Methods for preparing materials for lithium ion batteries
A process for preparing transition metal particles with a gradient in composition from the core of the particle to the outer layers. In particular, the process involves contacting a first transition metal solution with a second transition metal solution to form a transition metal source solution under specific process conditions. The transition metal particles with desired composition gradients are precipitated from the transition metal source solution. The transition metal particles may be combined with metals such as lithium to form cathode active metal oxides.
1. A process comprising:
dissolving a first transition metal compound in a solvent to form a first transition metal solution and dissolving a second transition metal compound in a solvent to form a second transition metal solution;
flowing the first transition metal solution into the second transition metal solution to form a transition metal source solution;
contacting the transition metal source solution with a precipitating agent to form a precursor solution; and
precipitating from the precursor solution a precipitated particle, the precipitated particle having a radius and a transition metal oxide core;
wherein:
the concentration of the first transition metal compound in the transition metal source solution and the concentration of the second transition metal compound in the transition metal source solution change with time; and
the precipitated particles have a transition metal gradient in which the ratio of the first transition metal to the second transition metal is inversely proportional to the radius of the particle over at least a portion of the radius.
2. The process of claim 1 , wherein the contacting comprises stirring.
3. The process of claim 1 , wherein a transition metal of the first transition metal compound is manganese, cobalt, nickel, chromium, vanadium, aluminum, zinc, sodium, titanium, or iron and a transition metal of the second transition metal compound is manganese, cobalt, nickel, chromium, vanadium, aluminum, zinc, sodium, titanium, or iron.
4. The process of claim 1 , wherein the first transition metal compound is manganese sulfate, nickel sulfate, cobalt sulfate, manganese nitrate, nickel nitrate, cobalt nitrate, manganese chloride, nickel chloride, cobalt chloride, manganese acetate, nickel acetate, cobalt acetate, manganese citrate, nickel citrate, or cobalt citrate and the second transition metal compound is manganese sulfate, nickel sulfate, cobalt sulfate, manganese nitrate, nickel nitrate, cobalt nitrate, manganese chloride, nickel chloride, cobalt chloride, manganese acetate, nickel acetate, cobalt acetate, manganese citrate, nickel citrate, or cobalt citrate.
5. The process of claim 1 , wherein:
the first transition metal compound comprises manganese and the second transition metal compound comprises cobalt;
the first transition metal compound comprises manganese and the second transition metal compound comprises nickel;
the first transition metal compound comprises cobalt and the second transition metal compound comprises nickel;
the first transition metal compound comprises nickel and the second transition metal compound comprises manganese;
the first transition metal compound comprises nickel and the second transition metal compound comprises cobalt; or
the first transition metal compound comprises cobalt and the second transition metal compound comprises nickel.
6. The process of claim 1 , wherein the precipitating agent comprises sodium carbonate, sodium hydroxide, potassium carbonate, potassium hydroxide, lithium carbonate, or lithium hydroxide.
7. The process of claim 1 further comprising contacting the precursor solution with a chelating agent prior to precipitating.
8. The process of claim 7 , wherein the chelating agent comprises ammonium hydroxide, hydrazine, or ethylenediaminetetraacetic acid.
9. The process of claim 1 further comprising:
dissolving a third transition metal compound in a solvent to form a third transition metal solution; and
flowing the third transition metal solution into the transition metal source solution.
10. The process of claim 9 , wherein the transition metal of the third transition metal compound is manganese, cobalt, or nickel.
11. The process of claim 9 , wherein the third transition metal compound is manganese sulfate, nickel sulfate, cobalt sulfate, manganese nitrate, nickel nitrate, or cobalt nitrate.
12. The process of claim 1 , wherein a concentration of a first transition metal in the first transition metal solution is from 0.001 M to 6 M.
13. The process of claim 1 , wherein a concentration of a second transition metal in the second transition metal solution is from 0.001 M to 6 M.
14. The process of claim 1 , wherein the solvent comprises water or an alcohol.
15. The process of claim 1 further comprising collecting the particles.
16. The process of claim 1 further comprising contacting the particles with lithium.
17. The process of claim 1 further comprising heating the particles at elevated temperature.
18. An electrochemical device comprising a particle prepared by the process of claim 1 .
19. The process of claim 1 , wherein the transition metal gradient correlates with the change in concentrations of the first and second transition metal compounds in the transition metal source solution.