Barrier layers
View Patent ↗Methods for fabricating integrated circuit electrical interconnects and electrical interconnects are provided. Methods include providing a substrate having a surface, the surface having a feature formed therein wherein the feature is a trench or via, depositing a metal layer, the metal of the metal layer being selected from the group consisting of Ru, Co, Pt, Ir, Pd, Re, and Rh, onto surfaces of the feature, depositing a copper seed layer wherein the copper seed layer comprises a dopant and the dopant is selected from the group consisting of Mn, Mg, MgB 2 . P, B, Al, Co and combinations thereof, onto the metal layer, and depositing copper into the feature. Devices comprising copper interconnects having metal liner layers are provided. Devices having liner layers comprising ruthenium are provided.
1. A device comprising;
a substrate having a layer of dielectric material on a surface of the substrate, the dielectric material having a feature formed therein, wherein the feature is a depression in the dielectric material, wherein the feature has at least one side wall and the side wall of the feature is coated with a barrier layer, wherein the barrier layer is comprised of a metal selected from the group consisting of Pt, Ir, Pd, Re, and Rh, and a substance selected from the group consisting of Mn, Mg, MgB 2 , P, B, Al, and Co, wherein the substance is present in the barrier layer in an amount from 1 to 10 atomic weight percent of the metal that is selected from the group consisting of Pt, Ir, Pd, Re, and Rh, wherein the feature contains copper, and wherein the barrier layer is between the copper and the dielectric material, wherein the feature does not comprise a layer comprising Ti, Ta, or W between the copper and the dielectric material.
2. The device of claim 1 wherein the barrier layer is between 1 and 4 nm thick.
3. The device of claim 1 wherein the feature is a trench or via.
4. A device comprising;
a substrate having a layer of dielectric material on a surface of the substrate, the dielectric material having a feature formed therein, wherein the feature is a depression in the dielectric material, wherein the feature has at least one side wall and wherein the side wall of the feature is coated with a barrier layer, wherein the barrier layer is comprised of ruthenium and a substance selected from the group consisting of B, MgB 2 , P, Al, and Co, wherein the substance is present in the barrier layer in an amount from 1 to 10 atomic weight percent of the ruthenium, wherein the feature contains copper, and wherein the barrier layer is between the copper and the dielectric material, wherein the feature does not comprise a layer comprising Ti, Ta, or W between the copper and the dielectric material.
5. The device of claim 4 wherein the barrier layer is between 1 and 4 nm thick.
6. The device of claim 4 wherein the feature is a trench or via.
7. A device comprising;
a substrate having a layer of dielectric material on a surface of the substrate, the dielectric material having a feature formed therein, wherein the feature is a depression in the dielectric material, wherein the feature has at least one side wall and wherein the side wall of the feature is coated with a barrier layer, wherein the barrier layer is comprised of ruthenium and a substance selected from the group consisting of MgB 2 and Al wherein the feature contains copper, and wherein the barrier layer is between the copper and the dielectric material, wherein the feature does not comprise a layer comprising Ti, Ta, or W between the copper and the dielectric material.
8. The device of claim 7 wherein the substance is present in the barrier layer in an amount from 1 to 10 atomic weight percent of the ruthenium.
9. The device of claim 7 wherein the substance is present in the barrier layer in an amount from 1 to 5 atomic weight percent of the ruthenium.
10. The device of claim 7 wherein the barrier layer is between 1 and 4 nm thick.
11. The device of claim 7 wherein the feature is a trench or via.
12. A device comprising;
a substrate having a layer of dielectric material on a surface of the substrate, the dielectric material having a feature formed therein, wherein the feature is a depression in the dielectric material, wherein the feature has at least one side wall and the side wall of the feature is coated with a barrier layer, wherein the barrier layer is comprised of a metal selected from the group consisting of Pt, Ir, Pd, Re, and Rh, and as substance selected from the group consisting of Mn, Mg, MgB 2 , P, B, Co, and Al, wherein the feature contains copper, and wherein the barrier layer is between the copper and the dielectric material, wherein the feature does not comprise a layer comprising Ti, Ta, or W between the copper and the dielectric material.
13. The device of claim 12 wherein the substance is present in the barrier layer in an amount from 1 to 10 atomic weight percent of the metal that is selected from the group consisting of Pt, Ir, Pd, Re, and Rh.
14. The device of claim 12 wherein the barrier layer is between 1 and 4 nm thick.
15. The device of claim 12 wherein the feature is a trench or via.