystal growth method for growing a crystal of a nitride semiconductor comprising:
depositing a buffer layer on a major surface of a substrate at a depositing rate of not more than 0.1 micrometers per hour, the buffer layer including Ga x Al 1-x N (0.1≦x<0.5) and having a thickness of not smaller than 20 nanometers and not larger than 50 nanometers, the substrate having asperities provided on the major surface; and
growing the crystal on the buffer layer at a temperature higher than a temperature of the substrate in the depositing the buffer layer, wherein said growing the crystal comprises producing said crystal with a pit density of less than 200 pits per 400 μm×400 μm area.
2. The method according to claim 1 , wherein
the depositing the buffer layer includes using a trimethylgallium gas with a partial pressure of not more than 0.00025, the partial pressure being a ratio of a flow rate of the trimethylgallium gas to a flow rate of a total of used gas including the trimethylgallium gas.
3. The method according to claim 1 , wherein
the buffer layer is polycrystalline.
4. The method according to claim 1 , wherein
the temperature of the substrate in the depositing the buffer layer is not higher than 600° C., and
the temperature of the substrate in the growing the crystal is not lower than 800° C.
5. The method according to claim 1 , wherein
the substrate is a sapphire substrate.
6. The method according claim 1 , wherein
the growing the crystal includes forming a non-doped GaN layer on the buffer layer and forming a GaN layer including Si on the non-doped GaN layer.
7. The method according to claim 6 , wherein
the growing the crystal further includes forming at least one of a light emitting portion and a p-type semiconductor layer on the GaN layer including Si.
8. The method according to claim 1 , wherein
the depositing the buffer layer and the growing the crystal include performing at least one of a metal organic chemical vapor deposition method, a halide vapor phase epitaxy method, and a molecular beam epitaxy method.
9. The method according to claim 1 , wherein
the growing the crystal includes processing using at least one of trimethylgallium, triethylgallium, trimethylaluminum, trimethylindium, biscyclopentadienylmagnesium, ammonia, silane, hydrogen, and nitrogen.
10. The method according to claim 1 , wherein
the substrate includes at least one of sapphire, GaN, SiC, and ZnO.
11. The method according to claim 1 , wherein
a reaction chamber in which the growing the crystal is performed is identical to a reaction chamber in which the depositing the buffer layer is performed, and
the growing the crystal is continuously performed with the depositing the buffer layer.
12. The method according to claim 1 , wherein
the depositing rate of the depositing the buffer layer is not less than 0.03 micrometers per hour.
13. The method according to claim 1 , wherein
the thickness of the buffer layer is not smaller than 30 nanometers and not larger than 40 nanometers.
14. The method according to claim 1 , wherein
the asperities include a protruding portion and a recessing portion, and
a difference between a thickness of the buffer layer in the protruding portion and a thickness of the buffer layer in the recessing portion is not larger than 7 nanometers.
15. The method according to claim 1 , wherein
a height of each of the asperities is not less than 0.5 micrometers and not more than 2 micrometers.
16. The method according to claim 1 , wherein
a width of each of the asperities is not less than 0.5 micrometers and not more than 5 micrometers, and
an arrangement pitch of the asperities is not less than 1 micrometer and not more than 8 micrometers.
17. The method according to claim 1 , wherein
the temperature of the substrate in the depositing the buffer layer is not higher than 500° C.
18. The method according to claim 1 , wherein the asperities include a protruding portion and a recessing portion, the protruding portion having a flat face,
a height of the asperities is not less than 0.5 μm and not more than 2 μm,
a width of the asperities is not less than 0.5 μm and not more than 5 μm, and
an arrangement pitch of the asperities is not less than 1 μm and not more than 8 μm.
19. The method according to claim 18 , wherein a difference between a first thickness of the buffer layer on the protruding portion and a second thickness of the buffer layer on the protruding portion is not more than 7 nm.
20. The method according to claim 19 , wherein the asperities covered with the buffer layer are buried by the crystal of the nitride semiconductor so as not to make a space between the crystal and the asperities covered with the buffer layer.
21. The method according to claim 1 , wherein said growing the crystal comprises producing said crystal with a pit density of less than 60 pits per 400 μm×400 μm area.
22. The method according to claim 1 , wherein said growing the crystal comprises producing said crystal with a pit density of less than 10 pits per 400 μm×400 μm area.